lauric acid methallyl ester | 21306-18-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: lauric acid methallyl ester
• 英文别名: Laurinsaeure-methallylester；(2-Methyl-allyl)-laurat；2-Methylprop-2-enyl dodecanoate
• CAS: 21306-18-3
• 化学式: C₁₆H₃₀O₂
• 分子量: 254.413
• InChiKey: YNWPCDCXNNAAPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲醇 、 月桂酸甲酯 在 sodium 作用下， 生成 lauric acid methallyl ester
  参考文献：
  名称：

  Swern; Jordan, Journal of the American Chemical Society, 1948, vol. 70, p. 2335,2338

  摘要：

  DOI：

文献信息

• Method for Allylating and Vinylating Aryl, Heteroaryl, Alkyl, and Alkene Halogenides Using Transition Metal Catalysis
  申请人：Gotta Matthias

  公开号：US20130184485A1

  公开（公告）日：2013-07-18

  What is described is a process for preparing organic compounds of the general formula (I) R—R′  (I) by converting a corresponding compound of the general formula (II) R—X   (II) in which X is fluorine, chlorine, bromine or iodine to an organomagnesium compound of the general formula (III) [M + ] n [R m MgX k Y 1 ]  (III) wherein compounds of the formula (III) are reacted with a compound of the general formula (IV) characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic amounts of an iron compound, based on the compound of the general formula (II), and optionally in the presence of b) a nitrogen-, oxygen- and/or phosphorus-containing additive in a catalytic or stoichiometric amount, based on the compound of the general formula (II).

  描述的是一种制备通式（I）R—R′的有机化合物的过程  (I)，通过将通式（II）R—X的相应化合物转化为通式（III）[M+]n[RmMgXkY1]的有机镁化合物  (III)，其中X为氟、氯、溴或碘，其中化合物的通式（III）与通式（IV）的化合物发生反应，其特点在于（III）与（IV）的反应在以下条件下进行：a）基于通式（II）的化合物的铁化合物的催化量，可选地在b）氮、氧和/或磷含量添加剂的存在下以催化量或化学计量量进行。
• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• Process for preparing vinylically-unsaturated compounds
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0506314A2

  公开（公告）日：1992-09-30

  Vinylically-unsaturated compounds are prepared by reacting a halogenated organic compound with a vinylically-unsaturated precursor compound in the presence of (a) a homogeneous zerovalent palladium catalyst complex, (b) a hydrogen halide acceptor and (c) a diluent, wherein the diluent is water or an aqueous solution containing up to 95 percent by volume of an organic solvent. When the catalyst complex includes an organophosphine or organoarsine ligand, the crude product may be purified by treatment with a peroxide for a time sufficient to oxidize organophosphine or organoarsine impurities present in the mixture. Said purification also can be used when the aqueous diluent is omitted or replaced by an anhydrous diluent.

  乙烯基不饱和化合物是通过卤代有机化合物与乙烯基不饱和前体化合物在(a)均相零价钯催化剂络合物、(b)卤化氢受体和(c)稀释剂存在下反应制备的，其中稀释剂是水或含有高达 95%（体积）有机溶剂的水溶液。当催化剂络合物包括有机膦或有机胂配体时，可以用过氧化物处理粗产品，处理时间足以氧化混合物中存在的有机膦或有机胂杂质。当省略水性稀释剂或用无水稀释剂代替水性稀释剂时，也可采用上述提纯方法。
• Sulphonated organic compound
  申请人：NAT OIL PROD CO

  公开号：US02341060A1

  公开（公告）日：1944-02-08
• US3936427A
  申请人：——

  公开号：US3936427A

  公开（公告）日：1976-02-03