2-(4-(4-bromobutyloxy)phenyl)-5-phenyl-[1,3,4]oxadiazole | 506424-28-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(4-(4-bromobutyloxy)phenyl)-5-phenyl-[1,3,4]oxadiazole
• 英文别名: 2-[4-(4-Bromobutoxy)phenyl]-5-phenyl-1,3,4-oxadiazole；2-[4-(4-bromobutoxy)phenyl]-5-phenyl-1,3,4-oxadiazole
• CAS: 506424-28-8
• 化学式: C₁₈H₁₇BrN₂O₂
• 分子量: 373.249
• InChiKey: MSBFFDBMSDRFIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  48.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(4-(4-bromobutyloxy)phenyl)-5-phenyl-[1,3,4]oxadiazole 、 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)-N,N-diphenylaniline 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 OXD-TPIP
  参考文献：
  名称：

  A multicomponent rhenium-based triplet emitter for organic electroluminescence

  摘要：

  A novel Re complex functionalized by a hole-transport and an electron-transport groups was utilized to fabricate organic light-emitting devices (OLEDs). A current efficiency up to 8.2 cd A(-1) corresponding to a power efficiency of 4.6 ml W-1 (a)nd a peak brightness as high as 5500 cd m(-2) were obtained. These results represent the best values reported for OLEDs based on rhenium complexes. Short lifetime, enhanced carrier injection capability of Re complex, and efficient charge-trapping followed by exciton confinement in the emissive layer should be responsible for the outstanding electrophosphore scent performances. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2006.12.044
• 作为产物：
  描述：

  4-羟基苯甲酰肼 在 N-甲基吡咯烷酮 、 sodium hydroxide 、 potassium carbonate 、 三氯氧磷 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 107.0h， 生成 2-(4-(4-bromobutyloxy)phenyl)-5-phenyl-[1,3,4]oxadiazole
  参考文献：
  名称：

  A multicomponent rhenium-based triplet emitter for organic electroluminescence

  摘要：

  A novel Re complex functionalized by a hole-transport and an electron-transport groups was utilized to fabricate organic light-emitting devices (OLEDs). A current efficiency up to 8.2 cd A(-1) corresponding to a power efficiency of 4.6 ml W-1 (a)nd a peak brightness as high as 5500 cd m(-2) were obtained. These results represent the best values reported for OLEDs based on rhenium complexes. Short lifetime, enhanced carrier injection capability of Re complex, and efficient charge-trapping followed by exciton confinement in the emissive layer should be responsible for the outstanding electrophosphore scent performances. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2006.12.044

文献信息

• A multicomponent rhenium-based triplet emitter for organic electroluminescence
  作者：C.B. Liu、J. Li、B. Li、Z.R. Hong、F.F. Zhao、S.Y. Liu、W.L. Li

  DOI：10.1016/j.cplett.2006.12.044

  日期：2007.2

  A novel Re complex functionalized by a hole-transport and an electron-transport groups was utilized to fabricate organic light-emitting devices (OLEDs). A current efficiency up to 8.2 cd A(-1) corresponding to a power efficiency of 4.6 ml W-1 (a)nd a peak brightness as high as 5500 cd m(-2) were obtained. These results represent the best values reported for OLEDs based on rhenium complexes. Short lifetime, enhanced carrier injection capability of Re complex, and efficient charge-trapping followed by exciton confinement in the emissive layer should be responsible for the outstanding electrophosphore scent performances. (c) 2006 Elsevier B.V. All rights reserved.