2-苯基硫烷基-辛酸 | 71715-68-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-苯基硫烷基-辛酸
• 英文名称: 2-phenylsulfanyl-octanoic acid
• 英文别名: 2-(Phenylsulfanyl)octanoic acid；2-phenylsulfanyloctanoic acid
• CAS: 71715-68-9
• 化学式: C₁₄H₂₀O₂S
• 分子量: 252.378
• InChiKey: KHLCLWFJRPFZNW-UHFFFAOYSA-N

物化性质

• 沸点：
  384.0±25.0 °C(Predicted)
• 密度：
  1.09±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  62.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  甲醇 、 2-苯基硫烷基-辛酸 在 sodium hydroxide 作用下， 生成 庚醛二甲基缩醛
  参考文献：
  名称：

  Electrochemical synthesis of aldehydes and acetals from α-phenylthiocarboxylic acid

  摘要：

  DOI：

  10.1016/s0040-4039(01)87186-0

文献信息

• [EN] METHOD FOR THE MANUFACTURE OF ALKOXYSILYL-CONTAINING THIOCARBOXYLIC ACID ESTERS<br/>[FR] PROCÉDÉ DE FABRICATION D'ESTERS D'ACIDE THIOCARBOXYLIQUE CONTENANT DE L'ALKOXYSILYLE
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2020223068A1

  公开（公告）日：2020-11-05

  There is provided herein a method for the manufacture of alkoxysilyl-containing thiocarboxylic acid ester which comprises reacting a thioester with a mercapto-functional alkoxy silane and/or an alkali metal salt, an alkaline earth metal salt, a trisubstituted ammonium salt of an alkoxysilyl-functional thiolate which uses economical and readily available reagents, avoids the use of phosgene or thionyl chloride reagents and produces byproducts that may be recycled.

  本文提供了一种制备含烷氧硅基硫代羧酸酯的方法，包括将硫酯与巯基功能烷氧硅烷和/或碱金属盐、碱土金属盐、烷氧硅基硫醇酸三取代铵盐反应，使用经济实惠且易得的试剂，避免使用光气或氯化硫酰试剂，并产生可循环利用的副产物。
• Method for the manufacture of alkoxysilyl-containing thiocarboxylic acid esters
  申请人：Momentive Performance Materials Inc.

  公开号：US10919920B2

  公开（公告）日：2021-02-16

  There is provided herein a method for the manufacture of alkoxysilyl-containing thiocarboxylic acid ester which comprises reacting a thioester with a mercapto-functional alkoxysilane and/or an alkali metal salt, an alkaline earth metal salt, a trisubstituted ammonium salt of an alkoxysilyl-functional thiolate which uses economical and readily available reagents, avoids the use of phosgene or thionyl chloride reagents and produces byproducts that may be recycled.

  本文提供了一种制造含烷氧基硅烷的硫代羧酸酯的方法，该方法包括使硫代酯与巯基官能团烷氧基硅烷和/或碱金属盐、碱土金属盐、烷氧基硅烷官能团硫酸酯的三取代铵盐反应，该方法使用经济且易于获得的试剂，避免使用光气或亚硫酰氯试剂，且产生的副产品可回收利用。
• NOKAMI JUNZO; KAWADA MIKIO; OKAWARA ROKURO; TORII SIGERU; TANAKA HIDEO, TETRAHEDRON. LETT., 1979, NO 12, 1045-1046
  作者：NOKAMI JUNZO、 KAWADA MIKIO、 OKAWARA ROKURO、 TORII SIGERU、 TANAKA HIDEO

  DOI：——

  日期：——
• METHOD FOR THE MANUFACTURE OF ALKOXYSILYL-CONTAINING THIOCARBOXYLIC ACID ESTERS
  申请人：Momentive Performance Materials Inc.

  公开号：US20200347084A1

  公开（公告）日：2020-11-05

  There is provided herein a method for the manufacture of alkoxysilyl-containing thiocarboxylic acid ester which comprises reacting a thioester with a mercapto-functional alkoxysilane and/or an alkali metal salt, an alkaline earth metal salt, a trisubstituted ammonium salt of an alkoxysilyl-functional thiolate which uses economical and readily available reagents, avoids the use of phosgene or thionyl chloride reagents and produces byproducts that may be recycled.
• Electrochemical synthesis of aldehydes and acetals from α-phenylthiocarboxylic acid
  作者：Junzo Nokami、Mikio Kawada、Rokuro Okawara、Sigeru Torii、Hideo Tanaka

  DOI：10.1016/s0040-4039(01)87186-0

  日期：1979.1