4-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2,2-diphenyl-1,3,2,4-dithiastannaboretane | 180971-15-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2,2-diphenyl-1,3,2,4-dithiastannaboretane
• CAS: 180971-15-7
• 化学式: C₃₉H₆₉BS₂Si₆Sn
• 分子量: 900.143
• InChiKey: ZVBJBUYPQACLDB-UHFFFAOYSA-N

物化性质

• 沸点：
  673.0±65.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.63
• 重原子数：
  49
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2,2-diphenyl-1,3,2,4-dithiastannaboretane 在 二苯硫醚 作用下， 以 苯 为溶剂， 生成 2,4-bis(2,4,6-tri-t-butylphenyl)-1,3,2,4-dioxadiboretane
  参考文献：
  名称：

  A novel approach to an oxoborane and its Lewis base complex

  摘要：

  Reaction of dimethyl sulfoxide (DMSO) with 1,3,2,4-dithiastannaboretane 3 bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt), an the baron atom gave an oxoborane (Tbt-B=O; 4), which formed a complex with DMSO stable in solution. The formation of the complex was confirmed by B-11 NMR and a [3+2] cycloaddition reaction with 2,4,6-tri-t-butylbenzonitrile oxide. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00929-5
• 作为产物：
  描述：

  二苯基二溴锡烷 、 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dimercaptoborane 在 正丁基锂 作用下， 生成 4-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2,2-diphenyl-1,3,2,4-dithiastannaboretane
  参考文献：
  名称：

  Formation of Oxoborane and Thioxoborane from a Dithiastannaboretane Derivative

  摘要：

  Reaction with an oxygen-donating reagent such as DMSO and thermolysis of a 1,3,2,4-dithiastannaboretane derivative bearing 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) group led to the formation of novel boron-group 16 element double bond compounds, oxoborane (Tbt-B=O) and thioxoborane (Tbt-B=S). The oxoborane and thioxoborane underwent cycloaddition reactions to give the corresponding adducts in good yields.

  DOI：

  10.1080/10426509708545677

文献信息

• Synthesis and Structures of Novel Dithiaboretanes Containing a Group 4, 14, or 15 Element
  作者：Mitsuhiro Ito、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1021/om970328+

  日期：1997.9.1

  aryltrihydroborate bearing the 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) group, followed by treatment with electrophiles such as Cp2TiCl2, Mes2GeBr2, Ph2SnCl2, and TbtSbBr2 resulted in the isolation of novel four-membered boracycles, 1,3,2,4-dithiaboratitanetane, 1,3,2,4-dithiagermaboretane, 1,3,2,4-dithiastannaboretane, and 1,3,2,4-dithiastibaboretane as stable crystals, respectively. The introduction of

  二巯基硼烷TbtB（SH）2（1）的二价化反应是通过硫化相应的拥挤的带有2,4,6-三[双（三（三甲基甲硅烷基）甲基]苯基] TbtB的芳基三氢硼酸锂合成的，然后进行处理具有亲电试剂，例如Cp 2 TiCl 2，Mes 2 GeBr 2，Ph 2 SnCl 2和TbtSbBr 2导致分离出新颖的四元硼环，1,3,2,4-二硫杂硼烷，1,3,2,4-二硫杂硼烷，1,3,2,4-二硫杂硼烷和1,3,2,4-二硫杂巴比妥烷分别为稳定的晶体。将C，Si或P原子引入四元环并不成功。通过X射线晶体学分析确定新获得的四元硼环的结构。四元环几乎是平面的并且垂直于Tbt基团的芳族环。发现四元环中硼原子周围的几何形状几乎是三角形平面，并且环中的SB-S角不小于90°，​​表明硼和硫原子周围的几何形状为与1没有太大不同 尽管被嵌入到环网系统中。
• Formation and reactions of a thioxoborane, a novel boron-sulfur double-bond compound
  作者：Norihiro Tokitoh、Mitsuhiro Ito、Renji Okazaki

  DOI：10.1016/0040-4039(96)01039-8

  日期：1996.7

  Thermolysis of an overcrowded tin-containing four-membered boracycle, 1,3,2-dithiastanna-boretane derivative 6, bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsiyl)methyl]-phenyl (Tbt), on the boron atom in the presence of several 1,3-dienes in toluene at 120 °C gave the corresponding diene adducts of an initially formed thioxoborane (Tbt-B=S; 7) together with a trimer of diphenylstannanethione

  过度拥挤的含锡四元环硼烷1,3,2-二噻吩并-硼烷烷衍生物6的热解，该衍生物带有一个非常庞大的芳基基团2,4,6-三[双（三甲基甲硅烷基）甲基]-苯基（Tbt） ，在硼原子上，在120°C下于甲苯中存在数个1,3-二烯时，给出了最初形成的thioxoborane（Tbt-B = S; 7）与三苯基二锡锡内酯8的三聚体的相应二烯加合物。还描述了将二烯加合物逆向[4 + 2]环加成到硫代氧杂硼烷7中。
• Cyclic Chalcogenides Containing Group 13–15 Elements
  作者：Renji Okazaki

  DOI：10.1080/10426500108546529

  日期：2001.1.1

  polychalcogenides containing a variety of heavier main group elements of groups 13, 14, and 15 as ring members have been synthesized as stable crystalline compounds by taking advantage of an effective steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]-phenyl (denoted as Tbt in this article). The molecular structures of tetrachalcogenametallolanes of group 14 elements, Tbt(R)ME4 (M = Si

  通过利用有效的空间保护基团 2,4,6-三[双(三甲基甲硅烷基)甲基]-苯基（在本文中表示为 Tbt）。X 分析了 14 族元素的四硫属元素金属烷、Tbt(R)ME4（M = Si、Ge、Sn 和 Pb；E = S、Se）和一些含有锑或硼原子作为环成员的多硫化物的分子结构射线晶体学来阐明这些新型环系统的骨架特征。
• Formation of Oxoborane and Thioxoborane from a Dithiastannaboretane Derivative
  作者：Mitsuhiro Ito、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1080/10426509708545677

  日期：1997.1.1

  Reaction with an oxygen-donating reagent such as DMSO and thermolysis of a 1,3,2,4-dithiastannaboretane derivative bearing 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) group led to the formation of novel boron-group 16 element double bond compounds, oxoborane (Tbt-B=O) and thioxoborane (Tbt-B=S). The oxoborane and thioxoborane underwent cycloaddition reactions to give the corresponding adducts in good yields.
• A novel approach to an oxoborane and its Lewis base complex
  作者：Mitsuhiro Ito、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1016/s0040-4039(97)00929-5

  日期：1997.6

  Reaction of dimethyl sulfoxide (DMSO) with 1,3,2,4-dithiastannaboretane 3 bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt), an the baron atom gave an oxoborane (Tbt-B=O; 4), which formed a complex with DMSO stable in solution. The formation of the complex was confirmed by B-11 NMR and a [3+2] cycloaddition reaction with 2,4,6-tri-t-butylbenzonitrile oxide. (C) 1997 Elsevier Science Ltd.