2-甲氧基-2-甲基-4,5-咪唑烷二酮 | 214191-56-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-甲氧基-2-甲基-4,5-咪唑烷二酮
• 英文名称: 2-methoxy-2-methyl-4,5-imidazolidinedione
• 英文别名: 2-methoxy-2-methyl-4,5-imidazolidindione；2-Methoxy-2-methylimidazolidine-4,5-dione
• CAS: 214191-56-7
• 化学式: C₅H₈N₂O₃
• 分子量: 144.13
• InChiKey: NESRMACYJSUTIP-UHFFFAOYSA-N

物化性质

• 熔点：
  153-160 °C
• 密度：
  1.31±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  67.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-甲氧基-2-甲基-4,5-咪唑烷二酮 在 硫酸 、 硝酸 作用下， 以67%的产率得到2-(dinitromethylene)-4,5-imidazolidinedione
  参考文献：
  名称：

  Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene

  摘要：

  Low temperature nitrations of 2-methylimidazole gave in addition to the known 2-methyl-5(4)-nitroimidazole (1), 2-(dinitromethylene)-5,5-dinitro-4-imidazolidinone (3) and parabanic acid (2). The tetranitro compound 3 was also obtained by nitration of 2-methyl-4,5-dihydro-( 1H)-5-imidazolone (:8). Thermal decomposition of 3 gave 2-(dinitromethylene)-4,5-imidazolidinedione (4) which also was the product from nitration of the new compound 2-methoxy-2-methyl-4,5-imidazolidinedione. Treatment of 4 with aqueous ammonia gave the previously unknown 1,1-diamino-2,2-dinitroethylene (5). The physical properties and chemical behaviour of (5) are described. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00673-5
• 作为产物：
  描述：

  甲醇 、 2-methyl-4,5-imidazolidinedione 生成 2-甲氧基-2-甲基-4,5-咪唑烷二酮
  参考文献：
  名称：

  Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene

  摘要：

  Low temperature nitrations of 2-methylimidazole gave in addition to the known 2-methyl-5(4)-nitroimidazole (1), 2-(dinitromethylene)-5,5-dinitro-4-imidazolidinone (3) and parabanic acid (2). The tetranitro compound 3 was also obtained by nitration of 2-methyl-4,5-dihydro-( 1H)-5-imidazolone (:8). Thermal decomposition of 3 gave 2-(dinitromethylene)-4,5-imidazolidinedione (4) which also was the product from nitration of the new compound 2-methoxy-2-methyl-4,5-imidazolidinedione. Treatment of 4 with aqueous ammonia gave the previously unknown 1,1-diamino-2,2-dinitroethylene (5). The physical properties and chemical behaviour of (5) are described. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00673-5

文献信息

• Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene
  作者：Nikolai V. Latypov、Jan Bergman、Abraham Langlet、Ulf Wellmar、Ulf Bemm

  DOI：10.1016/s0040-4020(98)00673-5

  日期：1998.9

  Low temperature nitrations of 2-methylimidazole gave in addition to the known 2-methyl-5(4)-nitroimidazole (1), 2-(dinitromethylene)-5,5-dinitro-4-imidazolidinone (3) and parabanic acid (2). The tetranitro compound 3 was also obtained by nitration of 2-methyl-4,5-dihydro-( 1H)-5-imidazolone (:8). Thermal decomposition of 3 gave 2-(dinitromethylene)-4,5-imidazolidinedione (4) which also was the product from nitration of the new compound 2-methoxy-2-methyl-4,5-imidazolidinedione. Treatment of 4 with aqueous ammonia gave the previously unknown 1,1-diamino-2,2-dinitroethylene (5). The physical properties and chemical behaviour of (5) are described. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.