(1-cyclohexenyl)diphenylphosphine | 82201-23-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1-cyclohexenyl)diphenylphosphine
• 英文别名: 1-(diphenylphosphino)cyclohexene；cyclohexen-1-yl(diphenyl)phosphane
• CAS: 82201-23-8
• 化学式: C₁₈H₁₉P
• 分子量: 266.323
• InChiKey: LZLSEBUSEBNVDT-UHFFFAOYSA-N

物化性质

• 沸点：
  406.3±24.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (1-cyclohexenyl)diphenylphosphine 在 air 作用下， 生成 cyclohex-1-en-1-yl(diphenyl)phosphine oxide
  参考文献：
  名称：

  光诱导的丙烯酰胺的二溴代磷酸合成三价磷衍生物

  摘要：

  研究了光诱导的烯烃的二溴代磷酸化。合成的溴代烷基膦酸二溴化物的脱氢溴化反应生成相应的二溴膦基烯烃，将其转化为烯基膦酸及其环状酯苯并[1,3,2]二恶唑磷。

  DOI：

  10.1134/s1070363217070131
• 作为产物：
  描述：

  环己酮 在 仲丁基锂 作用下， 反应 2.0h， 生成 (1-cyclohexenyl)diphenylphosphine
  参考文献：
  名称：

  Enephosphinilation

  摘要：

  DOI：

  10.1016/s0040-4039(01)82996-8

文献信息

• Palladium-catalyzed synthesis of vinyl phosphines from ketones
  作者：Scott R. Gilbertson、Zice Fu、Gale W. Starkey

  DOI：10.1016/s0040-4039(99)01819-5

  日期：1999.12

  palladium-catalyzed conversion of vinyl triflates to vinyl phosphines is reported. This process allows for the synthesis of vinyl phosphines from ketones. Selective enolization of a variety of ketones followed by trapping of the enolate as the vinyl triflate is reported. The vinyl triflates are then converted to the corresponding vinyl phosphine through palladium catalysis. The resulting vinyl phosphines can then

  据报道，钯催化的三氟甲基丙烯酸酯转化为乙烯基膦。该方法允许从酮合成乙烯基膦。据报道，对各种酮进行选择性烯醇化，然后随着三氟甲磺​​酸乙烯酯的捕获而捕获烯醇化物。然后通过钯催化将乙烯基三氟甲磺酸酯转化为相应的乙烯基膦。然后可以将所得的乙烯基膦还原为烷基膦。
• Palladacycle-Catalyzed Olefinic C–P Cross-Coupling of Alkenylsulfonium Salts with Diarylphosphines to Access Alkenylphosphines
  作者：Jie Zhu、Yun Ye、Yinhua Huang

  DOI：10.1021/acs.organomet.2c00330

  日期：2022.8.22

  An efficient olefinic C–P cross-coupling of alkenylsulfonium salts with secondary diarylphosphines is reported. The use of a palladacycle enables the facile formation of a C–P bond at the alkenyl moiety of alkenylsulfonium salts tolerating a wide range of functional groups under mild conditions. This protocol provides an easy access to various alkenylphosphine products in good to high yields with high

  报道了烯基锍盐与仲二芳基膦的有效烯烃 C-P 交叉偶联。使用钯环可以在温和条件下耐受多种官能团的烯基锍盐的烯基部分轻松形成 C-P 键。该协议提供了一种以良好至高产率和高水平立体选择性 ( E选择性) 的方式轻松获取各种烯基膦产品的途径。
• Reznikov; Krivchun; Bel'skii, Russian Journal of General Chemistry, 2000, vol. 70, # 7, p. 1032 - 1036
  作者：Reznikov、Krivchun、Bel'skii、Skvortsov

  DOI：——

  日期：——
• Method of Recycling A Recylable Plastic
  申请人：Ramesh Swaminathan

  公开号：US20070083068A1

  公开（公告）日：2007-04-12

  The present invention provides a method of recycling a plastic thereby forming a narrow spectrum of hydrocarbons having from 4 to 14 carbon atoms that can be directly used as gasoline without additional processing or refining. The method includes the step of feeding the plastic, selected from the group of polyethylene, polypropylene, polystyrene, and combinations thereof, into a heated vessel for melting. The method also includes the step of decomposing the plastic at a temperature of from 400° C. to 500° C. in the presence of a metallocene catalyst and a zeolitic catalyst thereby forming the hydrocarbons having from 4 to 14 carbon atoms. The metallocene catalyst includes dichlorobis(2-methylindenyl)zirconium (IV). The zeolitic catalyst includes ammonium Y zeolite and has a pore size of from 1 to 4 Angstroms.
• US7531703B2
  申请人：——

  公开号：US7531703B2

  公开（公告）日：2009-05-12