guaiacolethanol | 87194-82-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: guaiacolethanol
• 英文别名: 2-(3-Hydroxypropoxy)phenol
• CAS: 87194-82-9
• 化学式: C₉H₁₂O₃
• 分子量: 168.192
• InChiKey: FJTJVPJLCASRGA-UHFFFAOYSA-N

物化性质

• 沸点：
  304.8±17.0 °C(Predicted)
• 密度：
  1.181±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  guaiacolethanol 生成 Dimethyl-dithiocarbamic acid 4-[2-(3-hydroxy-propoxy)-phenoxy]-butyl ester
  参考文献：
  名称：

  Strijdonck, Gino P. F. van; Haare, John A. E. H. van; Hoenen, Paulus J.M., Journal of the Chemical Society, Dalton Transactions, 1997, p. 449 - 462

  摘要：

  DOI：
• 作为产物：
  描述：

  3-(2-methoxyphenoxy)propan-1-ol 在 二苯基膦酸锂 作用下， 生成 guaiacolethanol
  参考文献：
  名称：

  Strijdonck, Gino P. F. van; Haare, John A. E. H. van; Hoenen, Paulus J.M., Journal of the Chemical Society, Dalton Transactions, 1997, p. 449 - 462

  摘要：

  DOI：

文献信息

• New Kemp’s Diacid Derivatives Give Efficient Transport and Modifiable Selectivity for Alkaline Earth and Transition Metal Ions
  作者：Bruce W. Baldwin、Takuji Hirose、Zhen-He Wang、Tadafumi Uchimaru、Ari Yliniemelä

  DOI：10.1246/bcsj.70.1895

  日期：1997.8

  New derivatives of 1,3,5-trimethyl-r-1, c-3, c-5-cyclohexanetricarboxylic acid (Kemp’s triacid) showed high efficiency for alkaline earth and transition metal ion transport through a chloroform liquid membrane. Simple syntheses from Kemp’s triacid or its geometric isomer provided chelating agents with a tripodal binding site for metal cations. The tripodal binding site consisted of r-1, c-3-diaxial

  1,3,5-三甲基-r-1、c-3、c-5-环己烷三羧酸（肯普三酸）的新衍生物显示出通过氯仿液膜传输碱土金属和过渡金属离子的高效率。坎普三酸或其几何异构体的简单合成为螯合剂提供了金属阳离子的三足结合位点。三足结合位点由 r-1、c-3-双轴羧基和 c-5-酰胺、酯或 C-甲基组成。碱土金属运输变化很大，对 c-5 基团的变化很敏感。对于过渡金属运输，c-5-酰胺二酸具有较高的总运输效率。对于 c-5-酯或 C-甲基二酸，较小的二价阳离子的络合减少，导致对大阳离子的选择性增加。
• Mixture which can be thermally hardened and hardened by actinic radiation and use thereof
  申请人：——

  公开号：US20040053159A1

  公开（公告）日：2004-03-18

  A mixture curable thermally and with actinic radiation, comprising (A) a binder free from carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and having a glass transition temperature Tg of from −40 to +80° C., (B) at least one blocked and/or unblocked polyisocyanate having at least one soft, flexibilizing segment, which as a constituent of three-dimensional polymeric networks lowers their glass transition temperature Tg, and (C) at least one unsaturated polyfunctional urethane which is free from isocyanate-reactive functional groups and contains on average per molecule more than four carbon-carbon double bonds activatable with actinic radiation and at least one hardening segment, the hardening segment as a constituent of three-dimensional polymer networks increasing their glass transition temperature Tg; processes for preparing it and its use.

