2-氯辛酰氯 | 64781-13-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 中文名称: 2-氯辛酰氯
• 英文名称: 2-Chlorooctanoyl chloride
• CAS: 64781-13-1
• 化学式: C₈H₁₄Cl₂O
• 分子量: 197.105
• InChiKey: GTQMRKYASBKZSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲醇 、 2-氯辛酰氯 在 硫酸 作用下， 生成 2-chloro octanoic acid methyl ester
  参考文献：
  名称：

  Mass spectra of halogenated esters. 7. Methyl esters of 2-chloro C2C20n-alkanoic acids

  摘要：

  AbstractThe mass spectral fragmentation of a homologous series of methyl esters of 2‐chloro n‐alkanoic acids ranging from acetic (C2) to eicosanoic (C20) acid on electron impact has been investigated. The fragmentation pathways were elucidated with the aid of the first field‐free region metastable ions, the results being presented with one compound, i.e. with ionized methyl 2‐chloro‐octauoate. Owing to the Cl/H exchanges and to the formation of the non‐chlorinated parent esters prior to the fragmentations the spectra show the peak pairs with and without the chlorine atom. The effects become more evident with increasing chain length; shown most visually by the abundance ratios of the McLafferty rearrangement ions atm/z108/110 and 74, and fragments at m/z121/123 and 87.

  DOI：

  10.1002/oms.1210231010

文献信息

• Peroxygen bleach activators and bleaching compositions
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0150532A1

  公开（公告）日：1985-08-07

  This invention relates to peroxygen bleaching activator compounds and bleaching compositions. The peroxygen bleach activator compounds, used in combination with peroxygen bleach compounds which yield hydrogen peroxide in an aqueous solution, provide effective and efficient bleaching of textiles over a wide range of temperatures. In a highly preferred embodiment the bleaching compositions of the invention are detergent compositions. The method of preparing these peroxygen bleach activator compounds is also claimed.

  本发明涉及过氧漂白活化剂化合物和漂白组合物。过氧漂白活化剂化合物与在水溶液中产生过氧化氢的过氧漂白化合物结合使用，可在很宽的温度范围内对纺织品进行有效和高效的漂白。在一个非常优选的实施方案中，本发明的漂白组合物是洗涤剂组合物。本发明还提出了制备这些过氧漂白活化剂化合物的方法。
• ALICYCLIC COMPOUNDS AND CURABLE RESIN COMPOSITION
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1112995A1

  公开（公告）日：2001-07-04

  Decane compound or decene compound shown in the formula [1] below wherein A1 and A2 are independently hydrogen or (meth) acryloyl group or 2-vinyloxyethyl group; and the dotted line is single bond or double bond with the proviso that A1 and A2 are not hydrogen at the same time;, and curable resin composition containing said compound therein. The compound are suitable as the photo-monomer for resist raw materials because of high clarity at short wavelength ultraviolet light, dry etching resistance, adhesive property for the substrate and high solubility in alkaline developing solution in addition to high sensitivity and greater resolution; as the monomer for optic raw materials and disk overcoat materials because of high clarity, low birefringence and low water absorption rate; and as the monomer for the coating raw materials such as EB curable coating raw materials because of high reactivity, high wear characteristics and water resistance.

  下式[1]所示的癸烷化合物或癸烯化合物，其中 A1 和 A2 独立地为氢或 （甲基）丙烯酰基或 2-乙烯基乙基；虚线为单键或双键，但 A1 和 A2 不能同时为氢；以及含有所述化合物的可固化树脂组合物。 这些化合物适合用作光刻胶原料的光单体，因为它们在短波长紫外线下具有高透明度、耐干蚀性、对基材具有粘合性、在碱性显影液中具有高溶解性，此外还具有高灵敏度和更高分辨率；适合用作光学原料和盘面涂层材料的单体，因为它们具有高透明度、低双折射和低吸水率；适合用作涂层原料（如 EB 固化涂层原料）的单体，因为它们具有高反应性、高耐磨特性和耐水性。
• US4486327A
  申请人：——

  公开号：US4486327A

  公开（公告）日：1984-12-04
• US4483778A
  申请人：——

  公开号：US4483778A

  公开（公告）日：1984-11-20
• US4539130A
  申请人：——

  公开号：US4539130A

  公开（公告）日：1985-09-03