tris(2-(ethylamino)ethyl)amine | 124764-04-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(2-(ethylamino)ethyl)amine
• 英文别名: tris(2-ethylaminoethyl)amine；tris(ethylaminoethyl)amine；Et3TREN；tris-(2-ethylamino-ethyl)-amine；Tris-(2-aethylamino-aethyl)-amin；N-ethyl-N',N'-bis[2-(ethylamino)ethyl]ethane-1,2-diamine
• CAS: 124764-04-1
• 化学式: C₁₂H₃₀N₄
• 分子量: 230.397
• InChiKey: VHDZLFZNPPJLJC-UHFFFAOYSA-N

物化性质

• 沸点：
  85 °C(Press: 0.5 Torr)
• 密度：
  0.885±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  39.3
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris(2-(ethylamino)ethyl)amine 在 盐酸 、 ammonium hydroxide 、 sodium carbonate 、 diborane(6) 作用下， 以 乙腈 为溶剂， 反应 122.0h， 生成 7,10-Dimethyl-4,13-diethyl-1-<2-(ethylamino)ethyl>-1,4,7,10,13-pentaazacyclopentadecane
  参考文献：
  名称：

  Preparation of triaza-, tetraaza- and peraza-crown compounds containing aminoalkyl side groups or unsubstituted ring nitrogen atoms

  摘要：

  DOI：

  10.1021/jo00297a068
• 作为产物：
  描述：

  N,N',N''-(nitrilotris(ethane-2,1-diyl))triacetamide 在 lithium aluminium tetrahydride 作用下， 以 四氯化碳 为溶剂， 以58%的产率得到tris(2-(ethylamino)ethyl)amine
  参考文献：
  名称：

  三脚架四胺铜配合物掺入多孔二氧化硅骨架中的可逆配位作用

  摘要：

  本研究报告了使用模板方法的多孔结构材料的合成和合理设计。将四乙氧基甲硅烷基化的三脚架四胺（TREN）共价结合在具有双重印迹的二氧化硅骨架中：表面活性剂模板和金属离子印迹。阳离子表面活性剂（CTAB）的存在使材料具有高孔隙率，并且由于使用了甲硅烷基化的Cu II配合物，配体的三脚架或方金字塔形拓扑得以保留。去除表面活性剂并脱金属后，掺入的四胺被CuCl 2定量络合，该材料在热活化后显示出O 2的可逆结合在金属离子上发生。此化学吸附过程是通过UV /可见光和EPR光谱，与Cu监测：o 2加合物，被假定为一个终端上μ-η 1：η 1 -peroxodicopper（II）配合物通过氯离子桥接。在活化步骤中形成的Cu I活性物质在数个O 2期间被完全回收。绑定周期。铜配合物的高反应活性和双氧加合物的室温稳定性可以通过三脚架配体对不同几何形状的良好适应性，杂化二氧化硅中活性位点的限制来保护，这些活性

  DOI：

  10.1002/chem.200903148

文献信息

• BORATE-BASED BASE GENERATOR, AND BASE-REACTIVE COMPOSITION COMPRISING SUCH BASE GENERATOR
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20160340374A1

  公开（公告）日：2016-11-24

  An object of the present invention is to provide a compound which is capable of attaining a composition having high storage stability without reacting with a base-reactive compound, even in the case of storage for a long period of time in a mixed state with the base-reactive compound, such as an epoxy-based compound, as well as capable of generating a strong base (guanidines, biguanides, phosphazenes or phosphoniums) by irradiation of light (active energy rays) or heating; a base generator comprising the compound; and a base-reactive composition comprising the base generator and the base-reactive compound. The present invention relates to the compound represented by the general formula (A); the base generator comprising the compound; and the base-reactive composition comprising the base generator and the base-reactive compound. (wherein R 1 represents an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; an alkenyl group; a 2-furylethynyl group; a 2-thiophenylethynyl group; or a 2,6-dithianyl group; R 2 to R 4 each independently represent an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; the aryl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; a furanyl group; a thienyl group; or an N-alkyl-substituted pyrrolyl group; Z + represents an ammonium cation having a guanidinium group, a biguanidium group or a phosphazenium group, or a phosphonium cation.)

