1,2-bis(dicyclohexylphosphino)ethanenickel(0) | 141974-61-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: 1,2-bis(dicyclohexylphosphino)ethanenickel(0)
• 英文别名: Dicyclohexyl(2-dicyclohexylphosphanylethyl)phosphane;nickel；dicyclohexyl(2-dicyclohexylphosphanylethyl)phosphane;nickel
• CAS: 141974-61-0
• 化学式: C₂₆H₄₈P₂*Ni
• 分子量: 481.305
• InChiKey: DVXZVPVCJNASRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.28
• 重原子数：
  29
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-bis(dicyclohexylphosphino)ethanenickel(0) 、 1,2-双(二环己基磷基)-乙烷 以 甲苯 为溶剂， 生成 [(dcpe)2Ni]
  参考文献：
  名称：

  New nickel(O) complexes with bulky diphosphine ligands

  摘要：

  The synthesis and characterization of new complexes of formula Ni(dp), Ni(dp)C7H8 (dp = 1, 2-bis-dicyclohexylphosphino)ethane [dcpe]; 1,3-bis(dicyclohexylphosphino)propane [dcpp]; 1,4-bis(dicyclohexylphosphino) butane [dcpb]), Ni2(dcpe)3, Ni2(dcpb)3, Ni(dcpe)2 and Ni(depe)2 (depe = 1,2-bis(diethylphosphino)-ethane) are described. The electronic spectra of these complexes are discussed.

  DOI：

  10.1016/s0020-1693(00)80757-4
• 作为产物：
  描述：

  1,2-双(二环己基膦)乙烷氯化镍 在 sodium 作用下， 以 甲苯 为溶剂， 以70%的产率得到1,2-bis(dicyclohexylphosphino)ethanenickel(0)
  参考文献：
  名称：

  New nickel(O) complexes with bulky diphosphine ligands

  摘要：

  The synthesis and characterization of new complexes of formula Ni(dp), Ni(dp)C7H8 (dp = 1, 2-bis-dicyclohexylphosphino)ethane [dcpe]; 1,3-bis(dicyclohexylphosphino)propane [dcpp]; 1,4-bis(dicyclohexylphosphino) butane [dcpb]), Ni2(dcpe)3, Ni2(dcpb)3, Ni(dcpe)2 and Ni(depe)2 (depe = 1,2-bis(diethylphosphino)-ethane) are described. The electronic spectra of these complexes are discussed.

  DOI：

  10.1016/s0020-1693(00)80757-4

文献信息

• Reactivity of nickel (II) diphosphine complexes towards alkoxides: a new route to the synthesis of nickel(0) compounds through nickel(II) alkoxides
  作者：Adriano Sacco、Pietro Mastrorilli

  DOI：10.1039/dt9940002761

  日期：——

  and aldehyde (or acetone when R = Pri) in 1 :1 :1 ratio, showing the peculiar reducing effect of alkoxide promoted by the chelating property of the phosphorus ligand. The reaction of NaOMe with [Ni(dcpe)Cl2][dcpe = 1,2-bis(dicyclohexylphosphino)-ethane] afforded mainly [Ni2(dcpe)3] when carried out in the absence of free diphosphine, and [Ni(dcpe)2] in the presence of free diphosphine. The reaction always

  [Ni（L–L）Cl 2 ] [L–L = Ph 2 P（CH 2）n PPh 2，n = 2（dppe）或3（dppp）]与NaOR的反应（R = Me，Et或Pr i）在氮气气氛下以1：1：1的比例提供[Ni（L–L）2 ]，Ni（OR）2和醛（或丙酮（当R = Pr i时）），显示出由磷配体的螯合性能。NaOMe与[Ni（dcpe）Cl 2 ] [dcpe = 1,2-双（二环己基膦基）乙烷]的反应，在不存在游离二膦的情况下，主要得到[Ni 2（dcpe）3 ]，和[Ni （dcpe）2 ]在游离二膦存在下。在一氧化碳气氛下进行反应时，总是生成镍（ 0）物种[Ni（L–L）（CO） 2 ]。通过在低温下记录反应溶液的31 P NMR光谱证明了不稳定的烷氧基（二膦基）镍（ Ⅱ）配合物的中间形成。仅在[Ni（dcpe）Cl 2 ]与NaOMe反应的情况下，有可能分离出[Ni（dcpe）（OMe）
• Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities
  作者：Pietro Mastrorilli、Giovanni Moro、Cosimo Francesco Nobile、Mario Latronico

  DOI：10.1016/s0020-1693(00)80758-6

  日期：1992.2

  The reaction between Ni(O) complexes (dp) (dp = 1,2-bis(dicyclohexylphosphino)ethane, 1,3-bis(dicyclohexylphosphino) propane, 1,4-bis(dicyclohexylphosphino)butane; dcpe, dcpp, dcpb, respectively) and carbon dioxide is described. The influence of the P-Ni-P bond angle on the stability of the corresponding adducts is discussed. The reactions of Ni(dcpp)CO2 and Ni(dcpb)CO2 with dioxygen are also described.
• New nickel(O) complexes with bulky diphosphine ligands
  作者：Pietro Mastrorilli、Giovanni Moro、Cosimo Francesco Nobile、Mario Latronico

  DOI：10.1016/s0020-1693(00)80757-4

  日期：1992.2

  The synthesis and characterization of new complexes of formula Ni(dp), Ni(dp)C7H8 (dp = 1, 2-bis-dicyclohexylphosphino)ethane [dcpe]; 1,3-bis(dicyclohexylphosphino)propane [dcpp]; 1,4-bis(dicyclohexylphosphino) butane [dcpb]), Ni2(dcpe)3, Ni2(dcpb)3, Ni(dcpe)2 and Ni(depe)2 (depe = 1,2-bis(diethylphosphino)-ethane) are described. The electronic spectra of these complexes are discussed.