申请人:National Starch and Chemical Investment
Holding Corporation
公开号:EP0213317A2
公开(公告)日:1987-03-11
A self-crosslinking polymer consisting essentially of at least 1 mole % of a halohydrin monomer, at least 1 mole % of a tertiary or secondary amine salt monomer, and 0-98 mole % of a vinyl polymerizable monomer other than the halohydrin or amine salt monomers crosslinks, in the presence of a base, at a lower temperature than a polymer without the tertiary or secondary amine salt monomer. Typical polymers contain 3-chloro-2-hydroxypropyl acrylate or methacrylate; diallylamine hydrochloride, N-isopropyl methacrylamide hydrogen sulfate, dimethylaminopropyl methacrylamide, or dimethylaminoethyl methacrylate hydrochloride or acetate; and optionally other monomers such as a vinyl ester, an acrylate, or a dialkyl diallyl ammonium chloride. When the polymers contain a conductive cationic monomer such as dimethyl diallyl ammonium chloride, they are useful as electroconductive coatings for paper substrates. An adduct of epichlorohydrin and dimethylaminopropyl methacrylamide or dimethylaminoethyl methacrylate may be used in place of the 3-chloro-2-hydrodxypropyl acrylate or methacrylate for the electroconductive coatings.
一种自交联聚合物主要由至少 1 摩尔%的卤代醇单体、至少 1 摩尔%的叔胺盐或仲胺盐单体和 0-98 摩尔%的乙烯基可聚合单体(卤代醇或胺盐单体除外)组成,在碱存在下,其交联温度低于不含叔胺盐或仲胺盐单体的聚合物。典型的聚合物包含 3-氯-2-羟丙基丙烯酸酯或甲基丙烯酸酯;二烯丙基胺盐酸盐、N-异丙基甲基丙烯酰胺硫酸氢盐、二甲基氨基丙基甲基丙烯酰胺或甲基丙烯酸二甲氨基乙酯盐酸盐或醋酸盐;以及可选的其他单体,如乙烯基酯、丙烯酸酯或二烷基二烯丙基氯化铵。当聚合物含有导电阳离子单体(如二甲基二烯丙基氯化铵)时,可用作纸基材的导电涂层。在导电涂料中,可以使用环氧氯丙烷和甲基丙烯酰胺二甲胺基丙酯或甲基丙烯酸二甲胺基乙酯的加合物来代替 3-氯-2-羟基丙基丙烯酸酯或甲基丙烯酸酯。