[2.2]paracyclophane-4-carboxylic acid pentafluorophenyl ester | 374668-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: [2.2]paracyclophane-4-carboxylic acid pentafluorophenyl ester
• 英文别名: (2,3,4,5,6-Pentafluorophenyl) tricyclo[8.2.2.24,7]hexadeca-1(13),4,6,10(14),11,15-hexaene-5-carboxylate；(2,3,4,5,6-pentafluorophenyl) tricyclo[8.2.2.24,7]hexadeca-1(13),4,6,10(14),11,15-hexaene-5-carboxylate
• CAS: 374668-22-1
• 化学式: C₂₃H₁₅F₅O₂
• 分子量: 418.363
• InChiKey: WJBUBQYUDKRYQE-UHFFFAOYSA-N

物化性质

• 沸点：
  544.5±50.0 °C(Predicted)
• 密度：
  1.367±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  对二甲苯二聚体 在 吡啶 、 氢氧化钾 、 三氯化铝 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 为溶剂， 反应 16.5h， 生成 [2.2]paracyclophane-4-carboxylic acid pentafluorophenyl ester
  参考文献：
  名称：

  A New Method toward Microengineered Surfaces Based on Reactive Coating

  摘要：

  By using chemical vapor deposition (CVD) a range of substrates can be coated with a highly reactive polymer containing pentafluorophenol ester groups. A biotin-modified pattern is generated on the substrate by microcontact printing; such a pattern interacts specifically with fluorescein-conjugated streptavidin and thereby the pattern becomes observable with fluorescence microscopy.

  DOI：

  10.1002/1521-3773(20010903)40:17<3166::aid-anie3166>3.0.co;2-#

文献信息

• MULTIFUNCTIONAL CVD COATINGS
  申请人：Lahann Joerg

  公开号：US20080269456A1

  公开（公告）日：2008-10-30

  Multifunctional reactive polymers created by chemical vapor deposition (CVD) and methods of making such polymeric systems are provided. Such polymers provide multifunctional surfaces which can present two or more different molecules (e.g. biological ligands) in controlled ratios. Polymers may include compositional gradients allowing attached ligands to be presented as continuous gradients across a surface. The polymer compositions are modularly designable and applicable to a wider range of applications, including biomedical devices and diagnostic systems.
• US8399047B2
  申请人：——

  公开号：US8399047B2

  公开（公告）日：2013-03-19
• A New Method toward Microengineered Surfaces Based on Reactive Coating
  作者：Jörg Lahann、Insung S. Choi、Jinwook Lee、Klavs F. Jensen、Robert Langer

  DOI：10.1002/1521-3773(20010903)40:17<3166::aid-anie3166>3.0.co;2-#

  日期：2001.9.3

  By using chemical vapor deposition (CVD) a range of substrates can be coated with a highly reactive polymer containing pentafluorophenol ester groups. A biotin-modified pattern is generated on the substrate by microcontact printing; such a pattern interacts specifically with fluorescein-conjugated streptavidin and thereby the pattern becomes observable with fluorescence microscopy.