propane-1-tellurol | 87562-20-7

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: propane-1-tellurol
• 英文别名: Propyltellurmercaptan；Propylhydrotellurid；Propan-1-tellurol；Propane-1-tellurol
• CAS: 87562-20-7
• 化学式: C₃H₈Te
• 分子量: 171.697
• InChiKey: YGKKQLXNCXUKQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.72
• 重原子数：
  4
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  溴丙烷 在 碲化氢 、 sodium ethanolate 作用下， 生成 propane-1-tellurol
  参考文献：
  名称：

  Baroni, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1938, vol. <6>27, p. 241

  摘要：

  DOI：

文献信息

• Reaction Chemistry of ZnTe Metalorganic Vapor-Phase Epitaxy
  作者：Kerri J. Wilkerson、Menno J. Kappers、Robert F. Hicks

  DOI：10.1021/jp963990c

  日期：1997.3.1

  The reaction chemistry of zinc telluride (ZnTe) metalorganic vapor-phase epitaxy (MOVPE) from dimethylzinc (DMZn), diethylzinc (DEZn), and diisopropyltelluride (DIPTe) has been studied using on-line gas chromatography and infrared spectroscopy. Two growth regimes have been discovered: one at low values of the II/VI ratio and the other at higher values of the II/VI ratio. In the first regime, the group VI compound is consumed in excess, while in the second regime, the group II compound is consumed in excess. The crossover point lies at II/VI = 5.0 for DMZn and at II/VI = 0.3 for DEZn. Stoichiometric ZnTe is deposited under all growth conditions. The excess DIPTe consumed is converted into volatile diisopropylditelluride and isopropyltellurol. Conversely, the excess DEZn or DMZn consumed produces zinc metal. These waste byproducts accumulate in the outlet of the reactor. The hydrocarbon products generated from the ethyl and isopropyl ligands are indicative of radical disproportionation, recombination, and hydrogenation reactions. However, the methyl ligands mainly undergo surface hydrogenation to produce methane.
• Baroni, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1938, vol. <6>27, p. 241
  作者：Baroni

  DOI：——

  日期：——