  一种可通过热固化和光辐射固化的混合物，包括 (A) 不含碳碳双键的粘结剂，可通过辐射活化，包括至少一种（甲基）丙烯酸 酯共聚物，平均每个分子含有至少一个异氰酸酯反应官能团，玻璃化温度 Tg 为 -40 至 80 摄氏度、 (B) 至少一种封端和/或未封端的多异氰酸酯，该多异氰酸酯至少有一个柔软的柔 化段，作为三维聚合物网络的成分，可降低其玻璃化转变温度 Tg，以及 (C) 至少一种不饱和多官能度聚氨酯，该聚氨酯不含异氰酸酯反应官能团，每 个分子平均含有四个以上可被辐射活化的碳碳双键和至少一个硬化段，该硬化 段作为三维聚合物网络的组成成分可提高其玻璃化转变温度 Tg； 制备工艺及其用途。
• Hardenable powder paints, method for the production thereof, and mixing system for powder paints
  申请人：——

  公开号：US20040059050A1

  公开（公告）日：2004-03-25

  A curable powder coating material preparable by applying at least one dispersion and/or at least one solution (I) comprising (A) at least one functional constituent of a powder coating material, (B) at least one solvent, and, if desired, (C) at least one oligomeric and/or polymeric constituent, with partial, essentially complete or complete evaporation of the solvent or solvents (B) to the surface of dimensionally stable particles (II); and also a novel mixer system and a novel process for preparing and/or subsequently adjusting the material composition and/or performance properties profile of curable powder coating materials, using at least one dispersion and/or at least one solution (I).

  一种可固化粉末涂料，其制备方法是将至少一种分散体和/或至少一种溶液 (I) 涂在尺寸稳定颗粒 (II) 的表面上，溶剂 (B) 部分、基本完全或完全蒸发，该分散体和/或溶液 (I) 包含 (A) 至少一种粉末涂料功能成分，(B) 至少一种溶剂，如果需要，(C) 至少一种低聚物和/或聚合物成分；以及一种新型混合系统和一种新型工艺，用于使用至少一种分散体和/或至少一种溶液（I）制备和/或随后调整可固化粉末涂料的材料成分和/或性能特征。
• Aqueous dispersions, which can be hardened thermally and by using actinic radiation, method for the production thereof and their use
  申请人：——

  公开号：US20040052966A1

  公开（公告）日：2004-03-18

  Aqueous dispersions curable thermally and with actinic radiation, comprising (I) liquid, and/or highly viscous solid particles dimensionally stable under storage and application conditions, comprising (IA) a binder free of carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and at least one dispersive functional group, and (IB) at least one blocked polyisocyanate; (II) liquid, highly viscous and/or solid particles dimensionally stable under storage and application conditions, comprising at least one polyurethane (II) containing at least one isocyanate-reactive functional group, at least one functional group having at least one bond activatable with actinic radiation, and at least one dispersive functional group, and (III) at least one unsaturated constituent which is free of isocyanate-reactive functional groups and contains on average per molecule more than one carbon-carbon double bond activatable with actinic radiation; processes for preparing them, and their use.

  可通过热固化和光辐射固化的水性分散体，包括 (I) 在储存和应用条件下尺寸稳定的液体和/或高粘度固体颗粒，包括 (IA) 不含碳碳双键的粘合剂，可通过辐射活化，包括至少一种（甲基）丙烯酸酯共聚物，平均每个分子含有至少一个异氰酸酯反应性官能团和至少一个分散性官能团，以及 (IB) 至少一种封端多异氰酸酯； (II) 在储存和应用条件下尺寸稳定的液态、高粘度和/或固态颗粒，包括至少一种聚氨酯 (II)，其中含有至少一个异氰酸酯反应官能团、至少一个具有至少一个可被放 射线激活的键的官能团和至少一个分散官能团，以及 (III) 至少一种不饱和成分，不含异氰酸酯反应官能团，且平均每分子含有一个以上可被放 射线激活的碳碳双键； 制备工艺及其用途。
• Verfahren zur Bestimmung der Vortrocknungstemperatur eines Elektrotauchlacks
  申请人：BASF Coatings AG

  公开号：EP1333940B1

  公开（公告）日：2005-12-28