bis(N-pyrid-4-ylmethyl)adipoamide | 223682-28-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: bis(N-pyrid-4-ylmethyl)adipoamide
• 英文别名: N,N'-bis(pyridin-4-ylmethyl)hexanediamide
• CAS: 223682-28-8
• 化学式: C₁₈H₂₂N₄O₂
• 分子量: 326.398
• InChiKey: YDHSBQDABGGDAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  24
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  zinc(II) chloride 、 bis(N-pyrid-4-ylmethyl)adipoamide 以 甲醇 为溶剂， 生成 bis(N-pyrid-4-ylmethyl)adipoamide zinc chloride complex
  参考文献：
  名称：

  Molecular design of the polymer forming the complex with metal [I]: design of the hard-segments of thermoplastic elastomers by using model compounds

  摘要：

  The six model hard-segments of thermoplastic elastomers containing a pyridine ring were synthesised and the complexation studied with several metal chlorides. It is found that the model compounds containing MPY group (N-pyrid-2-ylmethyl amide) form the stoichiometric 1:1 complex with ZnCl2 by means of IR. This stoichiometric complexation is caused by the effective formation of the chelate ring between MPY group and ZnCl2. In addition, the complex structure exhibits strong interaction with each other, so that the melting temperature and enthalpy are remarkably increased. As the result, the MPY-ZnCl2 complex structure is the most suitable structure as the hard-segment of thermoplastic elastomers. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(98)00606-1
• 作为产物：
  描述：

  4-甲氨基吡啶 、 己二酰氯 在 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 以89%的产率得到bis(N-pyrid-4-ylmethyl)adipoamide
  参考文献：
  名称：

  Molecular design of the polymer forming the complex with metal [I]: design of the hard-segments of thermoplastic elastomers by using model compounds

  摘要：

  The six model hard-segments of thermoplastic elastomers containing a pyridine ring were synthesised and the complexation studied with several metal chlorides. It is found that the model compounds containing MPY group (N-pyrid-2-ylmethyl amide) form the stoichiometric 1:1 complex with ZnCl2 by means of IR. This stoichiometric complexation is caused by the effective formation of the chelate ring between MPY group and ZnCl2. In addition, the complex structure exhibits strong interaction with each other, so that the melting temperature and enthalpy are remarkably increased. As the result, the MPY-ZnCl2 complex structure is the most suitable structure as the hard-segment of thermoplastic elastomers. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(98)00606-1

文献信息

• Molecular design of the polymer forming the complex with metal [I]: design of the hard-segments of thermoplastic elastomers by using model compounds
  作者：Nobuhiro Moriguchi、Toshinori Tsugaru、Shigetoshi Amiya

  DOI：10.1016/s0022-2860(98)00606-1

  日期：1999.3

  The six model hard-segments of thermoplastic elastomers containing a pyridine ring were synthesised and the complexation studied with several metal chlorides. It is found that the model compounds containing MPY group (N-pyrid-2-ylmethyl amide) form the stoichiometric 1:1 complex with ZnCl2 by means of IR. This stoichiometric complexation is caused by the effective formation of the chelate ring between MPY group and ZnCl2. In addition, the complex structure exhibits strong interaction with each other, so that the melting temperature and enthalpy are remarkably increased. As the result, the MPY-ZnCl2 complex structure is the most suitable structure as the hard-segment of thermoplastic elastomers. (C) 1999 Elsevier Science B.V. All rights reserved.