(3R,6E)-3-acetoxy-7-methyl-6-nonene | 100429-35-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (3R,6E)-3-acetoxy-7-methyl-6-nonene
• 英文别名: (R)-quadrilure；quadrilure；Qrzwifridcaack-zjnqmxkesa-；[(E,3R)-7-methylnon-6-en-3-yl] acetate
• CAS: 100429-35-4
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: QRZWIFRIDCAACK-ZJNQMXKESA-N

物化性质

• 沸点：
  63-64 °C(Press: 13 Torr)
• 密度：
  0.885±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-戊烯酸,3-甲基-,(E)- 在 吡啶 、 sodium hydroxide 、 lithium aluminium tetrahydride 、 phosphate buffer 、 Lipase PS 、 magnesium ethylate 、 三溴化磷 、 sodium hydride 、 碘甲烷 作用下， 以 乙醚 、 乙醇 、 丙酮 为溶剂， 反应 91.0h， 生成 (3R,6E)-3-acetoxy-7-methyl-6-nonene
  参考文献：
  名称：

  Naoshima, Yoshinobu; Munakata, Yoshihito; Funai, Akio, Bioscience, Biotechnology and Biochemistry, 1992, vol. 56, # 6, p. 999 - 1000

  摘要：

  DOI：

文献信息

• A versatile and convenient protocol for the stereocontrolled synthesis of olefinic insect pheromones
  作者：Andrei A. Vasil'ev、Alexei L. Vlasyuk、Galina D. Gamalevich、Edward P. Serebryakov

  DOI：10.1016/0968-0896(96)00016-8

  日期：1996.3

  supplemented by an enzymatic hydrolysis, was successfully applied to the synthesis of configurationally pure (gp > or = 98%) pheromones of the furniture carpet beetle, dry bean beetle, rusty grain beetle, square-necked grain beetle and a trail-following pheromone mimic for subterranean termites.

  2,4-二烯酸烷基酯的Horner-Emmons合成与在复杂的L.Cr（CO）3催化剂（L = 3CO或芳烃）上的氢化反应相结合，提供了一种通用的，立体控制的且操作简单的方法（Z）-二取代的（Z）-三取代的（E）-三取代的烯烃和跳过的（Z，Z）-二取代的二烯烃具有均聚物类型的功能。该方案，有时还辅以酶促水解，已成功地应用于家具地毯甲虫，干豆甲虫，生锈的谷物甲虫，方颈谷物甲虫和小径的构型纯（gp>或= 98％）信息素的合成信息素模仿地下白蚁。
• Mori, Kenji; Puapoomchareon, Prapai, Liebigs Annalen der Chemie, 1990, # 2, p. 159 - 162
  作者：Mori, Kenji、Puapoomchareon, Prapai

  DOI：——

  日期：——
• MORI, KENJI;PUAPOOMCHAREON, PRAPAI, LIEBIGS ANN. CHEM.,(1990) N, C. 159-162
  作者：MORI, KENJI、PUAPOOMCHAREON, PRAPAI

  DOI：——

  日期：——
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.
• Naoshima, Yoshinobu; Munakata, Yoshihito; Funai, Akio, Bioscience, Biotechnology and Biochemistry, 1992, vol. 56, # 6, p. 999 - 1000
  作者：Naoshima, Yoshinobu、Munakata, Yoshihito、Funai, Akio

  DOI：——

  日期：——