5-(methylsulfonyl)-2-phenyl-1H-benzo[d]imidazole | 1255098-90-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 5-(methylsulfonyl)-2-phenyl-1H-benzo[d]imidazole
• 英文别名: 6-methylsulfonyl-2-phenyl-1H-benzimidazole
• CAS: 1255098-90-8
• 化学式: C₁₄H₁₂N₂O₂S
• 分子量: 272.327
• InChiKey: QRIOGHDSSIVIOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  71.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  在 copper diacetate 、 溶剂黄146 作用下， 以 二甲基亚砜 为溶剂， 反应 17.0h， 生成 5-(methylsulfonyl)-2-phenyl-1H-benzo[d]imidazole
  参考文献：
  名称：

  苯并咪唑图书馆的氧化环化方法

  摘要：

  描述了一种从苯胺平行合成苯并咪唑的有效方法。改变苯并咪唑的N1和C2载体的文库方法已经很成熟。但是，C4–C7变体传统上依赖于1,2-二苯胺结构单元，因此化学空间覆盖范围有限。我们已经开发了an形成/氧化环化序列，使苯胺能够作为苯并咪唑C4-C7 SAR平行生成形式的多样性集。通过使用PIDA或Cu介导的氧化作用来获得N和烷基烷基苯并咪唑的idine环化反应。该库协议现已用于四个药物化学项目的模拟生产。另外，通过类似的序列从氨基吡啶合成氮杂苯并咪唑。

  DOI：

  10.1021/acscombsci.9b00189

文献信息

• FLUORENE-TYPE COMPOUND, PHOTOPOLYMERIZATION INITIATOR COMPRISING SAID FLUORENE-TYPE COMPOUND, AND PHOTOSENSITIVE COMPOSITION CONTAINING SAID PHOTOPOLYMERIZATION INITIATOR
  申请人：Daito Chemix Corporation

  公开号：US20150259321A1

  公开（公告）日：2015-09-17

  According to an embodiment of the present invention, there is provided a novel fluorene-based compound and a photopolymerization initiator using the fluorene-based compound. The fluorene-based compound according to an embodiment of the present invention is represented by the general formula (1). A photopolymerization initiator having additionally high sensitivity can be provided by using the fluorene-based compound. In addition, a photopolymerization initiator that can impart additionally excellent characteristics can be provided by appropriately selecting, for example, a substituent.

  根据本发明实施例，提供了一种新的基于芴的化合物和使用该基于芴的化合物的光聚合引发剂。根据本发明实施例，基于芴的化合物由通式（1）表示。通过使用基于芴的化合物，可以提供具有更高灵敏度的光聚合引发剂。此外，通过适当选择例如取代基，可以提供具有额外优异特性的光聚合引发剂。
• Flavonoid complexes with cyclodextrins
  申请人：Wirth Corinna

  公开号：US20070155695A1

  公开（公告）日：2007-07-05

  The invention relates to complexes of certain flavonoid derivatives, of the formula I compositions which comprise such derivatives, corresponding processes for the preparation of the flavonoid derivatives or of compositions comprising same, and the use thereof, in particular for the care, preservation or improvement of the general state of the skin or hair. Formula (1), in which Z 1 to Z 4 and Z 6 to Z 10 each, independently of one another, denote H, OH, CH 3 COO, alkoxy, hydroxyalkoxy, mono- or oligoglycoside radicals and where the alkoxy and hydroxyalkoxy groups may be branched and unbranched and can have 1 to 18 C atoms. Formula (II) denotes, Z 5 is a mono- or the oligoglycoside radical, where bonded to this glycoside radical, in each case via an —O— group, is at least one radical selected from certain benzo molecule.

  本发明涉及某些黄酮衍生物的复合物，具有I式的组成物，包括这些衍生物的制备方法或包含它们的组合物的制备方法，以及它们的用途，特别是用于皮肤或头发的护理、保护或改善。式（1）中，Z1至Z4和Z6至Z10各自独立地表示H、OH、CH3COO、烷氧基、羟基烷氧基、单糖或寡糖基团，其中烷氧基和羟基烷氧基基团可以是支链和直链的，并且可以具有1到18个C原子。式（II）表示，Z5是单糖或寡糖基团，其中通过每个—O—基团，与该糖基团结合的至少有一种来自某些苯并分子的基团。
• COSMETIC FORMULATION COMPRISING FLAVONOID DERIVATIVES
  申请人：Wirth Corinna

  公开号：US20080199414A1

  公开（公告）日：2008-08-21

  The invention relates to cosmetic formulations, pharmaceutical preparations, food products and food supplements containing flavonoid derivatives. The flavonoid derivatives act therein, for instance, as UV filter. Some flavonoid derivatives represent novel compounds.
• STABILIZED PHOTOACTIVE COMPOSITION AND USE THEREOF
  申请人：Eni S.P.A.

  公开号：US20130150502A1

  公开（公告）日：2013-06-13

  Stabilized photoactive composition comprising at least one photoactive organic polymer; at least one light stabilizer selected from hindered amines; at least one UV absorber selected from triazines, benzoxazinones, benzotriazoles, benzophenones, benzoates, formamidines, cinnamates or propenoates, aromatic propanediones, benzoimidazoles, cycloaliphatic ketones, formanilides including oxamides, cyanoacrylates, benzopyranones, salicylates, or mixtures thereof. Said photoactive composition can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both rigid and flexible supports.
• US7345090B2
  申请人：——

  公开号：US7345090B2

  公开（公告）日：2008-03-18