hexadecane-1,15-diol | 99706-69-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexadecane-1,15-diol
• 英文别名: 1,16-hexadecanediol；1,15-Dihydroxy-hexadecan；1,15-Hexadecanediol
• CAS: 99706-69-1
• 化学式: C₁₆H₃₄O₂
• 分子量: 258.445
• InChiKey: SNEHHJRJHVGAII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  18
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  hexadecane-1,15-diol 在 ruthenium(IV) oxide 、 sodium chloride 作用下， 以 四氯化碳 、 水 为溶剂， 生成 15-oxohexadecanoic acid
  参考文献：
  名称：

  Indirect electrooxidation of alcohols and aldehydes by using a double mediatory system consisting of ruthenium tetraoxide/ruthenium dioxide and chlorine cation/chlorine anion redoxes in an aqueous-organic two-phase system

  摘要：

  DOI：

  10.1021/jo00352a006

文献信息

• ——
  作者：Gary N. Ross、Henry M. Fales、Helen A. Lloyd、Tappey Jones、Edward A. Sokoloski、Kimberly Marshall-Batty、Murray S. Blum

  DOI：10.1023/a:1010372114144

  日期：——

  Abdominal defensive glands of both sexes of the Gulf fritillary butterfly, Agraulis vanillae (Linnaeus) (Nymphalidae:Heliconiinae) emit a pronounced odor when disturbed. We have identified 6-methyl-5-hepten-2-one; oleic, palmitic, and stearic esters of the corresponding alcohol 6-methyl-5-hepten-2-ol; hexadecyl acetate; 1,16-hexadecanediol diacetate; and 1,15-hexadecanediol diacetate in the glandular exudate. Since we have determined that free-flying birds or birds in a butterfly conservatory discriminate against A. vanillae as prey, we suggest that the constituents in the glands may play a defensive role against potential avian predators.