2-甲基丙-2-烯基己酸酯 | 86143-85-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-甲基丙-2-烯基己酸酯
• 英文名称: hexanoic acid methallyl ester
• 英文别名: Hexansaeure-methallylester；2-Methylprop-2-EN-1-YL hexanoate；2-methylprop-2-enyl hexanoate
• CAS: 86143-85-3
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: IYEWGCASUHFCSS-UHFFFAOYSA-N

物化性质

• 沸点：
  213.7±9.0 °C(Predicted)
• 密度：
  0.886±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Methallyl alcohol trichloroacetate 、 己酸 在 18-冠醚-6 、 potassium carbonate 作用下， 反应 2.0h， 以85%的产率得到2-甲基丙-2-烯基己酸酯
  参考文献：
  名称：

  Renga, James M.; Wang, Pen-Chung, Synthetic Communications, 1984, vol. 14, # 1, p. 77 - 82

  摘要：

  DOI：

文献信息

• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• Instantaneously curable composition
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0206544A2

  公开（公告）日：1986-12-30

  A curable composition comprises (A) a polymer whose molecules have a main chain comprising carbon-carbon bonds and one or more isocyanatocarbonyl groups pendant to the main chain, the content of the isocyanatocarbonyl groups per polymer molecule being from 0.1 to 72.2% by weight, and (B) an active hydrogen atom-containing compound. Various polymers of the given type, including polymers having pendant isocyanatocarbonyl and/or isocyanato groups, are novel.

  一种可固化组合物包括：(A) 聚合物，其分子主链由碳-碳键组成，主链上有一个或多个 异氰酸羰基，每个聚合物分子中异氰酸羰基的含量为 0.1%至 72.2%（按重量计）；(B) 含 有活性氢原子的化合物。上述类型的各种聚合物，包括具有悬垂异氰酸羰基和/或异氰酸基的聚合物，都是新颖的。
• Functional polymers and their production
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0207621A2

  公开（公告）日：1987-01-07

  A functional polymer whose molecules have a main chain of carbon-carbon bonds and one or more pendant functional groups each appended to the main chain via a carbonyliminocarbonyl linkage, in which the or each functional group is chosen from fluorinated, aminotriazine, photosensitive, bicyclic and spiro structure-containing groups, and in which the content of the functional groups plus the carbonyliminocarbonyl linkages per molecule is from 0.1 to 99.9% by weight.

  一种功能性聚合物，其分子具有由碳-碳键组成的主链和一个或多个通过羰基亚氨基羰基连接附着在主链上的悬挂官能团，其中的官能团或每个官能团选自氟化、氨基三嗪、光敏、双环和含螺结构的基团，每个分子的官能团和羰基亚氨基羰基连接的含量按重量计为 0.1 至 99.9%。
• RESIN AND SURFACE PROTECTION PLATE OR AUTOMOTIVE MATERIAL
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：EP3327052A1

  公开（公告）日：2018-05-30

  Provided is a resin including both a structural unit derived from a monomer having a carbon-carbon double bond at a terminal thereof and a structural unit derived from a polyrotaxane compound, wherein the polyrotaxane compound is a compound substituted with a (meth)acryloyl group or a group containing a (meth)acryloyl group, the polyrotaxane includes optionally substituted cyclodextrin, a linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and a capping group for preventing the optionally substituted cyclodextrin from leaving, the capping group being located at a terminal of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and the weight average molecular weight of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape is greater than or equal to 21000 and less than or equal to 500000.

  本发明提供了一种树脂，该树脂包括衍生自末端具有碳碳双键的单体的结构单元和衍生自聚二十六烷化合物的结构单元，其中聚二十六烷化合物是被(甲基)丙烯酰基或含有(甲基)丙烯酰基的基团取代的化合物，聚二十六烷包括任选取代的环糊精、呈串状凝集在任选取代的环糊精中的线性分子以及用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状凝集在任选取代的环糊精中的线性分子的末端、和用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状包覆在任选取代的环糊精中的线性分子的末端，且呈串状包覆在任选取代的环糊精中的线性分子的重量平均分子量大于或等于 21000，小于或等于 500000。
• Resin and surface protective plate or automotive material
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US10647784B2

  公开（公告）日：2020-05-12

  Provided is a resin including both a structural unit derived from a monomer having a carbon-carbon double bond at a terminal thereof and a structural unit derived from a polyrotaxane compound, wherein the polyrotaxane compound is a compound substituted with a (meth)acryloyl group or a group containing a (meth)acryloyl group, the polyrotaxane includes optionally substituted cyclodextrin, a linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and a capping group for preventing the optionally substituted cyclodextrin from leaving, the capping group being located at a terminal of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and the weight average molecular weight of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape is greater than or equal to 21000 and less than or equal to 500000.

  本发明提供了一种树脂，该树脂包括衍生自末端具有碳碳双键的单体的结构单元和衍生自聚二十六烷化合物的结构单元，其中聚二十六烷化合物是被(甲基)丙烯酰基或含有(甲基)丙烯酰基的基团取代的化合物，聚二十六烷包括任选取代的环糊精、呈串状凝集在任选取代的环糊精中的线性分子以及用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状凝集在任选取代的环糊精中的线性分子的末端、和用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状包覆在任选取代的环糊精中的线性分子的末端，且呈串状包覆在任选取代的环糊精中的线性分子的重量平均分子量大于或等于 21000，小于或等于 500000。