tridec-12-en-2-ol | 96562-66-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: tridec-12-en-2-ol
• 英文别名: 12-tridecen-2-ol
• CAS: 96562-66-2
• 化学式: C₁₃H₂₆O
• 分子量: 198.349
• InChiKey: FXLCUSXGVHBSCJ-UHFFFAOYSA-N

物化性质

• 沸点：
  180 °C(Press: 30 Torr)
• 密度：
  0.840±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tridec-12-en-2-ol 在 jones reagent 作用下， 以 丙酮 为溶剂， 反应 0.17h， 以60%的产率得到12-十三碳烯-2-酮
  参考文献：
  名称：

  Paterne, Michel; Brown, Eric, Journal of Chemical Research, Miniprint, 1985, # 9, p. 2924 - 2947

  摘要：

  DOI：
• 作为产物：
  描述：

  tridec-1-en-12-yne 在 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II) 、 Au(IPr)Cl 、 水 、 silver trifluoroacetate 作用下， 以 异丙醇 为溶剂， 反应 22.0h， 以90%的产率得到tridec-12-en-2-ol
  参考文献：
  名称：

  Regioselective Reductive Hydration of Alkynes To Form Branched or Linear Alcohols

  摘要：

  The regioselective reductive hydration of terminal alkynes using two complementary dual catalytic systems is described. Branched or linear alcohols are obtained in 75-96% yield with >= 25:1 regioselectivity from the same starting materials. The method is compatible with terminal, di-, and trisubstituted alkenes. This reductive hydration constitutes a strategic surrogate to alkene oxyfunctionalization and may be of utility in multistep settings.

  DOI：

  10.1021/ja307145e

文献信息

• METAL COMPLEX AND PRODUCTION METHOD THEREFOR, CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST FOR OLEFIN POLYMERIZATION CONTAINING METAL COMPLEX, AND METHOD FOR PRODUCING POLYMER AND COPOLYMER OF -OLEFIN USING CATALYST FOR OLEFIN POLYMERIZATION
  申请人：The University Of Tokyo

  公开号：EP3476858A1

  公开（公告）日：2019-05-01

  Provided are a novel catalyst component with excellent polymerization activity, for producing an α-olefin polymer and an α-olefin copolymer, especially a polymer having a high molecular weight, and a method for producing an α-olefin polymer and an α-olefin copolymer using the catalyst component. A metal complex obtainable by contacting a compound represented by the following general formula [I] or [II] with a transition metal compound containing a transition metal belonging to 9th, 10th or 11th group in the periodic table: wherein R1, R2, R3 and R4 in the general formula [I] or [II], each independently represent (i) hydrogen, (ii) a halogen, (iii) a linear alkyl having 1 to 30 carbon atoms or the like, which optionally has one selected from the group consisting of a heteroatom and a group containing a heteroatom, or (iv) OR9 or the like; R5 and R6 each independently represent a linear alkyl group having 7 to 30 carbon atoms or the like, which optionally has one selected from the group consisting of a heteroatom and a group containing a heteroatom; E1 represents phosphorus, arsenic or antimony; and X1 represents oxygen or sulfur, and wherein, in the general formula [I], Z represents hydrogen or a leaving group, and m represents a valence of Z.

  本发明提供了一种具有优异聚合活性的新型催化剂组分，用于生产α-烯烃聚合物和 α-烯烃共聚物，特别是具有高分子量的聚合物；还提供了一种使用该催化剂组分生产 α-烯烃聚合物和 α-烯烃共聚物的方法。一种金属络合物，可通过将下式通式[I]或[II]所代表的化合物与含有周期表中第9、10或11族过渡金属的过渡金属化合物接触而获得： 其中通式[I]或[II]中的R1、R2、R3和R4各自独立地代表(i)氢，(ii)卤素，(iii)具有1至30个碳原子的直链烷基或类似物，其中任选有一个选自杂原子和含有杂原子的基团组成的组，或(iv)OR9或类似物；R5 和 R6 各自独立地代表具有 7 至 30 个碳原子的线性烷基或类似基团，其中任选有一个选自杂原子和含有杂原子的基团；E1 代表磷、砷或锑；X1 代表氧或硫，其中，在通式[I]中，Z 代表氢或离去基团，m 代表 Z 的化合价。
• Metal complex and method for producing the same, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the metal complex, and methods for producing α-olefin polymer and copolymer using the catalyst for olefin polymerization
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US11149099B2

  公开（公告）日：2021-10-19

  Provided are a novel catalyst component for producing an α-olefin (co)polymer, and a production method using the same. A metal complex is obtainable by contacting a compound represented by the general formula [I] or [II] with a transition metal compound containing a transition metal belonging to 9th to 11th group: wherein R1, R2, R3 and R4 represent (i) hydrogen, (ii) a halogen, (iii) a linear alkyl or the like, or (iv) OR9 or the like; R5 and R6 represent a linear alkyl group or the like; any one of R1-R6 may have a heteroatom or a heteroatom containing group; E1 represents phosphorus, arsenic or antimony; X1 represents oxygen or sulfur; Z represents hydrogen or a leaving group.

  本发明提供了一种用于生产α-烯烃（共）聚合物的新型催化剂组分，以及使用该催化剂组分的生产方法。通过将通式[I]或[II]代表的化合物与含有属于第 9 至第 11 族过渡金属的过渡金属化合物接触，可获得金属络合物： 其中R1、R2、R3和R4代表(i)氢，(ii)卤素，(iii)直链烷基或类似物，或(iv)OR9或类似物；R5和R6代表直链烷基或类似物；R1-R6中的任何一个可带有杂原子或含杂原子的基团；E1代表磷、砷或锑；X1代表氧或硫；Z代表氢或离去基团。
• Arbain, Dayar; Dasman,; Ibrahim, Satria, Australian Journal of Chemistry, 1990, vol. 43, p. 1949 - 1952
  作者：Arbain, Dayar、Dasman,、Ibrahim, Satria、Sargent, Melvyn V.

  DOI：——

  日期：——
• ARBAIN, DAYAR;DASMAN;IBRAHIM, SATRIA;SARGENT, MELVYN V., AUSTRAL. J. CHEM., 43,(1990) N1, C. 1949-1952
  作者：ARBAIN, DAYAR、DASMAN、IBRAHIM, SATRIA、SARGENT, MELVYN V.

  DOI：——

  日期：——
• METAL COMPLEX AND METHOD FOR PRODUCING THE SAME, CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST FOR OLEFIN POLYMERIZATION CONTAINING THE METAL COMPLEX, AND METHODS FOR PRODUCING ?-OLEFIN POLYMER AND COPOLYMER USING THE CATALYST FOR OLEFIN POLYMERIZATION
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US20190263945A1

  公开（公告）日：2019-08-29

  Provided are a novel catalyst component for producing an α-olefin (co)polymer, and a production method using the same. A metal complex is obtainable by contacting a compound represented by the general formula [I] or [II] with a transition metal compound containing a transition metal belonging to 9th to 11th group: wherein R 1 , R 2 , R 3 and R 4 represent (i) hydrogen, (ii) a halogen, (iii) a linear alkyl or the like, or (iv) OR 9 or the like; R 5 and R 6 represent a linear alkyl group or the like; any one of R 1 -R 6 may have a heteroatom or a heteroatom containing group; E 1 represents phosphorus, arsenic or antimony; X 1 represents oxygen or sulfur; Z represents hydrogen or a leaving group.