methyl undec-3-enoate | 64749-23-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methyl undec-3-enoate
• 英文别名: undec-3-enoic acid methyl ester；Methyl undec-3-enoate
• CAS: 64749-23-1
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: UXEZTQUHDSYCQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl undec-3-enoate 在 lithium aluminium tetrahydride 作用下， 生成 3-Undecen-1-ol
  参考文献：
  名称：

  Hydroboration and thermal isomerization of unsaturated alcohols

  摘要：

  DOI：

  10.1021/jo00970a014
• 作为产物：
  描述：

  反式-1-溴-2-癸烯 在 盐酸 、 双氧水 、 甲基三辛基氯化铵 作用下， 以 sodium hydroxide 、 甲苯 为溶剂， 反应 78.0h， 生成 methyl undec-3-enoate
  参考文献：
  名称：

  甲基硫代甲基对甲苯基砜在有机合成中的应用

  摘要：

  发现甲硫基甲基对甲苯基砜是制备各种有机化合物的有用试剂之一，例如 S-甲基 α-酮硫代碳酸酯、羧酸酯、五元和六元环烷酮和 α-甲氧基-α-芳基乙酸酯。

  DOI：

  10.1246/cl.1983.767

文献信息

• Enecarboxylation with diethyl oxomalonate as an enophilic equivalent of carbon dioxide. A synthesis of allylcarboxylic acids
  作者：Mary F. Salomon、Simon N. Pardo、Robert G. Salomon

  DOI：10.1021/ja00325a014

  日期：1984.6

  On prepare une serie d'acides carboxyliques allyliques a partir des olefines correspondantes par un processus en deux etapes equivalent a: 1) une reaction ene avec l'oxomalonate de diethyle conduisant a l'ester α-hydroxymalonique; 2) une bisdecarboxylation oxydante de ce dernier

  在制备 une serie d'acides carboxyliques allyliques a partir des ocoxyliques par un processus en deux etapes 等价物 a: 1) une 反应 ene avec l'oxomalonate de diethyle conduisant a l'ester α-hydroxymalonique; 2) une bisdecarboxylation oxydante de ce dernier
• STABILIZED MENTHOL AND OTHER VOLATILE COMPOUND COMPOSITIONS AND METHODS
  申请人：Ghalili Babak

  公开号：US20210236436A1

  公开（公告）日：2021-08-05

  The present disclosure relates to a stabilized or more stable volatile compound, e.g., menthol, compositions and methods of making and using them including a mixture of a stabilizer compound of formula (I), for example, undecylenic acid methyl ester, undecylenic acid or a salt thereof and a volatile compound where the volatile compound is less susceptible to volatizing into a gas. wherein A is —(CH2) a -CH═CH—(CH 2) 5-a -H where a is from 0 to 5, —(CH2) b -CH═CH—(CH 2) 6-b -H where b is from 0 to 6, —(CH2) c -CH═CH—(CH 2) 7-c -H where c is from 0 to 7, —(CH2) d -CH═CH—(CH 2) 5-d -H where d is from 0 to 8, or —CH2) e -CH═CH—(CH 2) 9-d -H where d is from 0 to 9; B is hydrogen or C 1-5 alkyl; and pharmaceutically acceptable salts thereof where B is hydrogen.
• [EN] STABILIZED MENTHOL AND OTHER VOLATILE COMPOUND COMPOSITIONS AND METHODS<br/>[FR] MENTHOL STABILISÉ ET AUTRES COMPOSITIONS DE COMPOSÉS VOLATILS ET PROCÉDÉS
  申请人：GHALILI BABAK

  公开号：WO2021154979A1

  公开（公告）日：2021-08-05

  The present disclosure relates to a stabilized or more stable volatile compound, e.g., menthol, compositions and methods of making and using them including a mixture of a stabilizer compound of formula (I), for example, undecylenic acid methyl ester, undecylenic acid or a salt thereof and a volatile compound where the volatile compound is less susceptible to volatizing into a gas. Formula (I) wherein A is -(CH2)a-CH=CH-(CH 2)s-a-H where a is from 0 to 5, -(CH2)b-CH=CH-(CH 2)e-b-H where b is from 0 to 6, -(CH2)c-CH=CH-(CH 2)/-ο-Η where c is from 0 to 7, -(CH2)d-CH=CH-(CH 2)8-d-H where d is from 0 to 8, or -CH2)e-CH=CH-(CH 2)g-d-H where d is from 0 to 9; B is hydrogen or C1-5 alkyl; and pharmaceutically acceptable salts thereof where B is hydrogen.
• Hydroboration and thermal isomerization of unsaturated alcohols
  作者：Keiiti Sisido、Mikio Naruse、Akihisa Saito、Kiitiro Utimoto

  DOI：10.1021/jo00970a014

  日期：1972.3
• UTILIZATION OF METHYLTHIOMETHYL<i>p</i>-TOLYL SULFONE IN ORGANIC SYNTHESIS
  作者：Katsuyuki Ogura、Nobuhiro Yahata、Kimitoshi Hashizume、Koichi Tsuyama、Kazumasa Takahashi、Hirotada Iida

  DOI：10.1246/cl.1983.767

  日期：1983.5.5

  Methylthiomethyl p-tolyl sulfone was found to be one of the useful reagents for preparation of various organic compounds such as S-methyl α-ketocarbothioates, carboxylic esters, five- and six-membered cycloalkanones, and α-methoxy-α-arylacetic esters.

  发现甲硫基甲基对甲苯基砜是制备各种有机化合物的有用试剂之一，例如 S-甲基 α-酮硫代碳酸酯、羧酸酯、五元和六元环烷酮和 α-甲氧基-α-芳基乙酸酯。