Bis-(2.4.5-trichlor-6-carbobutoxyphenyl)-oxalat | 30431-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis-(2.4.5-trichlor-6-carbobutoxyphenyl)-oxalat
• 英文别名: Bis(2-butoxycarbonyl-3,4,6-trichlorophenyl) oxalate
• CAS: 30431-50-6
• 化学式: C₂₄H₂₀Cl₆O₈
• 分子量: 649.136
• InChiKey: MCJCREGWRMCHIM-UHFFFAOYSA-N

物化性质

• 沸点：
  675.3±55.0 °C(Predicted)
• 密度：
  1.478±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  38
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  5-氯代水杨酸 在 硫酸 、 碘 、 氯 、 三乙胺 作用下， 以 溶剂黄146 、 苯 为溶剂， 反应 36.0h， 生成 Bis-(2.4.5-trichlor-6-carbobutoxyphenyl)-oxalat
  参考文献：
  名称：

  Dowd, Christopher D.; Paul, D. Brenton, Australian Journal of Chemistry, 1984, vol. 37, # 1, p. 73 - 86

  摘要：

  DOI：

文献信息

• Chemiluminescent composition
  申请人：LUMICA CORPORATION

  公开号：US20040238803A1

  公开（公告）日：2004-12-02

  The present invention provides a chemiluminescent composition including an oxalate and a fluorescent material wherein the chemiluminescent composition is mixed with a composition including hydrogen peroxide to induce chemiluminescence. The chemiluminescent composition comprises a solvent for the oxalate and the fluorescent material, which includes an acetyl citrate ester or an organic solvent containing an acetyl citrate ester. As an alternative to dibutyl phthalate which is suspected to be one of endocrine disrupting chemicals, the solvent of the present invention can assure safety to human body while maintaining excellent storage stability and luminescent performance.

  本发明提供一种化学发光组合物，包括草酸盐和荧光材料，其中该化学发光组合物与包含过氧化氢的组合物混合，以诱导化学发光。该化学发光组合物包括草酸盐和荧光材料的溶剂，其中溶剂包括乙酰柠檬酸酯或含有乙酰柠檬酸酯的有机溶剂。作为二丁基邻苯二甲酸酯的替代品，该发明的溶剂可以确保人体安全，同时保持优异的储存稳定性和发光性能。
• PHTHALATE-FREE CHEMILUMINESCENT FORMULATIONS
  申请人：Schrimmer Jeffrey D.

  公开号：US20120126188A1

  公开（公告）日：2012-05-24

  A phthalate-free chemiluminescent formulation and a device containing such phthalate-free chemiluminescent formulation are provided. The phthalate-free chemiluminescent formulation includes phthalate-free solvents such as triethyl citrate and acetyl tributyl citrate.

  提供一种不含邻苯二甲酸酯的化学发光配方和一种包含该化学发光配方的设备。该不含邻苯二甲酸酯的化学发光配方包括不含邻苯二甲酸酯的溶剂，例如柠檬酸三乙酯和醋酸三丁酯。
• Solid, thin chemiluminescent device
  申请人：OMNIGLOW CORPORATION

  公开号：EP0492053A1

  公开（公告）日：1992-07-01

  There is provided a flexible, thin, rectangular, chemiluminescent device comprised of a back sheet of a laminated metal foil having heat sealed thereto at its edges a bi-component front sheet, the first component of which is a laminated metal foil and the second component of which is a transparent or translucent polyolefin sheet, said first and second components being heat sealed to each other at their adjacent latitudinal edge, from about 20% to about 50% of the surface area of said front sheet being comprised of said first component; temporary separation means positioned so as to divide the interior area of said device into two compartments, one under each of said components, the compartment under said second component having positioned therein an absorbent material containing a solvent solution of an oxalate and, optionally, a fluorescer, and the compartment under said first component containing an activator solution.

