2-硝基乙烯基磺酰苯 | 61404-94-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-硝基乙烯基磺酰苯
• 英文名称: β-phenylsulfonyl nitroethylene
• 英文别名: 2-(phenylsulfonyl)-1-nitroethylene；2-nitro-1-(phenylsulfonyl)ethylene；1-Nitro-2-phenylsulfonylethene；1-Phenylsulfonyl-2-nitroethylen；(2-Nitroethenesulfonyl)benzene；2-nitroethenylsulfonylbenzene
• CAS: 61404-94-2
• 化学式: C₈H₇NO₄S
• 分子量: 213.214
• InChiKey: LWFNURQMDOMOAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-硝基乙烯基磺酰苯 、 N-benzylidene-4-methylaniline oxide 在 Keggin ion pillared Buserite 作用下， 反应 3.0h， 以85%的产率得到(3S,4S,5R)-5-(benzenesulfonyl)-2-(4-methylphenyl)-4-nitro-3-phenyl-1,2-oxazolidine
  参考文献：
  名称：

  柱状布塞瑞特作为 α-苯基-N-(对甲基苯基)硝酮与缺电子烯烃 1,3-偶极环加成反应的新型催化材料

  摘要：

  摘要 合成的聚氧铝 Keggin 离子柱撑布塞立石 (KPB) 首次被用作 α-N-二芳基硝酮如 α-苯基-N-(对甲基苯基) 的 1,3-偶极环加成反应的有效催化材料。 ) 硝酮与一些缺电子烯烃导致反式 4-取代异恶唑烷的独家形成。

  DOI：

  10.1080/00397919908085730
• 作为产物：
  描述：

  1-氯-2-硝基乙烯 、 sodium benzenesulfonate 生成 2-硝基乙烯基磺酰苯
  参考文献：
  名称：

  Aleksiev,D.I., Journal of Organic Chemistry USSR (English Translation), 1976, vol. 12, p. 1984 - 1985

  摘要：

  DOI：

文献信息

• Stereocontrol of stereogenic centres para on a benzene ring using the SE2? reaction of a pentadienylsilane
  作者：Ian Fleming、Colin P. Leslie

  DOI：10.1039/p19960001197

  日期：——

  The pentadienylsilane 9 and the dimethyl acetal 2 of isobutyraldehyde react with high (80:20)anti stereospecificity to give largely the diene 10a, which was converted into the para-disubstituted benzene 11a, having 1,6-related stereogenic centres.

  戊二烯基硅烷 9 和异丁醛的二甲基缩醛 2 以高 (80:20) 反立体定向性反应，主要生成二烯 10a，将其转化为具有 1,6 相关立构中心的对位二取代苯 11a。
• Preparation and reactivity of highly functionalized organometallics at the .alpha. position of oxygen or nitrogen
  作者：Paul Knochel、Tso Sheng Chou、Carole Jubert、Duddu Rajagopal

  DOI：10.1021/jo00055a010

  日期：1993.1

  Alpha-Halogenoalkyl carboxylates (FG-R1CH(X)(OCOR2); FG = COOR, CN, SR; X = I, Br) were readily prepared by the addition of an acid chloride or bromide (R2COX; X = Br or Cl) to an aldehyde (FG-RCHO) in the presence of a catalytic amount of ZnCl2. They insert efficiently zinc dust in THF-DMSO (X = Br, 8-10-degrees-C, 6-10 h) affording the corresponding zinc organometallics at the a position to oxygen FG-RCH(ZnBr)(OAc). After the addition of the THF-soluble copper salt CuCN.2LiCl, the corresponding copper reagents FG-RCH(Cu(CN)ZnBr)(OAc) are formed and reacted with various classes of electrophiles such as acid chlorides, aldehydes, enones, allylic and alkynyl halides, activated alkynes, nitro olefins and alkylidenemalonates providing polyfunctional molecules in excellent yields. Similarly, zinc organometallics at the a position to the nitrogen of cyclic imides were prepared by the zinc insertion to cyclic alpha-chloromethyl (or alpha-chloroethyl) imides. After their transmetalation to the corresponding copper organometallic ((R1CO)2NCH(R)(Cu(CN)ZnCl); R = Me or H), they were reacted with allylic and alkynyl halides and ethyl propiolate affording polyfunctional imides. The reaction of cyclic N-(chloromethyl)imides with aldehydes in the presence of chromium(II) chloride in THF furnishes protected amino alcohols in 36-95% yield.
• Soluble precursors convertible to tetrabenzoporphyrins below room temperature
  作者：Hidemitsu Uno、Takayuki Ishikawa、Toru Hoshi、Noboru Ono

  DOI：10.1016/s0040-4039(03)01265-6

  日期：2003.7

  Porphyrins fused with dihydroxylated bicyclo[2.2.2]octadiene at beta-positions were quantitatively converted to the corresponding tetrabenzoporphyrins either by treatment with NaH in DMF at 0degreesC or on boehmite at room temperature. (C) 2003 Published by Elsevier Science Ltd.
• Aleksiev,D.I., Journal of Organic Chemistry USSR (English Translation), 1976, vol. 12, p. 1984 - 1985
  作者：Aleksiev,D.I.

  DOI：——

  日期：——
• Pillared Buserite as a new catalytic material for the 1,3-dipolar cycloaddition of α-phenyl-N-(p-methyphenyl) nitrone with electron deficient olefins
  作者：V. Ramamoorthy、A. Ramasubbu、S. Muthusubramanian、S. Sivasubramanian

  DOI：10.1080/00397919908085730

  日期：1999.1.1

  Buserite (KPB), has been used as an effective catalytic material gffor the 1,3-dipolar cycloaddition reaction of α-N-diaryl nitrone such as αphenyl-N-(p-methylphenyl) nitrone with some electron deficient olefins resulting in the exclusive formation of trans-4-substituted isoxazolidines.

  摘要 合成的聚氧铝 Keggin 离子柱撑布塞立石 (KPB) 首次被用作 α-N-二芳基硝酮如 α-苯基-N-(对甲基苯基) 的 1,3-偶极环加成反应的有效催化材料。 ) 硝酮与一些缺电子烯烃导致反式 4-取代异恶唑烷的独家形成。