2-羟甲基-2-(1,3,3-三甲基-丁基)-丙烷-1,3-二醇 | 106652-67-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-羟甲基-2-(1,3,3-三甲基-丁基)-丙烷-1,3-二醇
• 英文名称: 2-hydroxymethyl-2-(1,3,3-trimethyl-butyl)-propane-1,3-diol
• 英文别名: 2-Hydroxymethyl-2-(1,3,3-trimethyl-butyl)-propan-1,3-diol；2-(4,4-Dimethylpentan-2-yl)-2-(hydroxymethyl)propane-1,3-diol
• CAS: 106652-67-9
• 化学式: C₁₁H₂₄O₃
• 分子量: 204.31
• InChiKey: ASNQBHHUPXDHTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3,5,5-三甲基-1-己醇 在 sodium hydroxide 、 air 、 银 作用下， 生成 2-羟甲基-2-(1,3,3-三甲基-丁基)-丙烷-1,3-二醇
  参考文献：
  名称：

  Bruner, Industrial and Engineering Chemistry, 1949, vol. 41, p. 2861

  摘要：

  DOI：

文献信息

• CYCLIC CARBONYL COMPOUNDS WITH PENDANT CARBONATE GROUPS, PREPARATIONS THEREOF, AND POLYMERS THEREFROM
  申请人：Fujiwara Masaki

  公开号：US20110269917A1

  公开（公告）日：2011-11-03

  A one pot method of preparing cyclic carbonyl compounds comprising an active pendant pentafluorophenyl carbonate group is disclosed. The cyclic carbonyl compounds can be polymerized by ring opening methods to form ROP polymers comprising repeat units comprising a side chain pentafluorophenyl carbonate group. Using a suitable nucleophile, the pendant pentafluorophenyl carbonate group can be selectively transformed into a variety of other functional groups before or after the ring opening polymerization.

  公开了一种制备含有活性吊挂五氟苯基碳酸酯基团的环状羰基化合物的一锅法。这些环状羰基化合物可以通过环开启方法聚合，形成包含侧链五氟苯基碳酸酯基团的ROP聚合物重复单元。使用适当的亲核试剂，可以在环开启聚合之前或之后，选择性地将吊挂的五氟苯基碳酸酯基团转化为各种其他功能基团。
• [EN] CYCLIC CARBONYL COMPOUNDS WITH PENDANT PENTAFLUOROPHENYL CARBONATE GROUPS, PREPARATIONS THEREOF, AND POLYMERS THEREFROM<br/>[FR] COMPOSÉS CARBONYLÉS CYCLIQUES AVEC GROUPEMENTS PENTAFLUOROPHÉNYLCARBONATE PENDANTS, LEURS SYNTHÈSES ET LEURS POLYMÈRES
  申请人：IBM

  公开号：WO2011135046A1

  公开（公告）日：2011-11-03

  A one pot method of preparing cyclic carbonyl compounds comprising an active pendant pentafluorophenyl carbonate group is disclosed. The cyclic carbonyl compounds can be polymerized by ring opening methods to form ROP polymers comprising repeat units comprising a side chain pentafluorophenyl carbonate group. Using a suitable nucleophile, the pendant pentafluorophenyl carbonate group can be selectively transformed into a variety of other functional groups before or after the ring opening polymerization.

  揭示了一种制备含有活性吊挂五氟苯基碳酸酯基团的环状羰基化合物的一锅法。这些环状羰基化合物可以通过环开启方法聚合，形成包含侧链五氟苯基碳酸酯基团的ROP聚合物重复单元。利用适当的亲核试剂，吊挂的五氟苯基碳酸酯基团可以在环开启聚合之前或之后被选择性地转化为各种其他功能基团。
• Method For The Combined Production of Polyols In The Presence Of An Inorganic Base
  申请人：OXEA GmbH

  公开号：US20190241492A1

  公开（公告）日：2019-08-08

  The present invention relates to a process for simultaneously consecutive preparation of polyols by base-catalysed reaction of at least two different mid-chain aldehydes with formaldehyde. The simultaneous consecutive mode of operation makes it possible to achieve high conversions and high selectivities for both aldehydes, with additional achievement of a distinct reduction in the amount of unreacted formaldehyde remaining. This leads to improved process economics, since the energy costs for workup of the formaldehyde stream are distinctly reduced.

  本发明涉及一种通过碱催化反应至少两种不同的中链醛和甲醛同时连续制备多元醇的方法。同时连续的操作方式使得两种醛都能够实现高转化率和高选择性，并且还能显著减少未反应的甲醛量。这导致了工艺经济性的改善，因为处理甲醛流的能量成本明显降低了。
• A thermoplastic polyurethane product
  申请人：Deseret Medical, Inc.

  公开号：EP0184465A2

  公开（公告）日：1986-06-11

  An antithrombogenic thermoplastic polyurethane product, and process for preparing the same, the product comprising a substrate and at least one layer of a polyurethane alloy complex comprising a thermoplastic polyurethane and completely dispersed therein a preformed complex of an antithrombogenic material and/or an antibiotic agent ionically bonded with a quaternary ammonium compound.

  一种抗血栓形成的热塑性聚氨酯产品及其制备工艺，该产品包括基材和至少一层聚氨酯合金复合物，该复合物由热塑性聚氨酯和完全分散在其中的抗血栓形成材料和/或与季铵盐化合物离子键合的抗生素制剂的预制复合物组成。
• Storage stable, one-package heat curable polyurethane adhesive compositions
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0197170A1

  公开（公告）日：1986-10-15

  New and improved storage stable, one package, heat curable polyurethane adhesive compositions are disclosed which comprise (a) a mixture of or a prepolymer adduct of: (i) an excess of a poly aliphatic isocyanate compound of the formula: wherein R and R' are each, independently, alkyl or substituted alkyl and X is a bridging means selected from divalent aliphatic, cycloaliphatic or aromatic groups; and (ii) at least one monomeric or polymeric compound containing a plurality of hydroxyl groups; in admixture with (b) a stoichiometric amount of a curing agent comprising a monomeric or polymeric compound having at least three hydroxyl groups at least one of which is a secondary hydroxyl group; and (c) optionally, an inert filler. The compositions are curable upon exposure to elevated temperatures of from about 100°-200°C to form high tensile strength, high adhesive strength bonds to a variety of substrates. The compositions have extended pot lives of up to six weeks and exhibit storage stability for up to six months.

  本发明公开了新型和改进的贮存稳定、单包装、热固化聚氨酯粘合剂组合物，其中包括 (a) 以下物质的混合物或预聚物加合物 (i) 式中过量的多脂肪族异氰酸酯化合物： 其中 R 和 R'各自独立地为烷基或取代烷基，X 为桥接手段，选自二价脂肪族、环脂族或芳香族基团；以及 (ii) 至少一种含有多个羟基的单体或聚合化合物； 与下列物质混合 (b) 一定量的固化剂，该固化剂包含至少三个羟基（其中至少一个是仲羟基） 的单体或聚合化合物；以及 (c) 可选的惰性填料。 这些组合物在暴露于约 100°-200°C 的高温时可固化，从而与各种基材形成高拉伸强度、高粘合强度的粘合剂。该组合物的罐装寿命可延长至六周，并具有长达六个月的储存稳定性。