4-decyl-4'-hydroxybiphenyl | 113248-05-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-decyl-4'-hydroxybiphenyl
• 英文别名: 4'-decyl-4-hydroxybiphenyl；4-(4-decylphenyl)phenol
• CAS: 113248-05-8
• 化学式: C₂₂H₃₀O
• 分子量: 310.48
• InChiKey: BBHSUIZJYYOAND-UHFFFAOYSA-N

物化性质

• 沸点：
  440.6±24.0 °C(Predicted)
• 密度：
  0.976±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-decyl-4'-hydroxybiphenyl 在 4-二甲氨基吡啶 、 4-甲基苯磺酸吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 水 、 丙酮 为溶剂， 反应 53.0h， 生成 (4'-decylbiphenyl-4-yl)-4-hydroxybenzoate
  参考文献：
  名称：

  Synthesis of novel chiral dopants based on optically active p-substituted mandelic acids

  摘要：

  Novel esters of optically active p-substituted mandelic acids (+)-1 and (+)-2 were prepared by a convergent synthetic strategy in high enantiomeric excess (99% ee). The esters (+)-1 and (+)-2 induce helical macrostructures in the mesophases of achiral liquid-crystal materials, although neither exhibits mesorphism on its own. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(03)00576-7
• 作为产物：
  描述：

  癸基苯 在 溴 、 碘 、 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 4-decyl-4'-hydroxybiphenyl
  参考文献：
  名称：

  Synthesis of novel chiral dopants based on optically active p-substituted mandelic acids

  摘要：

  Novel esters of optically active p-substituted mandelic acids (+)-1 and (+)-2 were prepared by a convergent synthetic strategy in high enantiomeric excess (99% ee). The esters (+)-1 and (+)-2 induce helical macrostructures in the mesophases of achiral liquid-crystal materials, although neither exhibits mesorphism on its own. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(03)00576-7

文献信息

• Liquid crystal compound
  申请人：Showa Shell Sekiyu Kabushiki Kaisha

  公开号：US05207947A1

  公开（公告）日：1993-05-04

  Liquid crystal compound of the formula ##STR1## wherein R.sub.1 and R.sub.2 each is a C.sub.1-18 alkyl group or an aralkyl group, R' is a haloalkyl group, X is --0--, --CO--, --COO-- or direct bond, Y is --COO--, --OCO-- or --CH.sub.2 O--, (A) and (B) each is ##STR2## and p and l each is zero or one.

  液晶化合物的公式为##STR1##，其中R1和R2各自是C1-18烷基或芳烷基，R'是卤代烷基，X是-0-，-CO-，-COO-或直接键，Y是-COO-，-OCO-或-CH2O-，（A）和（B）各自是##STR2##，p和l各自是零或一。
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, COMPOSITION FOR OPTICAL FILM, AND OPTICAL FILM, COMPENSATION FILM, ANTIREFLECTIVE FILM, AND DISPLAY DEVICE INCLUDING THE SAME
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170183286A1

  公开（公告）日：2017-06-29

  A polymerizable liquid crystal compound represented by Chemical Formula 1: wherein in Chemical Formula 1, groups and variables are the same as defined in the detailed description.

  化学式1所代表的可聚合液晶化合物： 在化学式1中，基团和变量与详细描述中定义的相同。
• Ferroelectric-like behaviour of the SmCP phase in liquid crystalline compounds with asymmetrical bent-core molecules
  作者：V. Novotná、M. Kašpar、V. Hamplová、M. Glogarová、L. Lejček、J. Kroupa、D. Pociecha

  DOI：10.1039/b601084a

  日期：——

  A new series of asymmetrical bent-shaped mesogens has been synthesised and their mesomorphic properties studied. All compounds exhibit the B2 (SmCP) phase. For some compounds we found a very low coercive field for switching to the saturated ferroelectric state and only one peak in the switching current. Due to the lack of SHG signal in the zero field state and the behaviour of the relaxation mode we cannot unambiguously assign ferroelectric or antiferroelectric character to the B2 phase observed. The observation of planar samples revealed a striped texture. Large optically active domains appear on very slow cooling, which are attributed to a non-homogeneous (twisted) in-plane structure imposed by surfaces. The twisted domains are suppressed under a critical electric field. A simple model of such a structure and its behavior in the electric field is proposed. The low temperature phase detected on further cooling is attributed to a crystalline-like smectic phase.

  我们合成了一系列新的不对称弯曲状介质，并研究了它们的介质性质。所有化合物都呈现出 B2（SmCP）相。对于某些化合物，我们发现切换到饱和铁电态的矫顽力场非常低，而且切换电流只有一个峰值。由于在零磁场状态下缺乏 SHG 信号以及弛豫模式的行为，我们无法明确地为观察到的 B2 相赋予铁电或反铁电特性。对平面样品的观察显示出一种条状纹理。在非常缓慢的冷却过程中会出现大的光学活性畴，这归因于表面施加的非均质（扭曲）面内结构。在临界电场下，扭曲畴被抑制。本文提出了这种结构及其在电场中行为的简单模型。在进一步冷却时检测到的低温相归因于类似晶体的胶凝相。
• Mesomorphic compound, liquid crystal composition, liquid crystal device,
  申请人：Canon Kabushiki Kaisha

  公开号：US05385692A1

  公开（公告）日：1995-01-31

  A mesomorphic compound of the formula (I) according to claim 1 is suitable as a component for liquid crystal composition providing improved response characteristics.

  根据第1项要求，化学式为(I)的介向化合物适用作液晶组分，可提供改善的响应特性。
• Liquid crystal compounds having naphthalene nucleus
  申请人：Showa Shell Sekiyu Kabushiki Kaisha

  公开号：EP0339987A2

  公开（公告）日：1989-11-02

  Novel ferroelectric liquid crystal compounds which may realize a stable molecular orientation which makes it possible to give a definite light-dark contrast in the no electric field state and attain a definite threshold property as well as hysterisis, and for making it possible to attain the dynamic drivinng as well as the high speed of response, owing to tri-stable phase thereof, of the general formulae (I) and (II) in which R₁ means an alkyl, alkoxy or alkyloxycarbonyl each of 1-20 carbon atoms, R₂ means optically active

  通式(I)和(II)的新型铁电液晶化合物，其可实现稳定的分子取向，从而有可能在无电场状态下产生明确的明暗对比，并获得明确的阈值特性以及滞后性，并且由于其三相稳定，有可能获得动态驱动以及高速响应。 其中 R₁ 指烷基、烷氧基或烷氧基羰基，每个烷氧基羰基含有 1-20 个碳原子，R₂ 指光学活性物质