monoperoxyadipic acid | 77155-29-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: monoperoxyadipic acid
• 英文别名: monoperadipic acxid；monoperadipic acid；6-Hydroperoxy-6-oxohexanoic acid
• CAS: 77155-29-4
• 化学式: C₆H₁₀O₅
• 分子量: 162.142
• InChiKey: KCAZSAYYICOMMG-UHFFFAOYSA-N

物化性质

• 沸点：
  349.4±44.0 °C(Predicted)
• 密度：
  1.316±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  monoperoxyadipic acid 、 2-羟基环己酮二聚物 生成 6-氧代己酸
  参考文献：
  名称：

  Freidin, B. G.; Perkel', A. L., Journal of applied chemistry of the USSR, 1981, vol. <2> 54, # 12, p. 2418 - 2422

  摘要：

  DOI：
• 作为产物：
  描述：

  2-羟基环己酮二聚物 在 偶氮二异丁腈 、 氧气 作用下， 以 氯苯 为溶剂， 生成 己二酸 、 己二酸酐 、 1,2-环己二酮 、 monoperoxyadipic acid 、 2-hydroxy-2-hydroperoxycyclohexanone 、 mono-(2-oxocyclohexyl) adipate
  参考文献：
  名称：

  Kinetics of the liquid-phase oxidation of 2-hydroxycyclohexanone

  摘要：

  The kinetics of oxygen uptake in the azobisisobutyronitrile-initiated oxidation of 2-hydroxycy-clohexanone (RCH(OH)C(O)R) at 323 K has been investigated (chlorobenzene solvent, [RCH(OH)C(O)R] = 0.15-1.30 mol/L, initiation rate of w (i) = 0.016-0.473 mol L-1 s(-1)). The effective oxidizability parameter k (p, eff)(2k (t,eff))(-0.5) has been determined by solving the inverse kinetic problem using the entire data array obtained while varying [RCH(OH)C(O)R] and w (i). The rate constants of chain propagation and termination and the equilibrium constant of the addition of the hydroxyperoxyl radical to the ketoalcohol have been derived from the dependence of the oxidizability parameter on the substrate concentration. The rate constant of bimolecular chain initiation has been calculated to be k (0) = 9.7 x 10(-7) L mol(-1) s(-1). The ratio of the rate constants of quadratic-law peroxyl radical recombination reactions without and with chain termination (k (eff)'/k (t,eff)') increases with increasing [RCH(OH)C(O)R], passes through a maximum at a substrate concentration of 0.8 mol/L, and then falls off. It is demonstrated that this effect is due to the variation of the proportions of the hydroperoxyl and organic (1-hydroxy-2-oxocyclohexylperoxyl or 1,2-dihydroxy-1-cyclo-hexylperoxyl) radicals in the reaction medium.

  DOI：

  10.1134/s0023158413030026

文献信息

• Controlled release laundry bleach product
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0070066A1

  公开（公告）日：1983-01-19

  A hydrophilic or hydrotropic peroxyacid laundry bleach plus a surfactant bleach release-delaying agent, contained inside a pouch, bag or substrate, provides a controlled bleach release laundry product.

  亲水性或亲水性过氧乙酸洗衣漂白剂加上表面活性剂漂白释放延缓剂，装在小袋、袋子或基材中，可提供一种可控漂白释放的洗衣产品。
• Thermoplastic starch composition derivatives from agricultural byproducts
  申请人：TEXCHEM POLYMERS SDN BHD

  公开号：US10196490B2

  公开（公告）日：2019-02-05

  A thermoplastic starch composition acquired from compounding a mixture comprises starch-containing agricultural waste in 45 to 70% by weight of total composition that the agricultural waste contains starch content less than 50% in dry weight; thermoplastic synthetic polymer in 25 to 50% by weight of total composition; plasticizer in 1 to 10% by weight of total composition; and coupling agent in 1 to 5% by weight of total composition; wherein the compounding is performed at a first temperature which is higher than room temperature.

  一种由混合物复配而成的热塑性淀粉组合物，包括含淀粉的农业废弃物，占总组合物重量的 45% 至 70%，其中农业废弃物的淀粉含量低于干重的 50%；热塑性合成聚合物，占总组合物重量的 25% 至 50%；增塑剂，占总组合物重量的 1% 至 10%；偶联剂，占总组合物重量的 1% 至 5%；其中复配是在高于室温的第一温度下进行的。
• Two solvent antimicrobial compositions and methods employing them
  申请人：——

  公开号：US20020168422A1

  公开（公告）日：2002-11-14

  The present invention relates to two solvent antimicrobial compositions and methods employing these two solvent compositions. The two solvent compositions typically contain a second solvent that is not or is only sparingly soluble in a diluting solvent. The two solvent composition can form a clear single-phase solution. The two solvent antimicrobial compositions can reduce the population of microbes on various surfaces such as facilities, containers, or equipment found in food, beverage, or pharmaceutical industries at temperatures between about −70° C. to about 100° C.

  本发明涉及双溶剂抗菌组合物和使用这些双溶剂组合物的方法。双溶剂组合物通常含有不溶于或仅少量溶于稀释溶剂的第二种溶剂。双溶剂组合物可以形成透明的单相溶液。双溶剂抗菌组合物可以减少各种表面上的微生物数量，如食品、饮料或制药行业中的设施、容器或设备，使用温度约为 -70°C 至 100°C。
• In situ mono-or diester dicarboxylate compositions
  申请人：——

  公开号：US20030021853A1

  公开（公告）日：2003-01-30

  The present invention relates to in situ compositions of mono- or diester dicarboxylates, methods employing these in situ compositions, and methods of making these in situ compositions. More particularly, the invention relates to mono- or diester dicarboxylate antimicrobial compositions that can reduce the population of microbes on various surfaces such as facilities, containers, or equipment found in food, beverage, or pharmaceutical processing, or in food, beverage, or pharmaceutical industries, at temperatures between about −70° C. to about 100° C.

  本发明涉及二羧酸单酯或二酯的原位组合物、使用这些原位组合物的方法以及制造这些原位组合物的方法。更具体地说，本发明涉及二羧酸单酯或二酯抗菌组合物，这些组合物可以在约 -70°C 至约 100°C 的温度下减少各种表面上的微生物数量，例如食品、饮料或药品加工中或食品、饮料或制药工业中的设施、容器或设备。
• Peroxygen compositions and methods for carpet or upholstery cleaning or sanitizing
  申请人：——

  公开号：US20030070692A1

  公开（公告）日：2003-04-17

  The present invention relates to methods and compositions for cleaning or sanitizing carpet or upholstery. Powder, other solid, or agglomerate compositions include active oxygen compound, surfactant, and builder. The methods of cleaning or sanitizing carpet or upholstery include applying to the carpet or upholstery such a solid (e.g., powder) or agglomerate composition or a use solution of one of these compositions.

  本发明涉及清洁或消毒地毯或室内装潢的方法和组合物。粉末、其他固体或团块组合物包括活性氧化合物、表面活性剂和增效剂。清洁或消毒地毯或室内装潢的方法包括向地毯或室内装潢施用这种固体（如粉末）或团块组合物或这些组合物之一的使用溶液。