(Z)-6-tetradecenal | 174155-53-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-6-tetradecenal
• 英文别名: (Z)-tetradec-6-enal
• CAS: 174155-53-4
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: HCWUCGFGFTYIIJ-HJWRWDBZSA-N

物化性质

• 沸点：
  290.6±9.0 °C(Predicted)
• 密度：
  0.839±0.06 g/cm3(Predicted)
• 保留指数：
  1568;1572

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (Z)-6-tetradecenal 在 重铬酸吡啶 、 lithium aluminium deuteride 作用下， 生成 (Z)-6-[1-2H1]tetradecenal
  参考文献：
  名称：

  Cycloalkene Budding:  A Unique Rearrangement Observed in the Mass Spectra of N,N-Dimethylhydrazones of Unsaturated Aldehydes

  摘要：

  DOI：

  10.1021/jo971960f
• 作为产物：
  描述：

  (Z)-6-tetradecen-1-ol 在 重铬酸吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 (Z)-6-tetradecenal
  参考文献：
  名称：

  摘要：

  The Iepidopteran genus Saturnia has three representatives in North America, S. walterorum, S.mendocino, and S. albofasciata. (E4,Z9)-Tetradecadienal (E4,Z9-14 : Ald) was identified as a sex pheromone component for all three species by combinations of coupled gas chromatography-electroantennogram detection (GC-EAD), GC-mass spectrometry (MS), and field trials. In field trials, all three species were strongly attracted to (E4,Z9-14 : Ald) as a single component. Small amounts of (Z)-9-tetradecenal (Z9-14: Ald) also were found in extracts of all three species, but blends of this compound with E4,Z9-14 : Aid were no more attractive to male moths than E4,Z9-14 : Aid alone. Extracts of pheromone glands of female S. walterorum occasionally contained a third, trace compound eliciting responses from male antennae in GC-EAD experiments, but this compound was not identified. It is suggested that the three species can use the same, single component as a sex attractant because the flight period of S. albofasciata (Fall) is different than that of the other two species (spring), whereas the geographic distributions of S. mendocino and S. walterorum overlap over only small portions of their ranges. Furthermore, the latter two species readily hybridize, so there may be minimal fitness cost to cross-attraction.

  DOI：

  10.1023/a:1010310204552

文献信息

• USE OF A REWIRED GENETIC CONTROL NETWORK TO INCREASE PRODUCT EXPRESSION
  申请人：IMPERIAL INNOVATIONS LIMITED

  公开号：US20150284711A1

  公开（公告）日：2015-10-08

  A method of identifying a cell with increased production of a desired product, the method comprising: (a) providing a population of cells which produce the desired product; (b) introducing a plurality of distinct nucleic acid molecule species into the population of cells, wherein the nucleic acid molecules comprise a first region which is operably-linked to a second region, wherein the first region comprises a promoter region from a first gene, and the second region comprises a nucleic acid sequence from a second gene that is capable of expressing a regulatory product under control of the promoter region; (c) culturing the population of cells under conditions in which the cells express the regulatory product under control of the promoter region; and (d) testing the population of cells for production of the desired product, thereby to identify a cell or cells with increased production of the desired product. The method may further comprise isolating a cell or cells with increased production of the desired product. The method may further comprise repeating steps (b), (c) and (d) on the isolated cells or cells, or descendants thereof with increased production of the desired product, thereby to identify a cell or cells with further increased production of the desired product. Typically the desired product is not encoded by the introduced nucleic acid molecule. The plurality of distinct nucleic acid molecule species typically comprise a plurality of combinations of multiple first and multiple second regions. The expressed regulatory product typically is a polypeptide but may be an RNA molecule. The method may further comprise isolating the nucleic acid molecule(s) introduced into the cell or cells with increased production of the desired product.
• ——
  作者：J. STEVEN McELFRESH、JOCELYN G. MILLAR、DANIEL RUBINOFF

  DOI：10.1023/a:1010310204552

  日期：——

  The Iepidopteran genus Saturnia has three representatives in North America, S. walterorum, S.mendocino, and S. albofasciata. (E4,Z9)-Tetradecadienal (E4,Z9-14 : Ald) was identified as a sex pheromone component for all three species by combinations of coupled gas chromatography-electroantennogram detection (GC-EAD), GC-mass spectrometry (MS), and field trials. In field trials, all three species were strongly attracted to (E4,Z9-14 : Ald) as a single component. Small amounts of (Z)-9-tetradecenal (Z9-14: Ald) also were found in extracts of all three species, but blends of this compound with E4,Z9-14 : Aid were no more attractive to male moths than E4,Z9-14 : Aid alone. Extracts of pheromone glands of female S. walterorum occasionally contained a third, trace compound eliciting responses from male antennae in GC-EAD experiments, but this compound was not identified. It is suggested that the three species can use the same, single component as a sex attractant because the flight period of S. albofasciata (Fall) is different than that of the other two species (spring), whereas the geographic distributions of S. mendocino and S. walterorum overlap over only small portions of their ranges. Furthermore, the latter two species readily hybridize, so there may be minimal fitness cost to cross-attraction.
• Cycloalkene Budding:  A Unique Rearrangement Observed in the Mass Spectra of <i>N,N</i>-Dimethylhydrazones of Unsaturated Aldehydes
  作者：Athula B. Attygalle、Kithsiri B. Herath、Jerrold Meinwald

  DOI：10.1021/jo971960f

  日期：1998.1.1