bis(2,4,6-triisopropylphenyl)difluorostannane | 142799-36-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2,4,6-triisopropylphenyl)difluorostannane
• 英文别名: bis(2,4,6-triisopropylphenyl)SnF2；(2,4,6-triisopropylphenyl)2SnF2；Stannane, difluorobis[2,4,6-tris(1-methylethyl)phenyl]-；difluoro-bis[2,4,6-tri(propan-2-yl)phenyl]stannane
• CAS: 142799-36-8
• 化学式: C₃₀H₄₆F₂Sn
• 分子量: 563.402
• InChiKey: UEYAVUYZHSXIPD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.92
• 重原子数：
  33
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(2,4,6-triisopropylphenyl)difluorostannane 在 SiO₂ 作用下， 以 四氢呋喃 、 苯 为溶剂， 生成 [bis(2,4,6-triisopropylphenyl)SnPH]2
  参考文献：
  名称：

  Synthesis of the first fluoro(phosphanyl)- and diphosphanyl-stannanes and surprising formation of [P(SnMe₃)₄]⁺SiF₅⁻

  摘要：

  对二氟锡烷 Is2SnF2 （Is = 2,4,6-三异丙基苯）进行单磷基化反应，使用 Si(PH2)4，生成了第一个可分离的氟（磷烷基）锡烷 Is2Sn(F)PH2 1。该化合物在 SiO2 辅助下，可以独特地分解为 [Is2Sn(PH)]2 2 和 HF，而对 1 进行进一步的磷化反应则生成了相当稳定的双磷烷基锡烷 Is2Sn(PH2)2 3；后者与 Me3SnF 在玻璃壁上反应，生成了第一个过锡基磷镇阳离子五氟硅酸盐 [P(SnMe3)4]+SiF5¯ 4。

  DOI：

  10.1039/b308660g
• 作为产物：
  描述：

  hexakis(2,4,6-triisopropylphenyl)cyclotristannoxane 在 氢氟酸 作用下， 以 苯 为溶剂， 以90%的产率得到bis(2,4,6-triisopropylphenyl)difluorostannane
  参考文献：
  名称：

  具有形式锡-碳双键的稳定化合物：双（2,4,6-三异丙基苯基）（芴基）锡

  摘要：

  Bis(2,4,6-triisopropylphenyl)(fluorenylidene)stannene-diethyl ether (1a), a new stable compound with a formal tin-carbon double bond, has been synthesized by dehydrofluorination of the corresponding fluoro-stannane with tert-butyllithium; it has been characterized by NMR (delta(Sn-119) + 288 ppm, delta(C-13) + 133.85 ppm) and UV spectroscopy (lambda(max) 542 nm) and by electrophilic addition reactions to the tin-carbon unsaturation,

  DOI：

  10.1021/om00044a005

文献信息

• A Nearly Planar Stannene with a Reactive Tin–Carbon Double Bond
  作者：Abdoul Fatah、Rami El Ayoubi、Heinz Gornitzka、Henri Ranaivonjatovo、Jean Escudié

  DOI：10.1002/ejic.200701277

  日期：2008.4

  7-di-tert-butylfluorenylidenestannane, Tip2Sn=CR2, an isolable stannene that displays a deep-purple colour, was synthesized by dehydrofluorination of the corresponding fluorostannane by tert-butyllithium. It exhibits the shortest Sn=C distance [2.003(5) A] and the slightest twisting around this unsaturation (10°) among the known stannenes. Its reaction with benzaldehyde according to a [2+2] cycloaddition

  双（2,4,6-三异丙基苯基）-2,7-二-叔丁基芴基亚锡烷，Tip2Sn=CR2，一种可分离的锡烯，呈深紫色，是通过叔丁基锂对相应氟锡烷的脱氟化氢作用合成的。在已知的锡烯中，它表现出最短的 Sn=C 距离 [2.003(5) A] 和最轻微的围绕该不饱和度 (10°) 的扭曲。它与苯甲醛根据 [2+2] 环加成反应以及与 α-乙烯醛和酮（如巴豆醛和甲基乙烯基酮）通过 [2+4] 环加成反应以接近定量的产率进行。与丙酮发生烯反应。用苯甲醛获得的四元环 1,2-oxastannacyclobutane 与第二个苯甲醛分子进行扩环，得到六元环二氧杂环己烷。
• Synthesis and molecular structure of fluoro(triphosphanyl)silane and attempts to synthesize a silylidyne–phosphane
  作者：Matthias Driess、Christian Monsé、Dieter Bläser、Roland Boese、Holger Bornemann、Arvid Kuhn、Wolfram Sander

