2-氯二苯并喹喔啉 | 1202564-31-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 2-氯二苯并喹喔啉
• 中文别名: 2-氯-二苯并[f,h]喹喔啉；2-氯菲并[9,10-B]吡嗪
• 英文名称: 2-chlorodibenzo[f,h]quinoxaline
• 英文别名: 3-chlorophenanthro[9,10-b]pyrazine
• CAS: 1202564-31-5
• 化学式: C₁₆H₉ClN₂
• 分子量: 264.714
• InChiKey: FEYJCWNQZBKYKT-UHFFFAOYSA-N

物化性质

• 沸点：
  462.3±25.0 °C(Predicted)
• 密度：
  1.391±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-氯二苯并喹喔啉 、 4-氯苯硼酸 在 palladium diacetate 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 21.0h， 以57%的产率得到2-(4-chlorophenyl)dibenzo[f,h]quinoxaline
  参考文献：
  名称：

  有機化合物、発光素子、発光装置、電子機器、及び照明装置

  摘要：

  提供利用有机电致发光的发光元件中作为分散发光层发光物质的宿主材料的有用新型荧光性有机化合物。根据以下一般式（G1）表示的有机化合物。“A代表取代或未取代的二苯并呋喃-二基、取代或未取代的二苯并噻吩-二基、取代或未取代的N-芳基-9H-咔唑基二基或取代或未取代的N-烷基-9H-咔唑基二基；Ar1和Ar2各自独立地代表单键或取代或未取代的芳基；X1和X2各自独立地代表C或N”。【选择图】无

  公开号：

  JP2015063518A
• 作为产物：
  描述：

  dibenzo[f,h]quinoxaline-1-oxide 在 三氯氧磷 作用下， 反应 1.0h， 以93%的产率得到2-氯二苯并喹喔啉
  参考文献：
  名称：

  [EN] ORGANOMETALLIC COMPLEX, AND LIGHTING APPARATUS, AND ELECTRONIC DEVICE USING THE ORGANOMETALLIC COMPLEX
  [FR] COMPLEXE ORGANOMÉTALLIQUE, APPAREIL D'ÉCLAIRAGE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LEDIT COMPLEXE ORGANOMÉTALLIQUE

  摘要：

  本发明涉及一种具有高色纯度的发射红光的有机金属配合物。提供了一种具有以下通用式（G1）所表示的结构的有机金属配合物。在该式中，R1至R13中至少有一个代表具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基，而其他一个或多个代表氢。M代表中心金属，其为第9族或第10族元素。L代表单负离子配体，当中心金属为第9族元素时，n为2，当中心金属为第10族元素时，n为1。

  公开号：

  WO2009157498A1

文献信息

• ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：OSAKA Harue

  公开号：US20120077987A1

  公开（公告）日：2012-03-29

  A novel substance with which an increase in life and emission efficiency of a light-emitting element can be achieved is provided. A carbazole compound having a structure represented by General Formula (G1) is provided. Note that a substituent which makes the HOMO level and the LUMO level of a compound in which a bond of the substituent is substituted with hydrogen deep and shallow, respectively is used as each of substituents in General Formula (G1) (R 1 , R 2 , Ar 3 , and α 3 ). Further, a substituent which makes the band gap (Bg) and the T1 level of a compound in which a bond of the substituent is substituted with hydrogen wide and high is used as each of the substituents in General Formula (G1) (R 1 , R 2 , Ar 3 , and α 3 ).

  提供一种新型物质，可以实现发光元件寿命和发射效率的提高。提供一种具有通用式（G1）表示的结构的咔唑化合物。请注意，在通用式（G1）中，使取代基的HOMO能级和LUMO能级分别变深和变浅的取代基被用作每个取代基（R1、R2、Ar3和α3）。此外，在通用式（G1)中，使取代基的带隙（Bg）和T1能级分别变宽和变高的取代基被用作每个取代基（R1、R2、Ar3和α3）。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120098417A1

  公开（公告）日：2012-04-26

  Provided is a novel substance that can emit phosphorescence. Alternatively, provided is a novel substance with high emission efficiency. An organometallic complex in which a 4-arylpyrimidine derivative is a ligand and iridium is a central metal is provided. Specifically, an organometallic complex having a structure represented by a general formula (G1) is provided. In the general formula (G1), R 1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, R 2 represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted phenyl group, R 3 represents hydrogen or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and Ar 1 represents a substituted or unsubstituted arylene group having 6 to 10 carbon atoms.