  本发明的目的是提供一种化合物，能够在与碱反应性化合物混合状态长时间存储的情况下，仍能获得具有高储存稳定性的组合物，而不与碱反应性化合物发生反应，同时还能通过光照（活性能量射线）或加热产生强碱（胍胺、双胍胺、磷氮烷或磷銨）；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。本发明涉及由通式（A）表示的化合物；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。（其中R1代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；烯基；2-呋喃基炔基；2-噻吩基炔基；或2,6-二硫基基；R2到R4各自独立地代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基；呋喃基；噻吩基；或N-烷基取代的吡咯基；Z+代表具有胍胺基团、双胍胺基团或磷氮烷基团的铵阳离子，或磷銨阳离子。）
• Reduction of Copper(II) Complexes of Tripodal Ligands by Nitric Oxide and Trinitrosation of the Ligands
  作者：Moushumi Sarma、Apurba Kalita、Pankaj Kumar、Amardeep Singh、Biplab Mondal

  DOI：10.1021/ja102279c

  日期：2010.6.16

  The copper(II) centers in two copper(II) complexes of tripodal amine ligands, in acetonitrile solvent, upon exposure to nitric oxide have been found to produce a thermally unstable [Cu(II)-NO] intermediate followed by the reduction of copper(II) to copper(I). This reduction resulted in the concomitant trinitrosation of the ligands at their terminal amine centers.

  已发现在乙腈溶剂中，铜 (II) 中心位于三足胺配体的两个铜 (II) 络合物中，当暴露于一氧化氮时，会产生热不稳定的 [Cu(II)-NO] 中间体，随后铜被还原(II) 到铜 (I)。这种还原导致配体在其末端胺中心伴随三亚硝化。
• Salts of triazinic compounds with phosphorus oxyacids, and use of said compounds in self-extinguishing polymeric compositions
  申请人：MINISTERO DELL' UNIVERSITA' E DELLA RICERCA SCIENTIFICA E TECNOLOGICA

  公开号：EP0537837A1

  公开（公告）日：1993-04-21

  Salts of triazinic compounds with phosphorus oxyacids, having the general formula (I): obtained by salifying oligomeric derivatives of 2,4, 6-triamino-1,3,5-triazine with a phosphorus-containing acid. The compounds with general formula (I) find use in particular as flame-retardant additives.

  三嗪化合物与含磷氧酸盐的盐，其一般式为(I)：通过用含磷酸盐对2,4,6-三氨基-1,3,5-三嗪的寡聚衍生物进行盐化而获得。具有一般式(I)的化合物特别用作阻燃添加剂。
• Self-extinguishing polymeric compositions
  申请人：MINISTERO DELL' UNIVERSITA' E DELLA RICERCA SCIENTIFICA E TECNOLOGICA

  公开号：EP0415371A2

  公开（公告）日：1991-03-06

  Described are self-extinguishing polymeric compositions comprising: (a) from 89 to 45 parts by weight of thermoplastic polymer, or of polymer endowed with elastomeric properties; b) from 8 to 30 parts by weight of one or more ammonium and/or amine phosphate(s) and/or phosphonate(s); (c) from 3 to 25 parts by weight of one or more 2,4,6-triamino-1,3,5-triazine derivatives of general formula (I): wherein the groups R to R₄, Z, Z₁ and Z₂ and the subscripts a and b are as defined in claim 1.

  所述自熄灭聚合物组合物包括 (a) 89 至 45 份（按重量计）热塑性聚合物或具有弹性特性的聚合物； b) 8 至 30 份（按重量计）一种或多种磷酸铵和/或胺和/或膦酸盐； (c) 一种或多种通式(I)的 2,4,6-三氨基-1,3,5-三嗪衍生物，按重量计，3 至 25 份： 其中基团 R 至 R₄、Z、Z₁ 和 Z₂ 以及下标 a 和 b 如权利要求 1 所定义。
• Diamino-s-triazinon derivatives and self-extinguishing polymeric compositions containing them
  申请人：MINISTERO DELL' UNIVERSITA' E DELLA RICERCA SCIENTIFICA E TECNOLOGICA

  公开号：EP0475367A1

  公开（公告）日：1992-03-18

  Disclosed are ameline derivatives of general formula (I): as defined in claim 1 and the use thereof as flame-proofing agents in self-extinguishing polymeric compositions.

  所公开的是通式（I）的酰胺啉衍生物： 及其在自熄性聚合物组合物中作为阻燃剂的用途。