  DOI：10.1016/s0022-328x(03)00725-3

  日期：2003.11

  The synthesis, isolation, spectroscopic characterization (IR, multi-nuclear NMR) and single-crystal X-ray diffraction analysis of FSi(PH2)3 (1a), the first isolable fluorophosphanylsilane, is reported along with the gas phase decomposition of 1a, MeSi(PH2)3 (1b) and EtSi(PH2)3 (1c) under flash vacuum or pulsed pyrolysis conditions and matrix isolation of the products. The title compound is formed quantitatively

  的合成，分离，光谱表征（IR，多核NMR）和FSI（PH的单晶X射线衍射分析2）3（1A），所述第一可分离fluorophosphanylsilane，与气相分解一起报告1a中，MeSi（PH 2）3（1b）和EtSi（PH 2）3（1c）在快速真空或脉冲热解条件下进行分离，并分离出产物。通过四膦酰基硅烷Si（PH 2）4的PH 2 / F-配体交换反应定量形成标题化合物在苯为溶剂中，二氟二芳基锡烷的摩尔比为1：1的是2 SnF 2（Is = 2,4,6-三异丙基苯基）。由于1a无法通过分步缩合从溶剂中分离出来，因此它的分离是通过制备GC进行的。单晶1a（三斜晶系，P通过在衍射仪上在175 K上通过微型化区域熔化和聚焦红外辐射原位结晶，生长出适合X射线衍射分析的1 ^）晶体。有趣的是，Si原子在F-Si-P角为120.4（7），110.4（7），106.3（1）°且法线为Si-F（1.60
• ATTEMPTED SYNTHESIS OF A TRANSITION-METAL STANNAPHOSPHENE COMPLEX
  作者：A. Kandri Rodi、H. Ranaivonjatovo、J. Escudié、A. Kerbal

  DOI：10.1080/10426509708043555

  日期：1997.7.1

  Fluoro-, chloro- and bromostannylphosphines (8-10) complexed on phosphorus by tungsten pentacarbonyl have been synthesized by reaction between lithium mesityl(tungsten pentacarbonyl)phosphide 4 and the corresponding dihalo(diisityl)tin (isityl: 2,4,6-triisopropylphenyl). Reaction of 8 with tert-butyllithium afforded the stable lithium fluorostannylphosphide 11. Addition of Me3SiCl or MgBr2 to 11 gave the corresponding chloro- and bromoderivatives 14 and 15. Similar compounds 16 and 17 were obtained from 9 and 10 and DBU. 11, 14, 15, 16 and 17 present a large (1)J(SnP) coupling constant (2099.0 to 2151.4 Hz) indicating a partial Sn-P double bond.
• A Stable Distannirane
  作者：Lise Baiget、Henri Ranaivonjatovo、Jean Escudié、Heinz Gornitzka

  DOI：10.1021/ja0464239

  日期：2004.9.1

  The first three-membered ring compound containing two tin and one carbon atoms, 1,1,2,2-tetra(2,4,6-triisopropylphenyl)-3-fluorenylidene-1,2-distannirane, has been synthesized in a two-step procedure from the 9-[bis(2,4,6-triisopropylphenyl)fluorostannyl]chloromethylenefluorene.
• First characterization of a compound with a tin–germanium double bond: the dimesityl(diisitylstanna)germene (Is)₂SnGe(Mes)₂
  作者：Marie-Anne Chaubon、Jean Escudié、Henri Ranaivonjatovo、Jacques Satgé

  DOI：10.1039/cc9960002621

  日期：——

  The dimesityl(diisitylstanna)germene 4 [isityl (Is) = 2,4,6-triisopropylphenyl] is synthesized by dehydrofluorination of the corresponding (fluorostannyl)germane 1 by tert-butyl-lithium at low temperature; its structure is evidenced at -20 degrees C by Sn-119 NMR spectroscopy (delta + 360), by addition of water and methanol to the tin-germanium double bond and by a [2 + 2] cycloaddition with benzaldehyde; warming the stannagermene 4 to room temperature affords the dimesityl(tetraisityldistanna)germirane 8.