(E)-2-(2-tert-butyl-6-(4-diethylaminostyryl)-4H-pyran-4-ylidene)-1,3-indanedione | 1165800-75-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: (E)-2-(2-tert-butyl-6-(4-diethylaminostyryl)-4H-pyran-4-ylidene)-1,3-indanedione
• 英文别名: 2-[2-tert-butyl-6-[(E)-2-[4-(diethylamino)phenyl]ethenyl]pyran-4-ylidene]indene-1,3-dione
• CAS: 1165800-75-8
• 化学式: C₃₀H₃₁NO₃
• 分子量: 453.581
• InChiKey: IWQFAKYJUNXCNB-SAPNQHFASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(2-(tert-butyl)-6-methyl-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione 、 N,N-二乙基-4-氨基苯甲醛 在 哌啶 作用下， 以 乙腈 为溶剂， 以42%的产率得到(E)-2-(2-tert-butyl-6-(4-diethylaminostyryl)-4H-pyran-4-ylidene)-1,3-indanedione
  参考文献：
  名称：

  New one- and two-dimensional 4H-pyranylidene NLO-phores

  摘要：

  Dipolar, V-shaped compounds derived from 4H-pyranylidene-linked acceptors have been synthesized, and their linear and nonlinear optical properties (displaying mu beta values up to 3000 x 10(-48) esu) have been compared to those of analogous one-dimensional derivatives. The pyranylidene ring behaves strictly as a spacer, and not as a donor group. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.03.197

文献信息

• Charge transport material, organic electroluminescent element, and illumination device, display device, or light-emitting device characterized by using said element
  申请人：Kitamura Tetsu

  公开号：US10804469B2

  公开（公告）日：2020-10-13

  [This] charge transport material which comprises a compound expressed by the following formula has a high efficiency and drive durability after high-temperature storage and resists the occurrence of dark spots (X101 represents a sulfur atom or an oxygen atom; R101 and R102 represent each independently an alkyl group, an aryl group, a heteroaryl group, a fluorine atom, or a silyl group, and may further be substituted with these groups; n101 represents an integer from 0 to 11; n102 represents an integer from 0 to 7; a plurality of R101 and R102 [groups] may be the same or different; and L101 represents a single bond or a divalent linking group; however, one of R101, L101, and R102 includes a fluorine atom, a fluoroalkyl group, a cycloalkyl group, a cycloalkylene group, a silyl group, an alkylsilyl group, an arylsilyl group, or a silicon atom linking group.)

  [该]电荷传输材料由下式表示的化合物组成，在高温储存后具有高效率和驱动耐久性，并且不会出现暗斑（X101 代表硫原子或氧原子；R101 和 R102 各自独立地代表烷基、芳基、杂芳基、氟原子或硅基，并可进一步被这些基团取代；n101 代表 0 至 11 的整数；n102 代表 0 至 7 的整数；多个 R101 和 R102[基团]可以相同或不同；以及 L101 代表单键或二价连接基团；然而，R101、L101 和 R102 中的一个包括氟原子、氟烷基、环烷基、环亚烷基、硅烷基、烷基硅烷基、芳基硅烷基或硅原子连接基团。)
• CHARGE TRANSPORT MATERIAL, OGANIC ELECTROLUMINESCENT ELEMENT, AND ILLUMINATION DEVICE, DISPLAY DEVICE, OR LIGHT-EMITTING DEVICE CHARACTERIZED BY USING SAID ELEMENT
  申请人：Kitamura Tetsu

  公开号：US20150069332A1

  公开（公告）日：2015-03-12

  [This] charge transport material which comprises a compound expressed by the following formula has a high efficiency and drive durability after high-temperature storage and resists the occurrence of dark spots (X 101 represents a sulfur atom or an oxygen atom; R 101 and R 102 represent each independently an alkyl group, an aryl group, a heteroaryl group, a fluorine atom, or a silyl group, and may further be substituted with these groups; n101 represents an integer from 0 to 11; n102 represents an integer from 0 to 7; a plurality of R 101 and R 102 [groups] may be the same or different; and L 101 represents a single bond or a divalent linking group; however, one of R 101 , L 101 , and R 102 includes a fluorine atom, a fluoroalkyl group, a cycloalkyl group, a cycloalkylene group, a silyl group, an alkylsilyl group, an arylsilyl group, or a silicon atom linking group.)