9,10-bis(chlorocarbonylmethyl)anthracene | 97760-32-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-bis(chlorocarbonylmethyl)anthracene
• 英文别名: 9,10-anthracene diethanoyl dichloride；9,10-anthracenediacetyl dichloride；anthracene-9,10-diyldi-acetyl chloride；Anthracen-9,10-diyldi-acetylchlorid；2-[10-(2-Chloro-2-oxoethyl)anthracen-9-yl]acetyl chloride；2-[10-(2-chloro-2-oxoethyl)anthracen-9-yl]acetyl chloride
• CAS: 97760-32-2
• 化学式: C₁₈H₁₂Cl₂O₂
• 分子量: 331.198
• InChiKey: IZDUBSIOSHBDSG-UHFFFAOYSA-N

物化性质

• 沸点：
  515.5±43.0 °C(Predicted)
• 密度：
  1.378±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis(chlorocarbonylmethyl)anthracene 在 diborane(6) 作用下， 反应 2.0h， 生成 6,9,17,20-tetraoxa-3,12-diaza<14,83,12>(9,10)anthracenophane
  参考文献：
  名称：

  大双环蒽-隐窝分子的合成，阳离子结合和光物理性质

  摘要：

  新的穴状配体（1a）和（1b）具有显着的光谱和光物理性质，受到阳离子结合和质子化的影响显着。

  DOI：

  10.1039/c39850000433
• 作为产物：
  描述：

  9,10-二(氯甲基)蒽 在 氢氧化钾 、 氯化亚砜 作用下， 生成 9,10-bis(chlorocarbonylmethyl)anthracene
  参考文献：
  名称：

  Rio, Annales de Chimie (Cachan, France), 1954, vol. <12> 9, p. 182,244

  摘要：

  DOI：

文献信息

• Synthesis, cation binding, and photophysical properties of macrobicyclic anthraceno-cryptands
  作者：Joseph P. Konopelski、Florence Kotzyba-Hibert、Jean-Marie Lehn、Jean-Pierre Desvergne、Frédéric Fagès、Alain Castellan、Henri Bouas-Laurent

  DOI：10.1039/c39850000433

  日期：——

  The new cryptands, (1a) and (1b), possess remarkable spectroscopic and photophysical properties which are markedly affected by cation binding and by protonation.

  新的穴状配体（1a）和（1b）具有显着的光谱和光物理性质，受到阳离子结合和质子化的影响显着。
• Synthesis and Characterization of 2,8-Diazaperylene-1,3,7,9-tetraone, a New Anthracene Diimide Containing Six-Membered Imide Rings
  作者：Ali Reza Mohebbi、Cedric Munoz、Fred Wudl

  DOI：10.1021/ol200659c

  日期：2011.5.20

  A successful synthesis of novel diimides, namely anthracene diimide containing six-membered imide rings, with potential application in organic electronics is reported. The single crystal of 5a exhibits a close interplanar spacing of 3.45 Å between molecules in a stack.

  据报道成功合成了新颖的二酰亚胺，即含有六元酰亚胺环的蒽二酰亚胺，具有在有机电子领域的潜在应用。5a单晶在堆栈中的分子之间显示出3.45Å的紧密晶面间距。
• Syntheses and Photophysical Studies of Cyclodextrin Derivatives with Two Proximate Anthracenyl Groups
  作者：Xiaoyong Zhang、Ken Sasaki、Yasuhisa Kuroda

  DOI：10.1021/jo060449w

  日期：2006.6.1

  [GRAPHICS]A series of permethylated cyclodextrin derivatives, cyclodextrin dimers doubly bridged with two anthracene moieties ( An(2)CD(2)) and singly bridged with one ( AnCD(2)) and the monomer bearing two anthracene moieties ( An(2)CD), were newly synthesized. For An(2)CD(2), the two isomeric forms are also identified. All compounds are soluble in both aqueous and various organic solvents. The bisanthracene systems, An(2)CD(2) and An(2)CD, show the thermal equilibrium in an aqueous solution between the intramolecularly interacting ( closed) and less-interacting ( open) states of the anthracene moieties, which results in the temperature-dependent absorption changes. These systems also show the characteristic excimer emission that is enhanced in water and weakened in organic solvents. The excitation spectra for the monomer and excimer fluorescence are found to be quite different from each other and similar to the absorption spectra of the open and the closed forms, respectively. The observed unique parallelism between excitation and absorption spectra for the present excimer systems indicates the dual ground state-dual excitation scheme where the excitation state formed from the closed ground state mainly gives excimer. The fluorescence lifetime analyses reveal that the rates of the conversion from the excited state of the open form to that of the closed one ( 6.0 x 10(6) s(-1) for An(2)CD(2)-2) are largely retarded compared with that of the ethyleneoxy linked bisanthracene system ( 8.8 x 10(7) s(-1)).
• Rio, Annales de Chimie (Cachan, France), 1954, vol. <12> 9, p. 182,244
  作者：Rio

  DOI：——

  日期：——
• Anthraceno-cryptands: a new class of cation-complexing macrobicyclic fluorophores
  作者：Frederic Fages、Jean Pierre Desvergne、Henri Bouas-Laurent、Pierre Marsau、Jean Marie Lehn、Florence Kotzyba-Hibert、Anne Marie Albrecht-Gary、Malak Al-Joubbeh

  DOI：10.1021/ja00205a017

  日期：1989.11

  Des ethylenedioxydiethylenes dioxadiaza [14]- et [16] anthracenophanes (A) sont etudies. Les electrons non apparies de l'azote forment avec le noyau anthracene des exciplexes intramoleculaires. Ces composes (A) donnent lieu a une emission de fluorescence (de type monomere et exciplexe) sensible a la nature protique ou aprotique du solvant. Les cryptates sont egalement etudies

  Des ethylenedioxydiethylenes dioxadiaza [14]- et [16] anthracenophanes (A) 子研究。Les electrons non apparies de l'azote formment avec le noyau anthracene des exciplexes inmoleculaires。Ces 组成 (A) donnent lieu a une Emission defluorescence (de type Monone et exciplexe) sensible a la nature protique ou aprotique du solvant。Les cryptates Sont egalement 研究