5-methyl-6,11-dihydro-5H-dibenzo[b,e]azepine | 1557-46-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯氮卓类
• 英文名称: 5-methyl-6,11-dihydro-5H-dibenzo[b,e]azepine
• 英文别名: 5-methyl-6,11-dihydro-5H-dibenz[b,e]azepine；5-Methyl-6,11-dihydro-5H-dibenz[b,e]azepin；N-Methyl-2,3:5,6-dibenzo-1-aza-cyclohepta-2,5-dien；5-Methyl-5,6-dihydro-morphanthridin；5-Methyl-6,11-dihydrobenzo[c][1]benzazepine
• CAS: 1557-46-6
• 化学式: C₁₅H₁₅N
• 分子量: 209.291
• InChiKey: USIDJIRCZFJHHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-methyl-6,11-dihydro-5H-dibenzo[b,e]azepine 在 乙二醇二甲醚 、 potassium Sodium 作用下， 生成 N-methyl-2-(2-methyl-benzyl)-aniline
  参考文献：
  名称：

  Wittig et al., Justus Liebigs Annalen der Chemie, 1955, vol. 594, p. 89,111

  摘要：

  DOI：
• 作为产物：
  描述：

  5H-二苯并[b,e]氮杂卓-6,11-二酮 在 1,4-二氧六环 、 chromium(III) oxide 、 乙醚 、 copper(II) oxide 作用下， 250.0 ℃ 、25.99 MPa 条件下， 生成 5-methyl-6,11-dihydro-5H-dibenzo[b,e]azepine
  参考文献：
  名称：

  Wittig et al., Justus Liebigs Annalen der Chemie, 1955, vol. 594, p. 89,111

  摘要：

  DOI：

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20150175564A1

  公开（公告）日：2015-06-25

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y 1 to Y 8 represent —C(═O)—O—, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group with at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group, A 1 represents a trivalent aromatic group, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom.)

  一种可聚合的化合物具有实用的低熔点、在通用溶剂中良好的溶解性，并且可以以低成本制备光学薄膜，表现出较低的反射亮度，并且在宽波长范围内实现偏振光的均匀转换，是一种光学各向异性材料。一种羰基化合物可作为制备可聚合化合物的原料。（在式（I）中，Y1至Y8代表—C(═O)—O—，G1和G2代表C1-20二价线性脂肪族基团，Z1和Z2代表未取代或取代有卤素原子的C2-10烯基基团，Ax代表至少具有一个芳香环的C2-30有机基团，Ay代表氢原子或C1-20烷基基团，A1代表三价芳香族基团，A2和A3代表C3-30二价脂环碳氢基团，A4和A5代表C6-30二价芳香族基团或类似物，Q1代表氢原子。）
• POLYMERIZABLE COMPOUND AND OPTICAL ISOMER
  申请人：DIC Corporation

  公开号：US20180022716A1

  公开（公告）日：2018-01-25

  The present invention provides a polymerizable compound having high storage stability without causing crystal precipitation when added to a polymerizable composition. The present invention also provides a polymerizable composition containing the compound. When the filmy polymer produced through polymerization of the polymerizable composition is irradiated with UV light, it hardly discolors or peels from substrate. Further, the present invention provides a polymer produced through polymerization of the polymerizable composition and an optically anisotropic body using the polymer.

  本发明提供了一种聚合物化合物，具有高储存稳定性，添加到聚合物化合物时不会导致结晶沉淀。本发明还提供了含有该化合物的聚合物化合物。当通过聚合物化合物的聚合产生薄膜状聚合物时，若用紫外光照射，它几乎不会变色或脱落。此外，本发明提供了通过聚合物化合物的聚合产生的聚合物，以及使用该聚合物的光学各向异性体。
• [EN] POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY<br/>[FR] COMPOSÉ POLYMÉRISABLE ET CORPS OPTIQUEMENT ANISOTROPE
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2017079867A1

  公开（公告）日：2017-05-18

  There is provided a polymerizable composition, by which discoloration or alignment defects are less likely to occur when a filmy polymer, which is obtained by adding a polymerizable compound to the polymerizable composition and polymerizing this composition, is irradiated with ultraviolet light. There are also provided a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low-wavelength dispersive or polymerizable reverse-wavelength dispersive compound having a partial structure represented by Formula (Z-0). Further, the present invention provides a composition containing the compound; a polymer obtained by polymerizing the composition; and an optically anisotropic body obtained by using the polymer.

  提供一种可聚合的组合物，通过该组合物得到的薄膜聚合物在紫外光照射时，不太容易发生变色或排列缺陷。还提供了通过聚合该聚合物组合物得到的聚合物，以及使用该聚合物的光学各向异性体。本发明提供了一种具有由式（Z-0）表示的部分结构的可聚合低波长色散或可聚合反波长色散化合物。此外，本发明提供了一种含有该化合物的组合物；通过聚合该组合物得到的聚合物；以及通过使用该聚合物得到的光学各向异性体。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC SUBSTANCE
  申请人：ZEON CORPORATION

  公开号：US20150274647A1

  公开（公告）日：2015-10-01

  The present invention relates to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer [in the formula, Y 1 to Y 8 are a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—, or the like; G 1 and G 2 are a divalent aliphatic group having 1 to 20 carbon atoms, or the like; Z 1 and Z 2 are an alkenyl group having 2 to 10 carbon atoms, or the like; A 1 is a tetravalent aromatic group, or the like; A 2 and A 3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, or the like; A 4 and A 5 are a divalent aromatic group having 4 to 30 carbon atoms, or the like; A x1 and A x2 are an organic group having 2 to 30 carbon atoms that includes an aromatic ring, or the like; A y1 and A y2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; Q 1 and Q 2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; and m and n are 0 or 1]. According to the present invention, a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article.

  本发明涉及：由式(I)表示的可聚合化合物；包括所述可聚合化合物和引发剂的可聚合组合物；通过聚合所述可聚合化合物或可聚合组合物得到的聚合物；以及包括所述聚合物的光学各向异性物品[在该式中，Y1至Y8为化学单键，—O—，—O—C(═O)—，—C(═O)—O—等；G1和G2为具有1至20个碳原子的二价脂肪族基等；Z1和Z2为具有2至10个碳原子的烯基基团等；A1为四价芳香族基等；A2和A3为具有3至30个碳原子的二价脂环烃基等；A4和A5为具有4至30个碳原子的二价芳香族基等；Ax1和Ax2为包括芳香环的具有2至30个碳原子的有机基团等；Ay1和Ay2为氢原子、具有1至6个碳原子的烷基基团等；Q1和Q2为氢原子、具有1至6个碳原子的烷基基团等；m和n为0或1]。根据本发明，可以制备具有实用低熔点、在通用溶剂中具有优异溶解性、成本低廉的可聚合化合物、可聚合组合物和聚合物，并且可以生产出在宽波长范围内实现偏振光均匀转换的光学薄膜，同时提供光学各向异性物品。
• Vasopressin V1a Antagonists
  申请人：Batt Andrzej Roman

  公开号：US20090029965A1

  公开（公告）日：2009-01-29

  The present invention concerns compounds inter alia according to general formula 1 a . Compounds according to the invention are vasopressin V 1a receptor antagonists. Pharmaceutical compositions of the compounds are useful as treatment of dysmenorrhoea.

  本发明涉及一些化合物，其中包括一般式1a所示的化合物。根据本发明的化合物是抗利尿激素V1a受体拮抗剂。该化合物的制药组合物可用于治疗痛经。