Methyl-11-[(2-methoxy-2-oxoethyl)thio]undecanoate | 1246357-44-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Methyl-11-[(2-methoxy-2-oxoethyl)thio]undecanoate
• 英文别名: Methyl 11-(2-methoxy-2-oxoethyl)sulfanylundecanoate；methyl 11-(2-methoxy-2-oxoethyl)sulfanylundecanoate
• CAS: 1246357-44-7
• 化学式: C₁₅H₂₈O₄S
• 分子量: 304.451
• InChiKey: BBTSJWJVHZGWIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  77.9
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  10-烯酸甲酯 、 巯基乙酸甲酯 在 2,2-二羟甲基丙酸 作用下， 生成 Methyl-11-[(2-methoxy-2-oxoethyl)thio]undecanoate
  参考文献：
  名称：

  Polyesters derived from bio-based eugenol and 10-undecenoic acid: synthesis, characterization, and structure–property relationships

  摘要：

  一系列具有多种热和机械性能的热塑性聚酯被制备出来，它们来自可再生的大麻酚，这种大麻酚是从木质纤维素生物质的丁香油中提取出来的。

  DOI：

  10.1039/c5ra17457k

文献信息

• [EN] NEW PROCESS OF PREPARATION OF POLYOLS AND POLYAMINES, AND PRODUCTS AS OBTAINED<br/>[FR] NOUVEAU PROCÉDÉ DE PRÉPARATION DE POLYOLS ET DE POLYAMINES, ET PRODUITS OBTENUS
  申请人：CENTRE NAT RECH SCIENT

  公开号：WO2013072436A1

  公开（公告）日：2013-05-23

  The present invention relates to the use of a compound of formula (I) : wherein: - R represents –OH or –NH2;- A1 represents a divalent alkylene radical, straight or branched, having from 2 to 20 carbon atoms; - A2 represents a divalent alkylene radical, straight or branched, having from 1 to 20 carbon atoms; - X1 and X2 represent, independently of each other, –NH- or –O-;- A3 represents a divalent alkylene radical, straight or branched, having from 1 to 10 carbon atoms; - Z represents a hydrogen or a group of formula (A'): wherein A1, A3 and R are as defined above in formula (I), for the preparation of a polymer chosen among polyurethane, polyester and polyamide.

  本发明涉及使用公式（I）的化合物：其中：- R代表-OH或-NH2；- A1代表一个二价亚烷基基团，直链或支链，具有2到20个碳原子；- A2代表一个二价亚烷基基团，直链或支链，具有1到20个碳原子；- X1和X2分别独立地代表-NH-或-O-；- A3代表一个二价亚烷基基团，直链或支链，具有1到10个碳原子；- Z代表氢或公式（A'）的基团：其中A1、A3和R在公式（I）中如上定义，用于制备选自聚氨酯、聚酯和聚酰胺的聚合物。
• NEW PROCESS OF PREPARATION OF POLYOLS AND POLYAMINES, AND PRODUCTS AS OBTAINED
  申请人：Centre National de la Recherche Scientifique (C.N.R.S.)

  公开号：EP2780320B1

  公开（公告）日：2017-05-17
• New Process of Preparation of Polyols and Polyamines, and Products as Obtained
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)

  公开号：US20140323651A1

  公开（公告）日：2014-10-30

  The present invention relates to the use of a compound of formula (I): wherein: —R represents —OH or —NH 2 ; —A 1 represents a divalent alkylene radical, straight or branched, having from 2 to 20 carbon atoms; —A 2 represents a divalent alkylene radical, straight or branched, having from 1 to 20 carbon atoms; —X 1 and X 2 represent, independently of each other, —NH— or −O—; —A 3 represents a divalent alkylene radical, straight or branched, having from 1 to 10 carbon atoms; —Z represents a hydrogen or a group of formula (A′): wherein A 1 , A 3 and R are as defined above in formula (I), for the preparation of a polymer chosen among polyurethane, polyester and polyamide.
• US9605145B2
  申请人：——

  公开号：US9605145B2

  公开（公告）日：2017-03-28
• Polyesters derived from bio-based eugenol and 10-undecenoic acid: synthesis, characterization, and structure–property relationships
  作者：Keling Hu、Dongping Zhao、Guolin Wu、Jianbiao Ma

  DOI：10.1039/c5ra17457k

  日期：——

  A series of thermoplastic polyesters with versatile thermal and mechanical properties were prepared from renewable eugenol, which is extracted from lignocellulosic biomass-clove oil.

  一系列具有多种热和机械性能的热塑性聚酯被制备出来，它们来自可再生的大麻酚，这种大麻酚是从木质纤维素生物质的丁香油中提取出来的。