10-Pentyl-10H-phenothiazine | 405298-95-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 10-Pentyl-10H-phenothiazine
• 英文别名: 10-pentylphenothiazine
• CAS: 405298-95-5
• 化学式: C₁₇H₁₉NS
• 分子量: 269.411
• InChiKey: IYGQPCPOLJTIGO-UHFFFAOYSA-N

物化性质

• 沸点：
  395.4±12.0 °C(Predicted)
• 密度：
  1.105±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  28.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  10-Pentyl-10H-phenothiazine 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以87%的产率得到10-Pentyl-10H-phenothiazine 5-oxide
  参考文献：
  名称：

  制备 N- 烷基吩噻嗪亚砜和砜的选择性氧化方法

  摘要：

  DOI：

  10.1515/hc.2001.7.3.277
• 作为产物：
  描述：

  吩噻嗪 、 1-溴戊烷 在 sodium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 生成 10-Pentyl-10H-phenothiazine
  参考文献：
  名称：

  具有不同烷基链长度的AIE活性9,10-双（N-烷基苯硫噻嗪-3-基-乙烯基-2）蒽的压电荧光色性质

  摘要：

  具有不同碳数（n）烷基链的n  ，9,10-双（N-烷基吩噻嗪-3-基-乙烯基-2）蒽（PT - C n）（n = 2，3，5，6，6，7，9，制备12、18）以进一步理解烷基长度对含烷基的9，10-双（芳基乙烯基）蒽的固态荧光和压致变色发光的影响。结果表明，受压和退火的PT - C n的荧光发射都逐渐蓝移，但是随着烷基长度的增加，退火态的蓝移幅度更加显着，从而导致含烷基的PT-更长。ç ñ显示更大的压电氟致变色（PFC）光谱偏移。粉末广角X射线衍射和差示扫描量热法实验表明，在各种外部刺激下晶态和非晶态之间的转变是PFC和恢复行为的原因。这项工作再次证明，结合分子化学结构的简单改变和外部刺激下聚集体形态的物理变化，可以调节某些有机荧光团的固态光学性质。

  DOI：

  10.1016/j.dyepig.2013.10.020

文献信息

• Organophotoreceptor with charge transport material with a hydrazone group linked to a heterocyclic group
  申请人：Jubran Nusrallah

  公开号：US20050095519A1

  公开（公告）日：2005-05-05

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R 1 and R 2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH 2 ) m —, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR 3 group, a CHR 4 group, or a CR 5 R 6 group where R 3 , R 4 , R 5 , and R 6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH 2 ) p — group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR 7 group where R 7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a multivalent structure selected to form n bonds with the corresponding X groups; and Z comprises a heterocyclic group selected from the group consisting of phenothiazine group, phenoxazine group, phenoxathiin group, dibenzo( 1,4 )dioxin group, thianthrene group, and phenazine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

  改进的有机光电受体包括一个电导基板和位于电导基板上的光电导元件，该光电导元件包括：(a) 具有下述结构的电荷传输材料：其中n为2到6之间的整数，包括2和6；R1和R2独立地为H、烷基、烷基芳基或芳基；X为具有下述结构的连接基团：—(CH2)m—，分支或直链，其中m为0到20之间的整数，包括0和20，并且其中一个或多个亚甲基基团可以选择性地被O、S、C═O、O═S═O、杂环基团、芳基、脲基、脲基、酯基、NR3基团、CHR4基团或CR5R6基团所取代，其中R3、R4、R5和R6独立地为H、羟基、硫醇基、烷基、烷基芳基、杂环基团或芳基；Y包括键、C、N、O、S、分支或直链的—(CH2)p—基团，其中p为0到10之间的整数，芳基、环烷基、杂环基团或NR7基团，其中R7为氢原子、烷基或芳基，其中Y具有多价结构，选择性地与相应的X基团形成n个键；Z包括从苯并噻嗪基团、苯氧噻嗪基团、苯氧硫氮基团、二苯并(1,4)二噁嗪基团、噻安三烯基团和苯并噻啉基团中选择的杂环基团；以及(b) 一个电荷生成化合物。描述了相应的静电复印设备和成像方法。
• Polyamine Derivative and Polyol Derivative
  申请人：Mita Naruyoshi

  公开号：US20080230743A1

  公开（公告）日：2008-09-25

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organic material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is a hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括上述任何一种化合物的有机材料稳定剂；一种稳定有机材料的方法；以及稳定的有机材料。通式（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子，烷基，烷氧基或酰基；R4是氢原子或烷基；n是3至16的整数）对于稳定有机材料免受光，热，氧，臭氧和电磁波（如X射线和γ射线）的损害非常有效。
• POLYAMINE DERIVATIVE AND POLYOL DERIVATIVE
  申请人：MITA NARUYOSHI

  公开号：US20120053270A1

  公开（公告）日：2012-03-01

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organinc material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is an hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括任何此类化合物的有机材料稳定剂；一种稳定有机材料的方法；以及一种稳定的有机材料。通式为（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子、烷基、烷氧基或酰基；R4是氢原子或烷基；n是3到16的整数）对于通过光、热、氧、臭氧和电磁波（如X射线和γ射线）恶化的有机材料的稳定化是有效的。
• The use of poly(oxyalkylated) hydrazines as corrosion inhibitors
  申请人：OLIN CORPORATION

  公开号：EP0057991A1

  公开（公告）日：1982-08-18

  Disclosed are selected poly(oxyalkylated) hydrazines of the formula: wherein R is selected from hydrogen, lower alkyl groups having from 1 to 4 carbon atoms, phenyl and mixtures thereof; and the sum of w, x, y, and z is from about 4 to about 20. These compounds are shown to be effective corrosion inhibitors for hydraulic fluids.

  已公开的精选聚（氧烷基化）肼的式为： 其中 R 选自氢、具有 1 至 4 个碳原子的低级烷基、苯基及其混合物；且 w、x、y 和 z 的总和为约 4 至约 20。 这些化合物已证明是液压油的有效腐蚀抑制剂。
• 4-Anilinophenoxy alkoxysilanes and their use as antioxidants
  申请人：OLIN CORPORATION

  公开号：EP0087534A1

  公开（公告）日：1983-09-07

  Disclosed are selected 4-hydroxyphenyl anilino alkoxysilanes of the formula: wherein R is hydrogen or a lower alkyl group having from 1 to 4 carbon atoms and each R' is individually selected from an alkyl group having 3 to 12 carbon atoms with the proviso that at least a majority of said R' radicals are sterically hindered alkyl groups. These compounds are disclosed to be effective antioxidants, especially in functional fluids having shielded polysilicate compounds, silicate esters, or silicone oils as base fluids.

  所公开的是精选的 4-羟基苯基苯胺烷氧基硅烷，其式如下： 其中 R 是氢或具有 1 至 4 个碳原子的低级烷基，每个 R'单独选自具有 3 至 12 个碳原子的烷基，但条件是所述 R'基中至少大部分是立体受阻烷基。 这些化合物是有效的抗氧化剂，特别是在以屏蔽聚硅酸化合物、硅酸酯或硅油为基础油的功能性液体中。