adipic acid bis-(2,2,2-trifluoro-ethyl ester) | 333-35-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: adipic acid bis-(2,2,2-trifluoro-ethyl ester)
• 英文别名: Adipinsaeure-bis-(2,2,2-trifluor-aethylester)；bis(2,2,2-trifluoroethyl) adipate；bis(2,2,2-trifluoroethyl) hexanedioate
• CAS: 333-35-7
• 化学式: C₁₀H₁₂F₆O₄
• 分子量: 310.193
• InChiKey: ZHGPZNAGINOIGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,2,2-三氟乙醇 、 己二酰氯 生成 adipic acid bis-(2,2,2-trifluoro-ethyl ester)
  参考文献：
  名称：

  Filler et al., Journal of the American Chemical Society, 75<1953<2693

  摘要：

  DOI：

文献信息

• Desymmetrizing Hydroformylation of Dihydromuconic Acid Diesters: Application to the Synthesis of (±)-Vindeburnol
  作者：Laura Salacz、Cyrille Charpentier、Jean Suffert、Nicolas Girard

  DOI：10.1021/acs.joc.6b02939

  日期：2017.2.17

  desymmetrizing hydroformylation of internal alkenes derived from dihydromuconic acid is described. The study of this reaction afforded easy access to polyfunction aldehydes. After the evaluation of the reactivity of the dimethyl ester derivative with various primary amines, this methodology was used to design a rapid synthesis of (±)-vindeburnol from tryptamine in only two steps.

  描述了衍生自二氢粘康酸的内部烯烃的脱对称加氢甲酰基化。该反应的研究提供了容易获得多官能醛的途径。在评估了二甲基酯衍生物与各种伯胺的反应性后，该方法仅需两个步骤即可用于设计从色胺中快速合成（±）-乙烯基苯丁醇的方法。
• Process for the production of polyesters using enzymes and supercritical fluids
  申请人：Bayer Corporation

  公开号：EP0729993A1

  公开（公告）日：1996-09-04

  A process of preparing a polyester by reacting a diol with an acid or acid ester in the presence of a solid enzyme and in a supercritical fluid is described.

  描述了一种在固体酶存在下和超临界流体中通过二元醇与酸或酸酯反应制备聚酯的工艺。
• PROCESS FOR PRODUCING FLUOROCOPOLYMER NANOCOMPOSITE
  申请人：Asahi Glass Company, Limited

  公开号：EP2508564A1

  公开（公告）日：2012-10-10

  To provide a process for producing a fluorinated copolymer nanocomposite comprising a fluorinated copolymer and inorganic fine particles dispersed therein to a high degree, and a process for producing a molded fluororesin product. The process for producing a fluorinated copolymer nanocomposite comprising a fluorinated copolymer and inorganic fine particles, characterized in that a mixture (A) containing a fluorinated copolymer comprised of repeating units based on tetrafluoroethylene and repeating units based on ethylene, inorganic fine particles, and a solvent which can dissolve the fluorinated copolymer under ordinary or elevated pressure at a temperature of not higher than the melting point of the fluorinated copolymer, is heated to at least a temperature at which the fluorinated copolymer dissolves in the solvent, and the solvent is subsequently removed. The process for producing a molded fluororesin product by using the fluorinated copolymer nanocomposite to produce a molded product.

  提供一种生产由含氟共聚物和高度分散于其中的无机微粒组成的含氟共聚物纳米复合材料的工艺，以及一种生产模塑氟树脂产品的工艺。 生产包含含氟共聚物和无机微粒的含氟共聚物纳米复合材料的工艺，其特征在于混合物 (A) 包含由基于四氟乙烯的重复单元和基于乙烯的重复单元组成的含氟共聚物、无机微粒、和一种溶剂，该溶剂可在不高于氟化共聚物熔点的温度下，在普通或高压条件下溶解氟化共聚物，将该混合物加热至至少使氟化共聚物溶解在溶剂中的温度，然后除去溶剂。使用含氟共聚物纳米复合材料生产模塑氟树脂产品的工艺。
• COATING COMPOSITION FOR COATING SURFACE OF REFLECTIVE PLATE FOR SOLAR HEAT COLLECTION PURPOSES, REFLECTIVE PLATE FOR SOLAR HEAT COLLECTION PURPOSES, AND PROCESSES FOR PRODUCTION OF THE COATING COMPOSITION AND THE REFLECTIVE PLATE
  申请人：Asahi Glass Company, Limited

  公开号：EP2559743A1

  公开（公告）日：2013-02-20

  To provide a coating composition capable of forming a coating film having excellent functions on the surface of a solar heat-collecting reflective plate, and a solar heat-collecting reflective plate obtainable by such a composition, as well as processes for their production. A coating composition for coating the surface of a solar heat-collecting reflective plate, which comprises a fluorinated copolymer having repeating units derived from ethylene and repeating units derived from tetrafluoroethylene, and a solvent capable of dissolving the fluorinated copolymer at a temperature of not higher than the melting point of the fluorinated copolymer; a solar heat-collecting reflective plate obtainable by such a composition; and processes for producing such a composition and a reflective plate.

  提供一种能在太阳能集热反射板表面形成具有优异功能的涂膜的涂层组合物，以及用这种组合物获得的太阳能集热反射板及其生产工艺。一种用于在太阳能集热反射板表面涂膜的涂层组合物，它包括一种具有来自乙烯的重复单元和来自四氟乙烯的重复单元的氟化共聚物，以及一种能够在不高于氟化共聚物熔点的温度下溶解该氟化共聚物的溶剂；一种可通过这种组合物获得的太阳能集热反射板；以及生产这种组合物和反射板的工艺。
• METHOD FOR REACTING ETHYLENE/TERAFLUOROETHYLENE COPOLYMER HAVING FUNCTIONAL GROUP
  申请人：Asahi Glass Company, Limited

  公开号：EP2559712A1

  公开（公告）日：2013-02-20

  Provided is a method for efficiently and homogeneously reacting an ETFE having a functional group and a compound having a reactive functional group which can react with the functional group. A method for reacting an ethylene/tetrafluoroethylene copolymer having a functional group, which comprises reacting, in the presence of a solvent which can dissolve the ethylene/tetrafluoroethylene copolymer having a functional group, the ethylene/tetrafluoroethylene copolymer having a functional group and a compound (A) having a reactive functional group which can react with the functional group, in a dissolved state.

  本发明提供了一种使具有官能团的乙烯-四氟乙烯共聚物和具有可与官能团反应的活性官能团的化合物高效、均匀地反应的方法。 一种使具有官能团的乙烯/四氟乙烯共聚物反应的方法，包括在能溶解具有官能团的乙烯/四氟乙烯共聚物的溶剂存在下，使具有官能团的乙烯/四氟乙烯共聚物和具有能与官能团反应的活性官能团的化合物（A）在溶解状态下反应。