  提供了一种柔性、薄型、矩形的化学发光装置，该装置由层压金属箔背板和双组分前板组成，前板的第一组分是层压金属箔，第二组分是透明或半透明聚烯烃板，第一组分和第二组分在相邻的纬向边缘热封，前板表面积的约20%至约50%由第一组分组成；临时分隔装置，其作用是将所述装置的内部区域分成两个隔间，每个隔间位于所述组件的下方，所述第二组件下方的隔间内放置有吸收材料，其中含有草酸盐溶剂溶液和可选的荧光剂，而所述第一组件下方的隔间内则含有活化剂溶液。
• A porous, flexible structure for chemiluminescent device
  申请人：OMNIGLOW CORPORATION

  公开号：EP0663560A2

  公开（公告）日：1995-07-19

  The present invention provides a porous, flexible structure comprising A) a non-particulate phase comprising a vinyl halide or vinylidene halide polymer having a molecular weight of about 100,000 to about 500,000 which constitutes 0.5 to about 15.0 weight percent of total polymer, B) an agglomerated particle phase comprising either 1) about 85.0 to about 99.5 weight percent of total polymer of vinyl halide or vinylidene halide polymer particles having a diameter of from about 25 to about 125 µm and a molecular weight of from about 50,000 to about 120,000, or mixtures of said particles, or 2) about 45 to about 98.5 weight percent of total polymer of vinyl halide or vinylidene halide polymer particles having a diameter of from about 25 to about 125 µm and a molecular weight of from about 50,000 to about 120,000, or mixtures of said particles, and about 1 to about 40 weight percent of total polymer of vinyl halide or vinylidene halide polymer particles having a diameter of from about 130 to about 225 µm and a molecular weight of from about 100,000 to about 225,000 and C) a plasticizer comprising a solvent solution of a chemiluminescent compound and, optionally, a fluorescer, dispersed throughout both said phases.

  本发明提供了一种多孔柔性结构，该结构包括：A) 非颗粒相，包括卤化乙烯基或卤化亚乙烯基聚合物，其分子量约为 100,000 至约 500,000，占聚合物总量的 0.5 至约 15.0 重量百分比；B) 团聚颗粒相，包括 1) 约 85.0 至约 99.5 重量百分比的卤化乙烯基或偏卤化乙烯基聚合物颗粒，其直径约为 25 至约 125 µm，分子量约为 50,000 至约 120,000 或上述颗粒的混合物，或 2) 约 45 至约 98.5 重量百分比的卤化乙烯基或偏卤化乙烯基聚合物颗粒，其直径约为 25 至约 125 微米，分子量约为 50,000 至约 120,000 或上述颗粒的混合物、C) 增塑剂，包括分散在上述两相中的化学发光化合物和荧光剂的溶剂溶液。
• Chemiluminescent compositions
  申请人：Lumica Corporation

  公开号：EP1477545A1

  公开（公告）日：2004-11-17

  The present invention provides a chemiluminescent composition including an oxalate and a fluorescent material. The chemiluminescent composition is mixed with a composition including hydrogen peroxide to induce chemiluminescence. The chemiluminescent composition comprises a solvent for the oxalate and the fluorescent material, which includes an acetyl citrate ester or an organic solvent containing an acetyl citrate ester. This avoids the use of dibutyl phthalate as the solvent. Dibutyl phthalate is suspected to be an endocrine-disrupting chemical, so using the solvent specified in the present invention improves the degree of safety to the human body. Excellent storage stability and luminescent performance are, however, maintained.

  本发明提供了一种包括草酸盐和荧光材料的化学发光组合物。该化学发光组合物与包括过氧化氢的组合物混合以诱导化学发光。化学发光组合物包括草酸盐和荧光材料的溶剂，其中包括乙酰柠檬酸酯或含有乙酰柠檬酸酯的有机溶剂。这就避免了使用邻苯二甲酸二丁酯作为溶剂。邻苯二甲酸二丁酯被怀疑是一种干扰内分泌的化学物质，因此使用本发明指定的溶剂可提高对人体的安全程度。不过，本发明仍能保持出色的储存稳定性和发光性能。