6-Hydrazino-4-methyl-2-phenyl-pyrimidin | 98296-26-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 6-Hydrazino-4-methyl-2-phenyl-pyrimidin
• 英文别名: 4-Hydrazinyl-6-methyl-2-phenylpyrimidine；(6-methyl-2-phenylpyrimidin-4-yl)hydrazine
• CAS: 98296-26-5
• 化学式: C₁₁H₁₂N₄
• 分子量: 200.243
• InChiKey: OHGUDCJFELKUIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  63.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-Hydrazino-4-methyl-2-phenyl-pyrimidin 在 硫酸 、 溶剂黄146 、 sodium nitrite 作用下， 以 乙醇 、 水 为溶剂， 反应 20.0h， 生成 4-甲基-2-苯基咪唑
  参考文献：
  名称：

  Giammanco, Lorenzo; Invidiata, Francesco Paolo, Heterocycles, 1985, vol. 23, # 6, p. 1459 - 1464

  摘要：

  DOI：
• 作为产物：
  描述：

  4-氯-6-甲基-2-苯基嘧啶 在 肼 作用下， 以 乙醇 为溶剂， 反应 4.0h， 以80%的产率得到6-Hydrazino-4-methyl-2-phenyl-pyrimidin
  参考文献：
  名称：

  Giammanco, Lorenzo; Invidiata, Francesco Paolo, Heterocycles, 1985, vol. 23, # 6, p. 1459 - 1464

  摘要：

  DOI：

文献信息

• Three differently coloured concomitant polymorphs: synthesis, structure and packing analysis of (4-(3′,5′-dimethyl-1<i>H</i>-pyrazol-1′-yl)-6-methyl-2-phenylpyrimidine)dichlorocopper(II)
  作者：Eugenia V. Peresypkina、Mark B. Bushuev、Alexander V. Virovets、Victor P. Krivopalov、Ludmila G. Lavrenova、Stanislav V. Larionov

  DOI：10.1107/s010876810403294x

  日期：2005.4.1

  A novel pyrazolylpyrimidine ligand (L) and its complex CuLCl₂ were prepared and structurally characterized. The simultaneous crystallization of three polymorphs of CuLCl₂, green (G), emerald green (EG) and orange (O), was discovered. The molecular structures vary only slightly between the three forms. The Cu atom forms four coordinate bonds with the two N and two Cl atoms, and a shortened Cu...H contact with an H atom of the phenyl ring in L. The structural difference between polymorphs was analyzed with the boundary surfaces of molecular Voronoi–Dirichlet polyhedra. The difference in colour of the polymorphs is likely to be due to the different π–π stackings. There is no stacking in the G modification, but EG and O polymorphs demonstrate face-to-face and slipped stacking, resulting in dimers and infinite chains, respectively. The EG and O polymorphs are packed according to the hexagonal close-packing motif, while in G no special topology is found.

  制备了一种新型吡唑嘧啶配体（L）及其复合物 CuLCl2，并对其进行了结构表征。发现了 CuLCl2 的三种多晶型：绿色（G）、翠绿色（EG）和橙色（O）。三种形态的分子结构仅略有不同。Cu 原子与两个 N 原子和两个 Cl 原子形成四个坐标键，并与 L 中苯环的一个 H 原子形成缩短的 Cu...H 接触。多晶体的颜色差异可能是由于不同的 π-π 堆叠造成的。G 型多晶体没有堆叠，但 EG 和 O 型多晶体出现了面对面堆叠和滑动堆叠，分别形成了二聚体和无限链。EG 和 O 多晶体按照六边形紧密堆积模式堆积，而 G 多晶体则没有发现特殊的拓扑结构。
• Azo compound containing metal and optical recording medium using the compound
  申请人：——

  公开号：US20020015915A1

  公开（公告）日：2002-02-07

  An object of the present invention is to provide an optical recording medium that is excellent in recording and reading-out characteristics in the case of using a shortwave semiconductor laser and is good in light resistance and durability. A metal-containing azo compound comprising an azo compound represented by the following general formula [I] and at least one metal salt: General formula [I] 1 wherein X is a hydroxyl group, a carboxyl group, a sufonamide group, a carbonylamide group or an amino group, R 1 and R 2 are independently a hydrogen atom, a substituted or unsubstituted and linear or branched alkyl group, a substituted or unsubstituted and unsaturated hydrocarbon, a substituted or unsubstituted aromatic ring, or an alkoxy group, each of R 3 , R 4 , R 5 , R 6 , R 7 and R 8 is a hydrogen atom, a linear or branched alkyl group which may have one or more substituents, a linear or branched and unsaturated hydrocarbon which may have one or more substituents, a substituted or unsubstituted aromatic ring, an alkoxy group, a halogen atom or a cyano group, and a combination of R 1 and R 2 or a combination of R 6 and R 7 may form a ring through a connecting group.

  本发明的目的是提供一种光学记录介质，在使用短波半导体激光器的情况下，该介质具有优异的记录和读出特性，并且具有良好的耐光性和耐久性。一种含金属的偶氮化合物，由以下通式[I]代表的偶氮化合物和至少一种金属盐组成： 通式[I&rsqb； 1 其中 X 是羟基、羧基、磺酰胺基、羰基酰胺基或氨基，R 1 和 R 2 独立地为氢原子、取代或未取代的直链或支链烷基、取代或未取代的不饱和烃基、取代或未取代的芳香环或烷氧基，每个 R 3 , R 4 , R 5 , R 6 , R 7 和 R 8 是氢原子、可带有一个或多个取代基的直链或支链烷基、可带有一个或多个取代基的直链或支链不饱和烃、取代或未取代的芳香环、烷氧基、卤素原子或氰基，以及 R 1、R 7 和 R 8 的组合。 1 和 R 2 或 R 6 和 R 7 可通过连接基团形成一个环。
• GIAMMANCO, L.;INVIDIATA, F. P., HETEROCYCLES, 1985, 23, N 6, 1459-1464
  作者：GIAMMANCO, L.、INVIDIATA, F. P.

  DOI：——

  日期：——
• Giammanco, Lorenzo; Invidiata, Francesco Paolo, Heterocycles, 1985, vol. 23, # 6, p. 1459 - 1464
  作者：Giammanco, Lorenzo、Invidiata, Francesco Paolo

  DOI：——

  日期：——