9-[2'-(3"-indenyl)-1'-naphthyl]fluorene | 512786-31-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-[2'-(3"-indenyl)-1'-naphthyl]fluorene
• 英文别名: sp-9-[2'-(3''-indenyl)-1'-naphthyl]fluorene；9-[2-(3H-inden-1-yl)naphthalen-1-yl]-9H-fluorene
• CAS: 512786-31-1
• 化学式: C₃₂H₂₂
• 分子量: 406.527
• InChiKey: QZXKUWPIFCURRI-UHFFFAOYSA-N

物化性质

• 沸点：
  612.8±50.0 °C(Predicted)
• 密度：
  1.227±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氯化锆(IV) 、 9-[2'-(3"-indenyl)-1'-naphthyl]fluorene 在 n-butyllithium 作用下， 以 苯 为溶剂， 以55%的产率得到[1'-(9-fluorenyl)-2'-(1''-indenyl)naphthalene]zirconium dichloride
  参考文献：
  名称：

  Zirconocene dichloride complexes with a 1,2-naphthylidene bridge as catalysts for the polymerisation of ethylene and propylene

  摘要：

  Ansa-zirconocene dichloride complexes containing a 9-fluorenyl group at the 1-position of naphthalene and a 2-indenyl 12, 1-indenyl 13, or cyclopentadienyl 14 group at the 2-position of the naphthalene were synthesised and characterised. The molecular structures of the complexes have been determined by single crystal X-ray diffraction studies. After activation with excess methyl-alumoxane (MAO). the complexes were used as homogeneous catalysts for the homopolymerisation of ethylene and propylene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.021
• 作为产物：
  描述：

  1-溴-2-(2-氯乙基)苯 在 对甲苯磺酸 magnesium 、 1,2-二溴乙烷 作用下， 以 四氢呋喃 、 苯 为溶剂， 反应 22.0h， 生成 9-[2'-(3"-indenyl)-1'-naphthyl]fluorene
  参考文献：
  名称：

  通过邻-（β-镁烷基）苯基二卤化镁与羧酸酯反应的新方法合成3-取代-1 H-茚

  摘要：

  通过邻-（β-镁烷基烷基）苯基二卤化镁与羧酸酯的反应，然后使中间的1-取代-1-茚满醇脱水，开发了3-取代-1 H-茚的新合成方法。已经制备了允许合成3-取代的，2-甲基-3-取代的和4-甲基-3-取代的-1 H-茚的二格里纳试剂，两步序列的总产率为45至95％。

  DOI：

  10.1016/s0040-4039(02)02344-4

文献信息

• A new synthesis of 3-substituted-1H-indenes through reaction of o-(β-magnesioalkyl)phenylmagnesium dihalides with carboxylate esters
  作者：Robert W. Baker、Michael A. Foulkes、Michael Griggs、Bao N. Nguyen

  DOI：10.1016/s0040-4039(02)02344-4

  日期：2002.12

  A new synthesis of 3-substituted-1H-indenes has been developed through the reaction of o-(β-magnesioalkyl)phenylmagnesium dihalides with carboxylate esters, followed by dehydration of the intermediate 1-substituted-1-indanols. Di-Grignard reagents allowing the synthesis of 3-substituted-, 2-methyl-3-substituted-, and 4-methyl-3-substituted-1H-indenes have been prepared, with overall yields for the

  通过邻-（β-镁烷基烷基）苯基二卤化镁与羧酸酯的反应，然后使中间的1-取代-1-茚满醇脱水，开发了3-取代-1 H-茚的新合成方法。已经制备了允许合成3-取代的，2-甲基-3-取代的和4-甲基-3-取代的-1 H-茚的二格里纳试剂，两步序列的总产率为45至95％。
• Zirconocene dichloride complexes with a 1,2-naphthylidene bridge as catalysts for the polymerisation of ethylene and propylene
  作者：Helmut G Alt、Robert W Baker、Mahmoud Dakkak、Michael A Foulkes、Marc O Schilling、Peter Turner

  DOI：10.1016/j.jorganchem.2004.03.021

  日期：2004.6

  Ansa-zirconocene dichloride complexes containing a 9-fluorenyl group at the 1-position of naphthalene and a 2-indenyl 12, 1-indenyl 13, or cyclopentadienyl 14 group at the 2-position of the naphthalene were synthesised and characterised. The molecular structures of the complexes have been determined by single crystal X-ray diffraction studies. After activation with excess methyl-alumoxane (MAO). the complexes were used as homogeneous catalysts for the homopolymerisation of ethylene and propylene. (C) 2004 Elsevier B.V. All rights reserved.