3-methyl-9-vinyl-carbazole | 25904-49-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-methyl-9-vinyl-carbazole
• 英文别名: 9-Ethenyl-3-methyl-9H-carbazole；9-ethenyl-3-methylcarbazole
• CAS: 25904-49-8
• 化学式: C₁₅H₁₃N
• 分子量: 207.275
• InChiKey: OOWDQTDDYREURW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-甲基咔唑 、 乙酸乙烯酯 生成 3-methyl-9-vinyl-carbazole
  参考文献：
  名称：

  SHEXIREV, YU. P.;SUTYAGIN, V. M.;LOPATINSKIJ, V. P., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1984, 27, N 9, 1021-1024

  摘要：

  DOI：

文献信息

• PHOSPHORS AND PROCESS FOR PRODUCTION THEREOF, LUMINESCENT COMPOSITIONS, AND ORGANIC ELECTROLUMINESCENT DEVICES AND PROCESSES FOR PRODUCTION THEREOF
  申请人：JSR Corporation

  公开号：EP1516901A1

  公开（公告）日：2005-03-23

  Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof. A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1). [In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R1 and R2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R1 and R2 may be either the same or different, X1 represents a phenylene group or a carbonyloxy group, X2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]

  本发明公开了一种可通过湿法形成薄膜并提供具有高亮度的有机电致发光器件的磷光剂及其生产工艺，以及一种含有该磷光剂的发光组合物、一种具有含有该磷光剂的发光层的有机电致发光器件及其生产工艺。 根据本发明的磷光剂包括一种聚合物，其分子中具有由以下通式（1）表示的结构单元。 [通式（1）中，M 代表价数为 2 至 4 的金属原子，R1 和 R2 分别代表氢原子、卤素原子、环烷基、芳基和杂环基，且 R1 和 R2 可以相同或不同，X1 代表亚苯基或碳酰氧基，X2 代表亚烷基，L 代表有机配位体，p 为 1 至 3 的整数，q 为 0 或 1。］
• COPOLYMER AND OPTICAL FILM USING SAME
  申请人：Tosoh Corporation

  公开号：EP3553097A1

  公开（公告）日：2019-10-16

  Provided are a novel copolymer which is expected to form an optical film that has excellent retardation characteristics such as high retardation even in a thin film and an optical film using the same. A copolymer comprising a residue unit A represented by the general formula (1) and a residue unit B represented by the general formula (2): wherein R1 and R2 each independently represent hydrogen (provided that the case where R1 and R2 are both hydrogen is eliminated), a cyano group, an ester group (-C(=O)OX1), an amide group (-C(=O)N(X2)(X3)), or an acyl group (-C(=O)X4) (where X1 to X3 each independently represent a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 1 to 12 carbon atoms, or a cyclic alkyl group having 3 to 6 carbon atoms, and X4 represents a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 1 to 12 carbon atoms, or a cyclic group having 3 to 14 carbon atoms); R3 to R7 each independently represent hydrogen, a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 1 to 12 carbon atoms, a cyclic group having 3 to 14 carbon atoms, a halogen, a hydroxy group, a carboxy group, a nitro group, a cyano group, an alkoxy group (-OX5), an ester group (-C(=O)OX6), an amide group (-C(=O)N(X7)(X8)), an acyl group (-C(=O)X9), an amino group (-N(X10)(X11)), or a sulfonic acid group (-SOOX12) (where X5 to X8 each independently represent a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 1 to 12 carbon atoms, or a cyclic alkyl group having 3 to 6 carbon atoms, X9 to X12 each independently represent hydrogen, a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 1 to 12 carbon atoms, or a cyclic alkyl group having 3 to 6 carbon atoms); and adjacent substituents among R3 to R7 may form a fused ring structure each other, wherein R8 represents an m-membered heterocyclic residue containing one or more heteroatoms or a 5-membered or 6-membered ring residue containing no heteroatom (provided that, when R8 is a 6-membered ring residue containing no heteroatom, at least one of R3 to R7 in the general formula (1) represents a hydroxy group), and m represents an integer of 5 to 10; and the m-membered heterocyclic residue, the 5-membered ring residue, and the 6-membered ring residue may form a fused ring structure.

