5-(2-(2-methoxyethoxy)ethyl)-5H-thieno[3,4-c]pyrrole-4,6-dione | 1449698-13-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 5-(2-(2-methoxyethoxy)ethyl)-5H-thieno[3,4-c]pyrrole-4,6-dione
• 英文别名: 5-[2-(2-Methoxyethoxy)ethyl]thieno[3,4-c]pyrrole-4,6-dione；5-[2-(2-methoxyethoxy)ethyl]thieno[3,4-c]pyrrole-4,6-dione
• CAS: 1449698-13-8
• 化学式: C₁₁H₁₃NO₄S
• 分子量: 255.295
• InChiKey: VZYLQLGQYOYQBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  84.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3,4-噻吩二羧酸 在 4-二甲氨基吡啶 、 乙酸酐 作用下， 以 1,4-二氧六环 为溶剂， 生成 5-(2-(2-methoxyethoxy)ethyl)-5H-thieno[3,4-c]pyrrole-4,6-dione
  参考文献：
  名称：

  Langmuir–Blodgett Films of Amphiphilic Thieno[3,4-c]pyrrole-4,6-dione-Based Alternating Copolymers

  摘要：

  The synthesis of four amphiphilic thieno[3,4-c]pyrrole-4,6-dione (TPD)-based alternating copolymers and their behavior at the air-water interface are reported. Homogeneous and stable monolayers of TPD-based copolymers were prepared. Brewster angle microscopy (BAM) was utilized to characterize the morphology and topography of these Langmuir films, UV-vis absorption spectroscopy as well as atomic force microscopy has revealed a regular transfer of some copolymers on glass substrates. It was possible to obtain homogeneous Langmuir-Blodgett films of up to 30 layers. Infrared dichroic measurements revealed an edge-on orientation. These Langmuir-Blodgett films made of conjugated polymers are therefore good candidates for organic field-effect transistors (OFETs).

  DOI：

  10.1021/ma401030m

文献信息

• Langmuir–Blodgett Films of Amphiphilic Thieno[3,4-<i>c</i>]pyrrole-4,6-dione-Based Alternating Copolymers
  作者：Mariane Perpethue Ouattara、Stéphane Lenfant、Dominique Vuillaume、Michel Pézolet、Jean-François Rioux-Dubé、Josée Brisson、Mario Leclerc

  DOI：10.1021/ma401030m

  日期：2013.8.27

  The synthesis of four amphiphilic thieno[3,4-c]pyrrole-4,6-dione (TPD)-based alternating copolymers and their behavior at the air-water interface are reported. Homogeneous and stable monolayers of TPD-based copolymers were prepared. Brewster angle microscopy (BAM) was utilized to characterize the morphology and topography of these Langmuir films, UV-vis absorption spectroscopy as well as atomic force microscopy has revealed a regular transfer of some copolymers on glass substrates. It was possible to obtain homogeneous Langmuir-Blodgett films of up to 30 layers. Infrared dichroic measurements revealed an edge-on orientation. These Langmuir-Blodgett films made of conjugated polymers are therefore good candidates for organic field-effect transistors (OFETs).