perchloratetetrakis(triphenylphosphine)copper(I)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: perchloratetetrakis(triphenylphosphine)copper(I)
• 化学式: 4C₁₈H₁₅P*ClO₄*Cu
• 分子量: 1212.16
• InChiKey: VHOAFTKLZHLLRJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  perchloratetetrakis(triphenylphosphine)copper(I) 、 1,2-双(二苯基膦)乙烷 以 乙醇 为溶剂， 以40%的产率得到[Cu(1,2-bis(diphenylphosphanyl)ethane)2](ClO4)
  参考文献：
  名称：

  Synthesis, spectroscopic and structural characterization of adducts of stoichiometry CuX:dppe (1:2) (X=I, ClO4, BH4, O3SCF3, SCN, dppe=Ph2P(CH2)2PPh2)

  摘要：

  Syntheses and spectroscopic features (IR, NMR and ESI MS) are reported for five 1:2 adducts of CuX with dppe (X = I, ClO4, NCS, O3SCF3 (equivalent to tfs) BH4; dppe = Ph2P(CH2)(2)PPh2). ESI MS and P-31 NMR spectroscopy indicate that these species dissociate in solution yielding free diphosphine and 3:2 species. A single crystal X-ray structure determination has been carried out on Cu(dppe)(2)NCS defining a four-coordinate complex of the form [(P,P'-dpex)M(P-dpex)X] for M = Cu, the thiocyanate being N-bound; the ionic [Cu(P,P'-dppe)(2)]tfs has also been structurally characterized. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.046

文献信息

• Bianchini, Claudio; Ghilardi, Carlo A.; Meli, Andrea, Inorganic Chemistry, 1985, vol. 24, # 6, p. 932 - 939
  作者：Bianchini, Claudio、Ghilardi, Carlo A.、Meli, Andrea、Midollini, Stefano、Orlandini, Annabella

  DOI：——

  日期：——
• Synthesis and characterization of derivatives of copper(I) with N- and S-donor ligands
  作者：Claudio Pettinari、Riccardo Pettinari、Maura Pellei、Giancarlo Gioia Lobbia

  DOI：10.1016/s0277-5387(99)00089-3

  日期：1999.5

  New copper(I) complexes of the type [(PBz(3))L3Cu]X, (PBz(3))L2CuX, [(PBz(3))(2)L2Cu]X, [(PBz(3))(3)LCu]X (L=monodentate N-donor imidazole- or pyrazole-type ligand, Bz=benzyl, X=NO3 or ClO4), (PBz(3))(y)(N-N)(x)CuNO3 (N-N=bis(pyrazol-1-yl)methane, x=y=1; N-N=bis(1,2,4-triazol-1-yl)methane, x=y=2), (PPh3)L-2'CuX, (PPh3)(2)L'CuX, [(PPh3)L-3'Cu]X and (PPh3)L'CuX, (L'=monodentate S-donor 1-methyl-imidazoline-2(3H)-thione or imidazoline-2(1,3H)-thione) were obtained from the reaction of (PR3)(n)CuX with the appropriate N- or S-donor ligand. Reaction between [(PPh3)(n)Cu(L)(m)]X with PBz(3) often resulted in the formation of new [(PBz(3))(z)Lm-1Cu]X (z=n or n+1) complexes upon displacement of one molecule of L and two or three molecules of PPh3, whereas reaction of [(N-N)(2)Cu]ClO4 with PBz(3) and 1,10-phenanthroline (Phen) yielded [(PBz(3))(2)CuClO4] and [(Phen)(2)Cu]ClO4, respectively, upon displacement of both molecules of bidentate chelating ligands. No reaction occurred between (PPh3)L-2'CuX, (PPh3)(2)L'CuX or [(PPh3)L-3'Cu]X and PBz(3). All the derivatives obtained were characterized by IR spectroscopy, H-1 NMR, and conductance studies, and in some cases also by molecular weight measurements. (C) 1999 Elsevier Science Ltd. All rights reserved.
• Synthesis, spectroscopic and structural characterization of adducts of stoichiometry CuX:dppe (1:2) (X=I, ClO4, BH4, O3SCF3, SCN, dppe=Ph2P(CH2)2PPh2)
  作者：Corrado di Nicola、Claudio Pettinari、Massimo Ricciutelli、Brian W. Skelton、Neil Somers、Allan H. White

  DOI：10.1016/j.ica.2005.06.046

  日期：2005.9

  Syntheses and spectroscopic features (IR, NMR and ESI MS) are reported for five 1:2 adducts of CuX with dppe (X = I, ClO4, NCS, O3SCF3 (equivalent to tfs) BH4; dppe = Ph2P(CH2)(2)PPh2). ESI MS and P-31 NMR spectroscopy indicate that these species dissociate in solution yielding free diphosphine and 3:2 species. A single crystal X-ray structure determination has been carried out on Cu(dppe)(2)NCS defining a four-coordinate complex of the form [(P,P'-dpex)M(P-dpex)X] for M = Cu, the thiocyanate being N-bound; the ionic [Cu(P,P'-dppe)(2)]tfs has also been structurally characterized. (c) 2005 Elsevier B.V. All rights reserved.