1-(4-bromophenyl)-2,5,8,11-tetraoxadodecane | 1206833-00-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-bromophenyl)-2,5,8,11-tetraoxadodecane
• 英文别名: 1-bromo-4-[[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]methyl]benzene；1-Bromo-4-[2-[2-(2-methoxyethoxy)ethoxy]ethoxymethyl]benzene；1-bromo-4-[2-[2-(2-methoxyethoxy)ethoxy]ethoxymethyl]benzene
• CAS: 1206833-00-2
• 化学式: C₁₄H₂₁BrO₄
• mdl: MFCD26319307
• 分子量: 333.222
• InChiKey: FUWKAKMONIPOOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.571
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(4-bromophenyl)-2,5,8,11-tetraoxadodecane 在 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 、 sodium hydroxide 作用下， 以 四氢呋喃 、 乙二醇乙醚 、 乙醇 、 正己烷 、 水 、 甲苯 为溶剂， 反应 50.0h， 生成 4-(3,6-bis(4-2,5,8,11-tetraoxadodecylphenyl)-9H-carbazole-9-yl)benzoic acid
  参考文献：
  名称：

  Compounds having hole conducting property, co-adsorbent body comprising same, and dye-sensitized solar cell comprising the co-adsorbent body

  摘要：

  公开号：

  EP2711359B1
• 作为产物：
  描述：

  三甘醇单甲醚 、 对溴溴苄 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 6.5h， 以91%的产率得到1-(4-bromophenyl)-2,5,8,11-tetraoxadodecane
  参考文献：
  名称：

  Significance of Hydrophilic Characters of Organic Dyes in Visible-Light Hydrogen Generation Based on TiO₂

  摘要：

  A series of dyes were synthesized to examine the roles of the hydrophilic characteristics of R in sensitized hydrogen generation by dyegrafted Pt/TiO2 under visible light irradiation. The hydrogen-generation efficiencies and optimum amounts of the dyes grafted to Pt/TiO2 were affected substantially by the hydrophilic and steric effects of R; moderately hydrophilic DEO1 and DEO2 showed higher sensitization activity at a lower loading than hydrophobic D-H.

  DOI：

  10.1021/ol9026182

文献信息

• COMPOUNDS HAVING HOLE CONDUCTING PROPERTY, CO-ADSORBENT BODY COMPRISING SAME, AND DYE-SENSITIZED SOLAR CELL COMPRISING THE CO-ADSORBENT BODY
  申请人：Korea University Research and Business Foundation

  公开号：EP2712859B1

  公开（公告）日：2016-11-09
• Compound having hole conducting property, co-adsorbent body comprising same, and dye-sensitized solar cell comprising the co-adsorbent body
  申请人：Korea University Research and Business Foundation

  公开号：EP2712860B1

  公开（公告）日：2016-02-24
• Significance of Hydrophilic Characters of Organic Dyes in Visible-Light Hydrogen Generation Based on TiO₂
  作者：Su-Hyun Lee、Yiseul Park、Kyung-Ryang Wee、Ho-Jin Son、Dae Won Cho、Chyongjin Pac、Wonyong Choi、Sang Ook Kang

  DOI：10.1021/ol9026182

  日期：2010.2.5

  A series of dyes were synthesized to examine the roles of the hydrophilic characteristics of R in sensitized hydrogen generation by dyegrafted Pt/TiO2 under visible light irradiation. The hydrogen-generation efficiencies and optimum amounts of the dyes grafted to Pt/TiO2 were affected substantially by the hydrophilic and steric effects of R; moderately hydrophilic DEO1 and DEO2 showed higher sensitization activity at a lower loading than hydrophobic D-H.
• Compounds having hole conducting property, co-adsorbent body comprising same, and dye-sensitized solar cell comprising the co-adsorbent body
  申请人：Korea University Research and Business Foundation

  公开号：EP2711359B1

  公开（公告）日：2016-02-24