  本发明提供了一种新型共聚物，该共聚物可望形成一种光学薄膜，该光学薄膜具有优异的延缓特性，例如即使在薄膜中也具有高延缓性，本发明还提供了使用该共聚物的光学薄膜。 由通式（1）表示的残留单元 A 和通式（2）表示的残留单元 B 组成的共聚物： 其中 R1 和 R2 各自独立地代表氢（前提是排除 R1 和 R2 都是氢的情况）、氰基、酯基（-C(＝O)OX1）、酰胺基（-C(＝O)N(X2)(X3)）或酰基（-C(＝O)X4）（其中 X1 至 X3 各自独立地代表具有 1 至 12 个碳原子的直链烷基、具有 1 至 12 个碳原子的支链烷基或具有 3 至 6 个碳原子的环状烷基，而 X4 代表具有 1 至 12 个碳原子的直链烷基、具有 1 至 12 个碳原子的支链烷基或具有 3 至 14 个碳原子的环状基团）；R3 至 R7 各自独立地代表氢、具有 1 至 12 个碳原子的直链烷基、具有 1 至 12 个碳原子的支链烷基、具有 3 至 14 个碳原子的环基、卤素羟基、羧基、硝基、氰基、烷氧基 (-OX5)、酯基 (-C(=O)OX6)、酰胺基 (-C(=O)N(X7)(X8))、酰基 (-C(=O)X9)、氨基 (-N(X10)(X11))、或磺酸基（-SOOX12）（其中 X5 至 X8 各自独立地代表具有 1 至 12 个碳原子的直链烷基、具有 1 至 12 个碳原子的支链烷基或具有 3 至 6 个碳原子的环状烷基，X9 至 X12 各自独立地代表氢、具有 1 至 12 个碳原子的直链烷基、具有 1 至 12 个碳原子的支链烷基或具有 3 至 6 个碳原子的环状烷基）；R3 至 R7 中的相邻取代基可相互形成融合环结构、 其中 R8 代表含有一个或多个杂原子的 m 元杂环残基或不含杂原子的 5 元或 6 元环残基（条件是，当 R8 是不含杂原子的 6 元环残基时，通式（1）中 R3 至 R7 中至少有一个代表羟基），且 m 代表 5 至 10 的整数；且 m 元杂环残基、5 元环残基和 6 元环残基可形成融合环结构。
• Copolymer and optical film using same
  申请人：TOSOH CORPORATION

  公开号：US11225540B2

  公开（公告）日：2022-01-18

  A novel copolymer suitable for an optical film which is excellent in optical characteristics and has high retardation even in a thin film state, and an optical film containing the same are provided. A copolymer excellent in optical characteristics and easy to form a composite with a different polymer, and an optical film composed of the same are also provided.

  本发明提供了一种适用于光学薄膜的新型共聚物，这种共聚物具有优异的光学特性，即使在薄膜状态下也具有较高的延缓性，本发明还提供了一种含有这种共聚物的光学薄膜。此外，还提供了一种光学特性优异且易于与其他聚合物形成复合材料的共聚物，以及由其构成的光学薄膜。
• Light emitting polymer composition, and organic electroluminescence device and production process thereof
  申请人：JSR CORPORATION

  公开号：US20030116788A1

  公开（公告）日：2003-06-26

  Disclosed herein is a light emitting polymer composition which permits providing an organic electroluminescence device high in luminous efficiency and excellent in durability and forming a functional organic material layer with ease by the wet process. The light emitting polymer composition comprising a polymer component and a phosphorescent agent contained in the polymer component, wherein the polymer component is composed of a hole transporting component formed from 50 to 99 mol % of a hole transporting monomer and an electron transporting component formed from 50 to 1 mol % of an electron transporting monomer. The polymer component is a copolymer composed of 50 to 99 mol % of structural units derived from the hole transporting monomer and 50 to 1 mol % of structural units derived from the electron transporting monomer, or is composed of a hole transporting polymer obtained from the hole transporting monomer and an electron transporting polymer obtained from the electron transporting monomer, and a proportion of the hole transporting polymer to the electron transporting polymer is 50:50 to 99:1 in terms of a molar ratio reduced to the monomers. The light emitting polymer composition is used in an organic electroluminescence device and a production process thereof.

  本文公开了一种发光聚合物组合物，该组合物可提供发光效率高、耐用性好的有机电致发光器件，并可通过湿法工艺轻松形成功能性有机材料层。 该发光聚合物组合物包括聚合物成分和聚合物成分中所含的磷光剂，其中聚合物成分由 50 至 99 摩尔%的空穴传输单体形成的空穴传输成分和 50 至 1 摩尔%的电子传输单体形成的电子传输成分组成。该聚合物成分是由 50 至 99 摩尔%的空穴传输单体衍生的结构单元和 50 至 1 摩尔%的电子传输单体衍生的结构单元组成的共聚物，或者是由空穴传输单体获得的空穴传输聚合物和电子传输单体获得的电子传输聚合物组成的共聚物，并且空穴传输聚合物与电子传输聚合物的摩尔比为 50:50 至 99:1。该发光聚合物组合物可用于有机电致发光装置及其生产工艺中。
• Phosphors and process for production thereof, luminescent compositions, and organic electroluminescent devices and processes for production thereof
  申请人：Sakakibara Mitsuhiko

  公开号：US20050145830A1

  公开（公告）日：2005-07-07

  Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof. A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1). [In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R 1 and R 2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R 1 and R 2 may be either the same or different, X 1 represents a phenylene group or a carbonyloxy group, X 2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]

  本发明公开了一种可通过湿法形成薄膜并提供具有高亮度的有机电致发光器件的磷光剂及其生产工艺，以及一种含有该磷光剂的发光组合物、一种具有含有该磷光剂的发光层的有机电致发光器件及其生产工艺。 根据本发明的磷光剂包括一种聚合物，其分子中具有由以下通式（1）表示的结构单元。 [在通式（1）中，M 代表价数为 2 至 4 的金属原子，R 1 和 R 2 代表氢原子、卤素原子、环烷基、芳基和杂环基，R 1 和 R 2 可以相同或不同，X 1 代表亚苯基或羰氧基，X 2 代表亚烷基，L 代表有机配体，p 是 1 到 3 的整数，q 是 0 或 1。］