2,2-bis (3-methyl-4-aminophenyl)-propane | 3283-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis (3-methyl-4-aminophenyl)-propane
• 英文别名: 2,2-bis-(4-amino-3-methyl-phenyl)-propane；2,2-Bis-(4-amino-3-methyl-phenyl)-propan；4.4'-Diamino-3.3'.α.α-tetramethyl-diphenylmethan；2,2-bis-(3'-methyl-4'-aminophenyl)propane；2,2-bis (3-methyl-4-aminophenyl) propane；2,2-bis(3'-methyl-4'-aminophenyl)propane；4-[2-(4-Amino-3-methylphenyl)propan-2-yl]-2-methylaniline
• CAS: 3283-01-0
• 化学式: C₁₇H₂₂N₂
• 分子量: 254.375
• InChiKey: UBKRDXUXTYBRHS-UHFFFAOYSA-N

物化性质

• 沸点：
  185-190 °C(Press: 0.1 Torr)
• 密度：
  1.060±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  2,2-bis (3-methyl-4-aminophenyl)-propane 生成 2,2-bis-(4-acetylamino-3-methyl-phenyl)-propane
  参考文献：
  名称：

  v. Braun, Justus Liebigs Annalen der Chemie, 1933, vol. 507, p. 14,22

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲基苯胺 盐酸盐 、 丙酮 在 水 作用下， 生成 2,2-bis (3-methyl-4-aminophenyl)-propane
  参考文献：
  名称：

  DE399149

  摘要：

  公开号：

文献信息

• ACETYLENE COMPOUND, SALT THEREOF, CONDENSATE THEREOF, AND COMPOSITION THEREOF
  申请人：Fujifilm Corporation

  公开号：EP2202220A1

  公开（公告）日：2010-06-30

  [Problem to be Solved] To provide an acetylene compound having a structure in which a unit having an amino group and a unit having an ethynyl group are bonded via a linking group, the acetylene compound being introducable to a polymer having thermal resistance. [Means for Solving the Problem] An acetylene compound represented by the following Formula (1) and a salt thereof: wherein in Formula (1), X represents a single bond or a divalent linking group; A represents a hydrocarbon group, a heteroaromatic ring or a heteroalicyclic compound; B represents a hydrocarbon group, a heteroaromatic ring, a heteroalicyclic compound or a single bond; R1 represents a hydrogen atom, a hydrocarbon group, a heteroaromatic ring, a heteroalicyclic compound or a silyl group; R4 represents a hydrogen atom or a group that can be a substituent of an amino group; and m, n and a each independently represent an integer of 1 or greater.

  解决的问题是提供一种乙炔化合物，其结构中含有通过连接基团连接的具有氨基团和乙炔基团的单元，该乙炔化合物可引入到具有热阻抗的聚合物中。解决问题的方法是通过以下式（1）表示的乙炔化合物及其盐：其中在式（1）中，X代表单键或二价连接基团；A代表烃基团、杂环芳香环或杂环脂环化合物；B代表烃基团、杂环芳香环、杂环脂环化合物或单键；R1代表氢原子、烃基团、杂环芳香环、杂环脂环化合物或硅基团；R4代表氢原子或可作为氨基团的取代基团；m、n和a分别独立表示大于或等于1的整数。
• PHOTOSENSITIVE RESIN COMPOSITION, POLYAMIDE RESIN, METHOD FOR PRODUCING POLYAMIDE RESIN, COMPOUND, METHOD FOR PRODUCING COMPOUND, METHOD FOR PRODUCING CURED FILM, AND CURED FILM
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20180107114A1

  公开（公告）日：2018-04-19

  A photosensitive resin composition capable of forming a cured film with satisfactory adhesion to substrates and excellent transparency, a polyamide resin which is used in the photosensitive resin composition, a method for producing the polyamide resin, a compound which is used as a raw material of the polyamide resin, a method for producing the compound, a method for producing a cured film using the photosensitive resin composition, and a cured film which is obtained by curing the photosensitive resin composition. The photosensitive resin composition including a resin and a photopolymerization initiator. The resin is a polyamide resin including a structural unit, which includes a specific saturated alicyclic skeleton, and at least one carboxy group esterified by a unit containing a polymerizable group of a predetermined structure.

