2-[3,4,5-tri(tetradecoxy)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline | 873874-64-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-[3,4,5-tri(tetradecoxy)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline
• CAS: 873874-64-7
• 化学式: C₆₁H₉₆N₄O₃
• 分子量: 933.458
• InChiKey: DXGLLSZVGCYDSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23.6
• 重原子数：
  68
• 可旋转键数：
  43
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  82.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-[3,4,5-tri(tetradecoxy)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline 、 uranyl(VI) triflate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  A Propeller-like Uranyl Metallomesogen

  摘要：

  Uranyl triflate forms with three imidazo[4,5-f]-1,10-phenanthroline ligands a propeller-like complex that exhibits a hexagonal columnar phase. The ligand is not liquid-crystalline, but a mesophase is induced upon complex formation with the uranyl salt. The thermal behavior has been investigated by polarizing optical microscopy and by high-temperature X-ray diffraction. A model of the stacking of the molecules in the mesophase is proposed.

  DOI：

  10.1021/ja056664w
• 作为产物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 3,4,5-tris(tetradecyloxy)benzaldehyde 在 ammonium acetate 、 溶剂黄146 作用下， 反应 5.0h， 以55%的产率得到2-[3,4,5-tri(tetradecoxy)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline
  参考文献：
  名称：

  A Propeller-like Uranyl Metallomesogen

  摘要：

  Uranyl triflate forms with three imidazo[4,5-f]-1,10-phenanthroline ligands a propeller-like complex that exhibits a hexagonal columnar phase. The ligand is not liquid-crystalline, but a mesophase is induced upon complex formation with the uranyl salt. The thermal behavior has been investigated by polarizing optical microscopy and by high-temperature X-ray diffraction. A model of the stacking of the molecules in the mesophase is proposed.

  DOI：

  10.1021/ja056664w

文献信息

• A Propeller-like Uranyl Metallomesogen
  作者：Thomas Cardinaels、Jan Ramaekers、Daniel Guillon、Bertrand Donnio、Koen Binnemans

  DOI：10.1021/ja056664w

  日期：2005.12.1

  Uranyl triflate forms with three imidazo[4,5-f]-1,10-phenanthroline ligands a propeller-like complex that exhibits a hexagonal columnar phase. The ligand is not liquid-crystalline, but a mesophase is induced upon complex formation with the uranyl salt. The thermal behavior has been investigated by polarizing optical microscopy and by high-temperature X-ray diffraction. A model of the stacking of the molecules in the mesophase is proposed.