This invention is related to a vinyl chloride resin as obtainable by graft-copolymerizing an acrylic copolymer (a) having a mean particle diameter of 60 to 250 nm with a vinyl monomer (b) predominantly composed of vinyl chloride,
said acrylic copolymer (a), being obtainable by graft-copolymerizing 40 to 90 weight % of a copolymer (a-1) with 10 to 60 weight % of a mixture monomer (a-2),
said copolymer (a-1) being composed of 100 weight parts of a radical-polymerizable monomer which gives a homopolymer having a glass transition point of not lower than -140 °C but lower than -60 °C and 0.1 to 1 weight part of a polyfunctional monomer,
and said mixture monomer (a-2) comprising 100 weight parts of a radical-polymerizable monomer predominantly comprised of a (meth)acrylate which gives a homopolymer having a glass transition point of not lower than -55 °C but lower than -10 °C and 1.5 to 10 weight parts of a polyfunctional monomer.
本发明涉及一种
氯乙烯树脂,可通过将平均粒径为 60 至 250 纳米的
丙烯酸共聚物 (a)与主要由
氯乙烯组成的
乙烯基单体(b)进行接枝共聚而获得、
所述
丙烯酸共聚物(a)可通过将 40 至 90 重量百分比的共聚物(a-1)与 10 至 60 重量百分比的混合物单体(a-2)进行接枝共聚而获得、
所述共聚物(a-1)由 100 重量份的可自由基聚合的单体和 0.1 至 1 重量份的多官能团单体组成,前者可产生
玻璃化转变点不低于-140°C 但低于-60°C 的均聚物、
所述混合物单体 (a-2) 包括 100 重量份主要由(甲基)
丙烯酸酯组成的可自由基聚合的单体,其均聚物的
玻璃化转变点不低于-55 °C,但低于-10 °C,以及 1.5 至 10 重量份的多官能团单体。