N-(2,6-dimethylphenyl)-3-phenyl-1,2,3a,8b-tetrahydroindeno[2,1-b]phosphol-4-imine | 253345-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: N-(2,6-dimethylphenyl)-3-phenyl-1,2,3a,8b-tetrahydroindeno[2,1-b]phosphol-4-imine
• CAS: 253345-22-1
• 化学式: C₂₅H₂₄NP
• 分子量: 369.446
• InChiKey: GPRIHAGPSUQZRQ-UHFFFAOYSA-N

物化性质

• 沸点：
  517.2±50.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(2,6-dimethylphenyl)-3-phenyl-1,2,3a,8b-tetrahydroindeno[2,1-b]phosphol-4-imine 以 二氯甲烷 为溶剂， 生成 (8-((2,6-dimethylphenyl)imino)-1-phenyl-3,3a,8,8a-tetrahydro-1l5-indeno[2,1-b]phosphol-1(2H)-yl)(((2,6-dimethylphenyl)imino)methyl)palladium(IV) chloride
  参考文献：
  名称：

  Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions:  From Monomers to Dendrimers

  摘要：

  Palladium complexes of a variety of beta- and gamma-iminophosphines have been prepared and characterized by X-ray diffraction studies. Their properties as catalyst for three different Stille coupling reactions have been investigated and compared to catalytic performances of a phosphorus-containing dendrimer incorporating analogous gamma-iminophosphine palladium complexes on the surface.

  DOI：

  10.1021/om011076m

文献信息

• Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions:  From Monomers to Dendrimers
  作者：Marek Koprowski、Rosa-Maria Sebastián、Valérie Maraval、Maria Zablocka、Victorio Cadierno、Bruno Donnadieu、Alain Igau、Anne-Marie Caminade、Jean-Pierre Majoral

  DOI：10.1021/om011076m

  日期：2002.10.1

  Palladium complexes of a variety of beta- and gamma-iminophosphines have been prepared and characterized by X-ray diffraction studies. Their properties as catalyst for three different Stille coupling reactions have been investigated and compared to catalytic performances of a phosphorus-containing dendrimer incorporating analogous gamma-iminophosphine palladium complexes on the surface.