1-(R),2-(R)-Hemicaronaldehyd | 31062-21-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-(R),2-(R)-Hemicaronaldehyd
• 英文别名: trans-2,2-Dimethyl-3-formylcyclopropancarbonsaeure；(1R,trans) 2,2-dimethyl-3-formyl-cyclopropane-carboxylic acid；(1R,3R)-3-formyl-2,2-dimethylcyclopropane-1-carboxylic acid
• CAS: 31062-21-2
• 化学式: C₇H₁₀O₃
• 分子量: 142.155
• InChiKey: PTQGFDXPHNRDCV-UHNVWZDZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-trimethylsilylethyl (1R,3S)-3-[(Z)-2-bromo-2-(4-chlorophenyl)ethenyl]-2,2-dimethylcyclopropane-1-carboxylate 、 1-(R),2-(R)-Hemicaronaldehyd 生成 2-trimethylsilylethyl (1R,3R)-3-[(Z)-2-(4-chlorophenyl)-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-Chrysanthemic acid 生成 1-(R),2-(R)-Hemicaronaldehyd
  参考文献：
  名称：

  CHEN, LIANG, XUADUN SHIFAN DASYUEH SYUEHBAO,(1989) N, S. 51-65

  摘要：

  DOI：

文献信息

• [EN] ESTER COMPOUND AND USE THEREOF<br/>[FR] COMPOSÉ ESTER ET SON UTILISATION
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2013027864A1

  公开（公告）日：2013-02-28

  An ester compound represented by formula (1): wherein Q represents N(CH2C≡CH)-CH2-C*(=O) or N(CH2C≡CH)-C(CH3)=N* (where, * represents a binding position with N atom being adjacent to a carbonyl group); R3 represents a C1-C4 alkyl group; and a relative configuration between the substituent at the 1-position of the cyclopropane ring and the substituent at the 3-position of the cyclopropane ring is a trans configuration, has an excellent pest control effect.

  公式（1）所代表的酯类化合物：其中Q代表N（CH2C≡CH）-CH2-C*（=O）或N（CH2C≡CH）-C（CH3）= N*（其中，*代表与N原子相邻的羰基基团结合位置）；R3代表C1-C4烷基；并且环丙烷环的1位取代基和3位取代基之间的相对构型为反式构型，具有优异的杀虫效果。
• METHOD FOR PRODUCING CYCLOPROPANECARBOXYLIC ACID ESTER
  申请人：Ohshita Jun

  公开号：US20120029227A1

  公开（公告）日：2012-02-02

  A method for producing a cyclopropanecarboxylate represented by formula (III): wherein, R represents a chain hydrocarbon group having 1 to 10 carbon atoms optionally having at least one member selected from the group consisting of halogen atoms, acyl groups having 2 to 7 carbon atoms optionally having a substituent, alkoxy groups having 1 to 7 carbon atoms optionally having a substituent, alkylthio groups having 1 to 3 carbon atoms and phenyl groups optionally having a substituent, a cyclic hydrocarbon group having 3 to 10 carbon atoms or a hydrogen atom; comprising reacting a cyclopropanecarboxylate represented by formula (I): wherein, R represents the same meaning as described above; and 2-cyanopropionic acid in the presence of a base.

  一种制备式（III）的环丙烷羧酸酯的方法：其中，R代表具有1至10个碳原子的链烃基，可选地具有来自卤素原子、具有2至7个碳原子的酰基、具有取代基的1至7个碳原子的烷氧基、具有1至3个碳原子的烷基硫基和可选地具有取代基的苯基、具有3至10个碳原子的环烃基或氢原子中至少一种的成员的群；包括在碱存在下将式（I）所表示的环丙烷羧酸酯与2-氰基丙酸反应。
• Cyclopropane carboxylic acid derivatives
  申请人：Roussel Uclaf

  公开号：US04556666A1

  公开（公告）日：1985-12-03

  All stereoisomeric forms and mixtures of stereoisomers of compounds of the formula ##STR1## wherein X is selected from the group consisting of oxygen, sulfur, sulfoxide and sulfone, R.sub.1 and R.sub.3 are individually selected from the group consisting of optionally unsaturated alkyl of 1 to 7 carbon atoms and optionally unsaturated cycloalkyl of 3 to 7 carbon atoms optionally substituted with at least one halogen and optionally interrupted with at least one heteroatom and aryl and aralkyl of 6 to 18 carbon atoms and R.sub.2 is the residue of a R.sub.2 OH alcohol used in pyrethrinoids synthesis having pesticidal activity and their preparation and novel intermediates.

  公式为##STR1##的化合物的所有立体异构体和立体异构体混合物，其中X选自氧、硫、亚砜和砜的群体，R.sub.1和R.sub.3分别选自1至7个碳原子的可选不饱和烷基和3至7个碳原子的可选不饱和环烷基，可选地含有至少一个卤素和可选地中断至少一个杂原子和6至18个碳原子的芳香基和芳基烷基，R.sub.2是在拟除虫菊酯合成中使用具有杀虫活性的R.sub.2 OH醇的残基，以及它们的制备和新型中间体。
• ESTER COMPOUND AND ITS USE
  申请人：Ohshita Jun

  公开号：US20090253763A1

  公开（公告）日：2009-10-08

  An ester compound represented by the formula (I): (wherein, R 1 represents a C1-C3 alkyl group, a 2-propenyl group or a 2-propynyl group.) has excellent pest controlling activity and is useful as an active ingredient for a pest controlling agent.

  化学式为(I)的酯类化合物具有优异的杀虫活性，其中R1代表C1-C3烷基、2-丙烯基或2-丙炔基。该化合物可用作杀虫剂的有效成分。
• Ester Compound and Use Thereof
  申请人：Uekawa Toru

  公开号：US20100041750A1

  公开（公告）日：2010-02-18

  A compound represented by the formula (I): has an excellent pest controlling activity and therefore is useful for an effective ingredient of a pest control composition.

  化合物式为（I）的化合物具有出色的杀虫活性，因此可用作杀虫剂组成物的有效成分。