Core and shell particle for modifying impact resistance of a mouldable poly (meth) acrylate material
申请人:Schultes Klaus
公开号:US20060147714A1
公开(公告)日:2006-07-06
The present invention relates to a core-shell particle which has a core, a first shell and, where appropriate, a second shell, where: i) the core encompasses, based on its total weight, at least 75.0% by weight of (meth)acrylate repeat units; ii) the first shell has a glass transition temperature below 30° C.; iii) the second shell present where appropriate encompassed, based on its total weight, at lest 75.0% by weight of (meth)acrylate repeat units; iv) the first shell encompasses, based on its total weight, the following constituents; E) from 92.0 to 98.0% by weight of (meth)acrylate repeat units and
F) from 2.0 to 8.0% by weight of styrenic repeat units of the general formula (I)
where the radicals R
1
to R
6
are defined according to the Description and the percentages by weight of E) and F) give a total of 100.0% by weight, v) the radius of the core-shell particle inclusive of any second shell present, measured by the Coulter method, is in the range from above 160.0 to 240.0 nm. The present invention further relates to a process for preparing core-shell particles, to a moulding composition comprising core-shell particles, and to the use thereof.
本发明涉及一种核壳粒子,它具有一个核、一个第一外壳和(在适当情况下)一个第二外壳,其中:i) 核按其总重量计算,包含至少 75.0%(按重量计)的(甲基)丙烯酸酯重复单元;ii) 第一外壳的玻璃化转变温度低于 30°C ;iii) 第二外壳按其总重量计算,包含至少 75.0%(按重量计)的(甲基)丙烯酸酯重复单元;iv) 第一外壳按其总重量计算,包含至少 75.0%(按重量计)的(甲基)丙烯酸酯重复单元。(甲基)丙烯酸酯重复单元的重量比至少为 75.0%; iv) 第一层外壳的重量比包括以下成分: E) (甲基)丙烯酸酯重复单元的重量比从 92.0%到 98.0%不等和
F) 2.0%至 8.0%(按重量计)通式为(I)的苯乙烯重复单元
其中自由基 R
1
至 R
6
的重量百分比为 100.0%;v) 用库尔特法测量的核壳粒子的半径(包括任何存在的第二层壳)在 160.0 至 240.0 nm 以上的范围内。本发明还涉及一种制备核壳颗粒的工艺、一种包含核壳颗粒的模塑组合物及其用途。