  提供了一种可以发射磷光的新型物质。或者，提供了一种具有高发射效率的新型物质。提供了一种有机金属配合物，其中4-芳基嘧啶衍生物是配体，镭是中心金属。具体地，提供了一种具有通用式（G1）表示的结构的有机金属配合物。在通用式（G1）中，R1代表具有1至4个碳原子的取代或未取代的烷基基团或具有6至10个碳原子的取代或未取代的芳基基团，R2代表氢、具有1至4个碳原子的取代或未取代的烷基基团，以及取代或未取代的苯基，R3代表氢或具有1至4个碳原子的取代或未取代的烷基基团，Ar1代表具有6至10个碳原子的取代或未取代的芳烃基团。
• Organometallic Complex, and Light-Emitting Element and Display Device Using the Organometallic Complex
  申请人：Inoue Hideko

  公开号：US20120104373A1

  公开（公告）日：2012-05-03

  An object is to provide a novel organometallic complex capable of phosphorescence and having high heat resistance. Alternatively, an object is to provide a light-emitting device with high added value. The objects are achieved by providing an organometallic complex which has a structure represented by a general formula (G1) or (G2) below and is formed in such a way that a corresponding one of pyrazine derivatives represented by general formulae (G0) and (G0′) below is ortho-metalated by a Group 9 or Group 10 metal ion, or by providing a light-emitting element and a light-emitting device including the organometallic complex.

  提供一种新型具有磷光和高耐热性的有机金属配合物是一项目标。另外，提供一种具有高附加值的发光装置也是一个目标。通过提供一种具有以下一般式（G1）或（G2）所表示结构的有机金属配合物，该配合物是通过使以下一般式（G0）和（G0'）所表示的吡嗪衍生物之一被第9族或第10族金属离子正金属化而形成的，或者通过提供包括该有机金属配合物的发光元件和发光装置来实现这些目标。
• Composite material, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Ogita Kaori

  公开号：US09385328B2

  公开（公告）日：2016-07-05

  A composite material which includes an organic compound and an inorganic compound and has a high carrier-transport property is provided. A composite material having a good property of carrier injection into an organic compound is provided. A composite material in which light absorption due to charge-transfer interaction is unlikely to occur is provided. A composite material having a high visible-light-transmitting property is provided. A composite material including a hydrocarbon compound and an inorganic compound exhibiting an electron-accepting property with respect to the hydrocarbon compound is provided. The hydrocarbon compound has a substituent bonded to a naphthalene skeleton, a phenanthrene skeleton, or a triphenylene skeleton and has a molecular weight of 350 to 2000, and the substituent has one or more rings selected from a benzene ring, a naphthalene ring, a phenanthrene ring, and a triphenylene ring.

  提供一种包括有机化合物和无机化合物并具有高载流子传输性能的复合材料。提供一种具有良好载流子注入性能的复合材料。提供一种不太可能发生由于电荷转移相互作用而引起的光吸收的复合材料。提供一种具有高可见光透射性能的复合材料。提供一种包括烃化合物和对烃化合物具有电子受体性质的无机化合物的复合材料。烃化合物具有连接到萘骨架、菲骨架或三苯基骨架的取代基，分子量为350至2000，取代基中有一个或多个从苯环、萘环、菲环和三苯基环中选择的环。
• Organic Light-Emitting Element, Organometallic Complex, Light-Emitting Device, Electronic Appliance, and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120264936A1

  公开（公告）日：2012-10-18

  Disclosed is a phosphorescent organometallic complex having: a 6-membered aromatic heterocycle having a nitrogen atom; iridium or platinum to which the nitrogen atom coordinates; and an aryl group which is bonded to an α-carbon of the nitrogen atom and is ortho-metalated with the iridium or platinum, where at least one of the aromatic heterocycle and the aryl group has an alicyclic hydrocarbon having an intramolecular carbon-carbon bridged bond as a substituent. The ability of the bulky structure of the alicyclic hydrocarbon to inhibit aggregation of the organometallic complex, concerted with the strong electron-donating property of the alicyclic hydrocarbon to the aromatic heterocycle or the aryl group, contributes to the increase in absorption coefficient and phosphorescent efficiency of the organometallic complex. The improved absorption coefficient and the phosphorescent efficiency allow the formation of a light-emitting element with excellent external quantum efficiency over 25%.

  本发明揭示了一种磷光有机金属配合物，其具有：含有氮原子的6元芳香杂环；氮原子与铱或铂配位；以及与氮原子的α-碳键合并与铱或铂发生邻位金属化的芳基基团，其中至少有芳香杂环和芳基基团中的一个具有作为取代基的脂环烃，其具有分子内碳-碳桥键。脂环烃的臃肿结构能够抑制有机金属配合物的聚集，与脂环烃对芳香杂环或芳基基团的强电子给体性质协同作用，有助于提高有机金属配合物的吸收系数和磷光效率。改进的吸收系数和磷光效率使得形成的发光元件具有优异的外部量子效率超过25%。