tetrakis(phenylethinyl)germane | 27258-70-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrakis(phenylethinyl)germane
• 英文别名: tetrakis(phenylethynyl)germane；Tetra-phenylethinyl-german；Tetrakis(2-phenylethynyl)germane
• CAS: 27258-70-4
• 化学式: C₃₂H₂₀Ge
• 分子量: 477.101
• InChiKey: TUHGTAKKBYVMGQ-UHFFFAOYSA-N

物化性质

• 熔点：
  186 °C(Solv: pentane (109-66-0))
• 沸点：
  573.1±33.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  33
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(bis(trimethylsilyl)methyl)aluminium hydride 、 tetrakis(phenylethinyl)germane 以 甲苯 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Facile Synthesis of an Unsaturated Spiro Germane by Hydroalumination and Intramolecular 1,1-Carbalumination

  摘要：

  Treatment of the tetraethynylgermanium compound Ge(C CC6H5)(4) 4 with 2 equiv of H-Al-[CH(SiMe3)(2)](2) yielded the addition product Ge(C CC6H5)(2)[C{AIR(2)}=C(H)C6H5](2) (5, R = CH-(SiMe3)(2)) by reduction of two of its C C triple bonds. Heating of 5 to 260 degrees C for 10 min gave a unique rearrangement reaction which via intramolecular 1,1-carbalumination afforded the spiro germane 6 (a 3,7-bis[1-phenylmeth-(Z)-ylidene]-4-germaspiro[3,3]hepta-1,5-diene derivative), The molecular structure of 6 comprises two unsaturated 1-germacyclobut-2-ene heterocycles with a joint germanium atom and two exocyclic C=C double bonds.

  DOI：

  10.1021/om100359k
• 作为产物：
  描述：

  potassium phenylacetylide 、 四氯化锗 以 乙醚 为溶剂， 以64%的产率得到tetrakis(phenylethinyl)germane
  参考文献：
  名称：

  Koester, Roland; Seidel, Guenter; Klopp, Ingo, Chemische Berichte, 1993, vol. 126, # 6, p. 1385 - 1396

  摘要：

  DOI：

文献信息

• Synthesis of tri-and tetraalkynylgermanes
  作者：A. A. Andreev、V. V. Konshin、N. A. Vinokurov、N. V. Komarov

  DOI：10.1007/s11172-006-0434-5

  日期：2006.8

  A straightforward synthesis of tetra-and trialkynylgermanes by reactions of compounds containing Ge-N or Ge-Cl bonds with alk-1-ynes was proposed. Reactions of appropriate amino-or halogermanes with alk-1-ynes were effective only in the presence of an equivalent amount of zinc dihalide.

  通过含有 Ge-N 或 Ge-Cl 键的化合物与烷基-1-炔的反应，提出了一种直接合成四炔基锗和三炔基锗的方法。只有在等量的二卤化锌存在下，适当的氨基或卤代锗与烷-1-炔的反应才有效。
• A New Variation of the Sila-Sonogashira Reaction
  作者：E. S. Spesivaya、I. A. Lupanova、Dz. N. Konshina、I. V. Sukhno、V. V. Konshin

  DOI：10.1134/s1070363223060087

  日期：2023.6
• Koester, Roland; Seidel, Guenter; Klopp, Ingo, Chemische Berichte, 1993, vol. 126, # 6, p. 1385 - 1396
  作者：Koester, Roland、Seidel, Guenter、Klopp, Ingo、Krueger, Carl、Kehr, Gerald、et al.

  DOI：——

  日期：——
• Facile Synthesis of an Unsaturated Spiro Germane by Hydroalumination and Intramolecular 1,1-Carbalumination
  作者：Werner Uhl、Martina Rohling、Ernst-Ulrich Würthwein、Nugzar Ghavtadze、Klaus Bergander

  DOI：10.1021/om100359k

  日期：2010.11.8

  Treatment of the tetraethynylgermanium compound Ge(C CC6H5)(4) 4 with 2 equiv of H-Al-[CH(SiMe3)(2)](2) yielded the addition product Ge(C CC6H5)(2)[CAIR(2)}=C(H)C6H5](2) (5, R = CH-(SiMe3)(2)) by reduction of two of its C C triple bonds. Heating of 5 to 260 degrees C for 10 min gave a unique rearrangement reaction which via intramolecular 1,1-carbalumination afforded the spiro germane 6 (a 3,7-bis[1-phenylmeth-(Z)-ylidene]-4-germaspiro[3,3]hepta-1,5-diene derivative), The molecular structure of 6 comprises two unsaturated 1-germacyclobut-2-ene heterocycles with a joint germanium atom and two exocyclic C=C double bonds.