  一种具有良好粘附性和优异透明度的光敏树脂组合物，用于形成固化膜，其中包括用于光敏树脂组合物的聚酰胺树脂，制备聚酰胺树脂的方法，用作聚酰胺树脂原料的化合物，制备该化合物的方法，使用光敏树脂组合物制备固化膜的方法，以及通过固化光敏树脂组合物获得的固化膜。光敏树脂组合物包括树脂和光聚合引发剂。该树脂是一种聚酰胺树脂，包括结构单元，其中包括特定的饱和脂环骨架，以及至少一个由具有预定结构的可聚合基含有的单元酯化的羧基。
• PROCESS AND APPARATUS FOR PRODUCTION OF COLORLESS TRANSPARENT RESIN FILM
  申请人：OISHI Jitsuo

  公开号：US20100187719A1

  公开（公告）日：2010-07-29

  A method for producing a colorless transparent resin film by a solution flow casting method containing: flow-casting an organic solvent solution of a polyamic acid or a polyimide on a support; and drying, the method containing at least the following step (1), step (2) and step (3) in this order, and an apparatus therefor: (1) a step of flow-casting an organic solvent solution of a polyamic acid or polyamide on a support, (2) a step of evaporating the organic solvent while blowing a gas having an oxygen content of from 0.001 to 15% by volume at a temperature of from 100 to 170° C. onto the flow-cast material, and releasing as a self-supporting film from the support, and (3) a step of performing the following step (3-1) and step (3-2) in this order: (3-1) a step of lowering a residual ratio of the organic solvent in the self-supporting film while blowing a gas having an oxygen content of 15% by volume or less at a temperature of from 100 to 250° C. onto the film by using at least one dryer of a type of blowing a heated gas, and (3-2) a step of lowering the residual ratio of the organic solvent in the self-supporting film while blowing a gas having an oxygen content of 5% by volume or less at a temperature of from 150 to 400° C. onto the film by using at least one dryer of a type of blowing a heated gas.

  一种通过溶液流铸法制备无色透明树脂薄膜的方法，包括：在支撑物上流铸聚酰胺酸或聚酰亚胺的有机溶剂溶液；并干燥，该方法至少包括以下步骤（1）、步骤（2）和步骤（3），并提供相应的设备：(1)在支撑物上流铸聚酰胺酸或聚酰亚胺的有机溶剂溶液；(2)在向流铸材料吹送氧含量为0.001至15%体积的气体的同时，蒸发有机溶剂，温度在100至170°C之间，从支撑物上释放为自支撑膜；(3)按照以下步骤（3-1）和步骤（3-2）的顺序执行：(3-1)在使用至少一种吹送加热气体的干燥器的情况下，以15%体积以下的氧含量的气体在100至250°C的温度下吹送，降低自支撑膜中有机溶剂的残留比率；(3-2)在使用至少一种吹送加热气体的干燥器的情况下，以5%体积以下的氧含量的气体在150至400°C的温度下吹送，降低自支撑膜中有机溶剂的残留比率。
• Verfahren zur Herstellung von Bis(aminocyclohexyl)dialkylmethanen
  申请人：BASF Aktiengesellschaft

  公开号：EP0099516A1

  公开（公告）日：1984-02-01

  Verfahren zur Herstellung von Bis(aminocyclohexyl)dial- kylmethanen der allgemeinen Formel in der R1 und R2 gleich oder verschieden sein können und eine niedere Alkylgruppe und R3 ein Wasserstoffatom oder eine niedere Alkylgruppe bedeuten, wobei die beiden Cyclohexanringe gegebenenfalls substituiert sein können, durch Kondensation von in para-Stellung unsubstituierten Anilinen mit niederen aliphatischen Ketonen, in Gegenwart einer starken Säure und nachfolgende Hydrierung der so erhaltenen Produkte, in Gegenwart von Ruthenium enthaltenden Katalysatoren.

  通式为双(氨基环己基)二甲酰甲烷的制备工艺 其中 R1 和 R2 可以相同或不同，代表低级烷基，R3 是氢原子或低级烷基。 R3 是氢原子或低级烷基，在强酸存在下，通过在对位未被取代的苯胺与低级脂族酮缩合，然后在含钌催化剂存在下对由此得到的产物进行氢化，可以使两个环己烷环被选择性取代。
• Thermosetting resin composition
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0290860A2

  公开（公告）日：1988-11-17

  A thermosetting resin composition polyfunctional cyanate ester resin composition comprising: (I) a cyanate ester compound selected from the group consisting of a polyfunctional cyanate ester having at least two cyanate esters in its molecule, a prepolymer of such a cyanate ester and mixtures thereof; and (II) at least one non-branched aromatic compound in an amount of 5 - 40% by weight of the total resin composition, said aromatic compound having a number-average molecular weight of 178 - 800, an average number of aromatic nuclei of 2 - 6, and a boiling point of more than 300°C, and in which the portion having aromatic nuclei of 2 - 6 constitutes more than 50% is disclosed.

  一种热固性树脂组合物多官能团氰酸酯树脂组合物，包括 (I) 氰酸酯化合物，选自由其分子中至少含有两种氰酸酯的多官能团氰酸酯、氰酸酯预聚 物及其混合物组成的组；以及 (II) 至少一种非支链芳香族化合物，其用量占树脂组合物总量的 5-40%（按重量计），所述芳香族化合物的数均分子量为 178-800，芳香核的平均数目为 2-6，沸点超过 300°C，其中芳香核数目为 2-6 的部分占 50%以上。