1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]butane-1,3-dione | 1105615-11-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]butane-1,3-dione
• 英文别名: 1-[9-ethyl-6-(2-methylbenzoyl)carbazol-3-yl]butane-1,3-dione
• CAS: 1105615-11-9
• 化学式: C₂₆H₂₃NO₃
• 分子量: 397.474
• InChiKey: ZIEUVLXKRHDFGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  56.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-乙酰基-6-(邻甲基苯甲酰基)-N-乙基咔唑 在 盐酸 作用下， 以 正己烷 、 乙酸乙酯 为溶剂， 以17.29 g (43%)的产率得到1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]butane-1,3-dione
  参考文献：
  名称：

  ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND

  摘要：

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。

  公开号：

  US20100129753A1

文献信息

• Alkali-developable photosensitive resin composition and β-diketone compound
  申请人：Adeka Corporation

  公开号：US08338081B2

  公开（公告）日：2012-12-25

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R1 is a C1-C20 alkyl group; R2 represents R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种碱可显影光敏树脂组合物，包含（J）一种光聚合不饱和化合物，其结构是由（B）具有β-二酮基团或β-酮酸酯基团的化合物与（A）至少具有两个（甲基）丙烯酰基团和一个羟基的化合物的加成反应所导致，然后酯化所得加成产物的羟基与（C）多酸酐。具有β-二酮基团的化合物最好是由通式（I）表示的新型β-二酮化合物：其中R1是C1-C20烷基；R2代表R11，OR11，COR11，SR11，CONR12R13或CN；R11、R12和R13分别是氢，C1-C20烷基等；a为0到3；b为0到4。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND -DIKETONE COMPOUND
  申请人：Adeka Corporation

  公开号：EP2175320A1

  公开（公告）日：2010-04-14

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R1 is a C1-C20 alkyl group; R2 represents R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可碱显影的感光树脂组合物含有(J)可光聚合的不饱和化合物，其结构是由(B)具有β-二酮分子的化合物或具有β-酮酯基的化合物与(A)具有至少两个(甲基)丙烯酰基和一个羟基的化合物的(甲基)丙烯酰基发生加成反应，然后将加成产物的羟基与(C)多碱性酸酐酯化而成。具有 β-二酮分子的化合物最好是通式 (I) 所代表的新型 β-二酮化合物： 其中 R1 是 C1-C20 烷基；R2 代表 R11、OR11、COR11、SR11、CONR12R13 或 CN；R11、R12 和 R13 分别是氢、C1-C20 烷基等；a 是 0 至 3；b 是 0 至 4。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2175320B1

  公开（公告）日：2013-03-13
• US8338081B2
  申请人：——

  公开号：US8338081B2

  公开（公告）日：2012-12-25
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。