Butanedioic acid, 2,3-bis(1,1-dimethylethyl)-, diethyl ester | 344316-90-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Butanedioic acid, 2,3-bis(1,1-dimethylethyl)-, diethyl ester
• 英文别名: diethyl 2,3-ditert-butylbutanedioate
• CAS: 344316-90-1
• 化学式: C₁₆H₃₀O₄
• 分子量: 286.41
• InChiKey: ZUCVTIPWILNAMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-溴-3,3-二甲基丁酸乙酯 生成 Butanedioic acid, 2,3-bis(1,1-dimethylethyl)-, diethyl ester
  参考文献：
  名称：

  GALAMB, V.;PALYI, G., ACTA CHIM. ACAD. SCI. HUNG., 1982, 111, N 2, 131-139

  摘要：

  DOI：

文献信息

• Propylene polymers
  申请人：Morini Giampiero

  公开号：US20050032633A1

  公开（公告）日：2005-02-10

  The present invention relates to a solid catalyst component for the polymerization of olefins CH 2 ═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

  本发明涉及一种用于聚合烯烃CH2═CHR（其中R为氢或具有1-12个碳原子的碳氢基团）的固体催化剂组分，包括镁、钛、卤素和从特定公式的取代琥珀酸酯中选择的电子给体。当在聚合烯烃，特别是丙烯的聚合中使用该催化剂组分时，能够以高收率和以高二甲苯不溶性表示的高同构指数给出聚合物。
• OLEFIN POLYMERIZATION CATALYST, PROCESS FOR PRODUCING OLEFIN POLYMER, POLYPROPYLENE RESIN COMPOSITION AND ARTICLE COMPRISING THE SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20130109789A1

  公开（公告）日：2013-05-02

  An olefin polymerization catalyst is obtained by bringing the following components (A), (B) and (C) into contact with one another: (A) a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom and a halogen atom; (B) an organoaluminum compound; and (C) a triether represented by formula (I). An olefin polymerization solid catalyst can be provided having a sufficiently high polymerization activity and an ability to produce an olefin polymer with a low content of low-molecular weight components and amorphous components.

  一种烯烃聚合催化剂是通过将以下组分（A）、（B）和（C）彼此接触而获得的：（A）用于烯烃聚合的固体催化剂组分，其中包含钛原子、镁原子和卤素原子；（B）有机铝化合物；以及（C）由式（I）表示的三醚。可以提供具有足够高的聚合活性和能够产生低分子量成分和非晶态成分含量低的烯烃聚合物的固体聚合催化剂。
• SOLID CATALYST COMPONENT AND CATALYST FOR POLYMERIZATION OF OLEFINS, AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS USING SAME
  申请人：Toho Titanium CO., LTD.

  公开号：EP2360190A1

  公开（公告）日：2011-08-24

  A solid catalyst component for olefin polymerization is produced by causing (a) a solid component that includes magnesium, titanium, a halogen, and an electron donor, (b) an aminosilane compound shown by the following general formula (1), and (c) at least one organosilicon compound selected from an organosilicon compound shown by the following general formula (2-A) and an organosilicon compound shown by the following general formula (2-B) to come in contact with each other. A polymer having high stereoregularity is produced in high yield while achieving a high melt flow rate due to hydrogen by polymerizing an olefin in the presence of a catalyst that includes the solid catalyst component.         R1nSi(NR2R3)4-n     (1)         [CH2=CH-(CH2)1]qSiR44-q     (2-A)         R5Si(OR6)4-s     (2-B)

  一种用于烯烃聚合的固体催化剂组分是通过使(a)一种包括镁、钛、卤素和电子供体的固体组分，(b)如下通式(1)所示的氨基硅烷化合物，和(c)至少一种选自如下通式(2-A)所示的有机硅化合物和如下通式(2-B)所示的有机硅化合物的有机硅化合物相互接触而制得的。在含有固体催化剂组分的催化剂存在下，通过聚合烯烃，可以高产率地生产出具有高立体规整度的聚合物，同时由于氢气的存在，可以达到较高的熔体流动速率。 R1nSi(NR2R3)4-n (1) [CH2=CH-(CH2)1]qSiR44-q (2-A) R5Si(OR6)4-s (2-B)
• SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, MANUFACTURING METHOD, AND CATALYST AND OLEFIN POLYMER MANUFACTURING METHOD
  申请人：Toho Titanium CO., LTD.

  公开号：EP2374821A1

  公开（公告）日：2011-10-12

  A solid catalyst component for olefin polymerization includes a solid component obtained by causing a magnesium compound(a), a titanium halide compound(b), and an electron donor compound(c) to come in contact with each other, the titanium compound in an amount equivalent to a titanium content of 0.2 to 2.5 wt% in the solid catalyst component being washed away from the solid catalyst component by washing with heptane. A granular or spherical polymer that has high stereoregularity and a narrow particle size distribution can be obtained in high yield while suppressing production of a fine powder by polymerizing an olefin using a catalyst that includes the solid catalyst component.

  用于烯烃聚合的固体催化剂组分包括通过使镁化合物(a)、卤化钛化合物(b)和电子供体化合物(c)相互接触而得到的固体组分，钛化合物的量相当于固体催化剂组分中 0.2 至 2.5 wt%的钛含量，通过庚烷洗涤从固体催化剂组分中洗掉。使用包含固体催化剂组分的催化剂聚合烯烃，可以获得立体粒度高、粒度分布窄的颗粒状或球状聚合物，同时抑制细粉末的产生。
• METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION, AND OLEFIN POLYMERS
  申请人：Toho Titanium Co., Ltd.

  公开号：EP2636688A1

  公开（公告）日：2013-09-11

  An environmentally-friendly solid catalyst component for olefin polymerization exhibits high hydrogen activity and high polymerization activity, can produce a polymer that exhibits a high MFR and high stereoregularity in high yield using a small amount of hydrogen, and exhibits high copolymerization activity and excellent copolymerization properties (e.g., block ratio). The solid catalyst component for olefin polymerization is produced by bringing (a) a magnesium compound, (b) an internal electron donor, and (c) a tetravalent-element halogen compound into contact with each other in an inert organic solvent, the internal electron donor (b) being represented by R12C(COOCH3)2 (wherein R1 is selected from a branched alkyl group having 3 to 20 carbon atoms, a halogen atom, a linear or branched halogen-substituted alkyl group having 2 to 20 carbon atoms, a linear alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a vinyl group, and an allyl group).

  一种用于烯烃聚合的环境友好型固体催化剂组分具有高氢活性和高聚合活 性，可使用少量氢气生产出高 MFR 和高立体规整度的聚合物，并具有高共聚活 性和优异的共聚特性（如嵌段比）。用于烯烃聚合的固体催化剂组分是通过在惰性有机溶剂中使(a)镁化合物、(b)内部电子供体和(c)四价元素卤素化合物相互接触而制得的、内部电子供体 (b) 由 R12C(COOCH3)2 表示（其中 R1 选自具有 3 至 20 个碳原子的支链烷基、卤原子、具有 2 至 20 个碳原子的直链或支链卤代烷基、具有 1 至 20 个碳原子的直链烷基、具有 3 至 20 个碳原子的环烷基、乙烯基和烯丙基）。