1,1,2,3-Tetrachlorobut-1-ene | 63099-66-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2,3-Tetrachlorobut-1-ene
• CAS: 63099-66-1
• 化学式: C₄H₄Cl₄
• 分子量: 193.9
• InChiKey: FBSPLEKACMFIFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,4-三甲基苯 、 1,1,2,3-Tetrachlorobut-1-ene 、 三氯化铝 以60%的产率得到
  参考文献：
  名称：

  DYUSENOV M. I.; NIKISHIN G. I.; SHAPETKO N. N.; KOZHABEKOV ZH. E.; LUBUZH+, KAZSSR GYLYM AKAD. XABARLARY, IZV. AN KAZSSR. CEP. XIM., 1980, HO 1, 79-8+

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1,1,2,3-Pentachlorobutane 生成 1,1,2,3-Tetrachlorobut-1-ene
  参考文献：
  名称：

  KAPLANYAN, EH. E.;ADAMYAN, A. P.;TATEVOSYAN, N. TS.;MKRTCHYAN, A. M.;MKRY+, ARM. XIM. ZH., 1984, 37, N 2, 95-101

  摘要：

  DOI：

文献信息

• ADIABATIC PLUG FLOW REACTORS AND PROCESSES INCORPORATING THE SAME
  申请人：Tirtowidjojo Max M.

  公开号：US20110087056A1

  公开（公告）日：2011-04-14

  The present invention provides adiabatic plug flow reactors suitable for the production of chlorinated and/or fluorinated propene and higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes. The reactors comprise one or more designs that minimize the production of by-products at a desired conversion.

  本发明提供了适用于从氯化和/或氟化烷烃和氯化和/或氟化烯烃的反应中生产氯化和/或氟化丙烯和更高烯烃的绝热塞流反应器。这些反应器包括一种或多种设计，可以最大限度地减少副产物的产生，同时实现所需的转化率。
• ISOTHERMAL MULTITUBE REACTORS AND PROCESSES INCORPORATING THE SAME
  申请人：Tirtowidjojo Max M.

  公开号：US20110087054A1

  公开（公告）日：2011-04-14

  The present invention provides isothermal multitube reactors suitable for the production of chlorinated and/or fluorinated propene and higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes. The reactors utilize a feed mixture inlet temperature at least 20° C. different from a desired reaction temperature.

  本发明提供了适用于从氯化和/或氟化烷烃和氯化和/或氟化烯烃的反应中生产氯化和/或氟化丙烯和较高烯烃的等温多管反应器。这些反应器利用了进料混合物入口温度至少比期望的反应温度高20°C。
• PROCESSES FOR THE PRODUCTION OF CHLORINATED AND/OR FLUORINATED PROPENES AND HIGHER ALKENES
  申请人：Tirtowidjojo Max M.

  公开号：US20110087055A1

  公开（公告）日：2011-04-14

  The present invention provides continuous, gas phase, free radical processes for the production of chlorinated and/or fluorinated propenes or higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes, wherein wherein at least a portion of any intermediate boiler by-products generated by the process are removed from the process

  本发明提供了连续的气相自由基过程，用于从氯化和/或氟化烷烃和氯化和/或氟化烯烃的反应中生产氯化和/或氟化丙烯或更高烯烃，其中过程产生的任何中间锅炉副产物的至少一部分被从过程中移除。
• Process for production of 2,3-dichlorobutadiene-1,3
  申请人：REDWINE TERRY WAYNE

  公开号：US20090163746A1

  公开（公告）日：2009-06-25

  Purified chlorinated alkenes are produced by a process in which a mixture of i) a first chlorinated alkene that has at least one beta-chlorine substituent and no alpha-chlorine substituents and ii) a second chlorinated alkene that has at least one alpha-chlorine substituent is contacted with chlorine in an amount sufficient to further chlorinate the second chlorinated alkene, but which is insufficient to cause conversion of more than 20% of the first chlorinated alkene. The resultant reaction product may be easily enriched to provide a chlorinated alkene product wherein a) the weight percentage of chlorinated alkenes having at least one beta-chlorine substituent and no alpha-chlorine substituents, based on the total weight of the chlorinated alkenes present in the enriched chlorinated alkene product compared to b) the weight percentage of chlorinated alkenes having at least one beta-chlorine substituent and no alpha-chlorine substituents, based on the total weight of the chlorinated alkenes present in the mixture prior to chlorination is increased by at least 0.25 wt. %.

  经过一种方法制备纯化的氯化烯烃，其中混合物包括i）至少有一个β-氯代取代基且没有α-氯代取代基的第一氯化烯烃和ii）至少有一个α-氯代取代基的第二氯化烯烃，该混合物与氯气接触，氯气的量足以进一步氯代第二氯化烯烃，但不足以使第一氯化烯烃的转化率超过20％。所得的反应产物可以轻松富集，以提供氯化烯烃产品，其中a）基于富集的氯化烯烃产品中存在的氯化烯烃的总重量，至少有一个β-氯代取代基且没有α-氯代取代基的氯化烯烃的重量百分比，与b）基于氯化前混合物中存在的氯化烯烃的总重量，至少有一个β-氯代取代基且没有α-氯代取代基的氯化烯烃的重量百分比相比，增加了至少0.25重量％。
• COMPOSITIONS BASED ON 1,1,3,3-TETRACHLOROPROPENE
  申请人：ARKEMA FRANCE

  公开号：US20180148394A1

  公开（公告）日：2018-05-31

  The present invention relates to compositions based on F-1230za (1,1,3,3-tetrachloropropene), or on a mixture consisting of F-1230za and F-1230zd (1,3,3,3-tetrachloropropene), the manufacture thereof, and also the use thereof in particular for the production of F-1233zdE (trans-1-chloro-3,3,3-trifluoropropene), F-1234zeE (trans-1,3,3,3-tetrafluoropropene), and/or F-245fa (1,1,1,3,3-pentafluoropropane).

  本发明涉及基于F-1230za（1,1,3,3-四氯丙烯）或由F-1230za和F-1230zd（1,3,3,3-四氯丙烯）组成的混合物的组合物，其制造方法以及特别适用于生产F-1233zdE（反-1-氯-3,3,3-三氟丙烯）、F-1234zeE（反-1,3,3,3-四氟丙烯）和/或F-245fa（1,1,1,3,3-五氟丙烷）的用途。